公开(公告)号：US06777499B2

公开(公告)日：2004-08-17

申请号：US10152184

申请日：2002-05-20

申请人： Yang Li ,  Dingyi Hong ,  Mingchu Gu ,  Jinzong Yang ,  Yurong Wang ,  Hongde Xu ,  Xingjun Lu ,  Li Yang ,  Jian Ding ,  Zhanxia Lv ,  Yongjun Lu ,  Yuchun Song

发明人： Yang Li ,  Dingyi Hong ,  Mingchu Gu ,  Jinzong Yang ,  Yurong Wang ,  Hongde Xu ,  Xingjun Lu ,  Li Yang ,  Jian Ding ,  Zhanxia Lv ,  Yongjun Lu ,  Yuchun Song

IPC分类号： C08F29300

CPC分类号： C08F297/04 ,  C08F297/02

摘要： The present invention relates to multiblock interpolymers having the following symmetric structures and processes for their preparation: Y-X-Y, wherein Y represents a block of a random copolymer of conjugated diene and monovinyl aromatic monomer; and X represents a block of butadiene homopolymer, a block of isoprene homopolymer, or a block of butadiene/isoprene copolymer, and processes for the preparation thereof. The present multiblock interpolymers have in the same molecule both a rubber block of random copolymer of conjugated diene and monovinyl aromatic monomer and a rubber block selected from blocks of butadiene homopolymer, isoprene homopolymer and butadiene/isoprene copolymers, and hence possess excellent properties of the both two kinds of rubbers, and can be used widely as integrated rubber materials with excellent property balance, the present processes can simply prepare the above integrated rubber material in situ in a single reactor.

摘要翻译： 本发明涉及具有以下对称结构的多嵌段互聚物及其制备方法：Y-X-Y，其中Y表示共轭二烯和单乙烯基芳族单体的无规共聚物的嵌段; X表示丁二烯均聚物嵌段，异戊二烯均聚物嵌段或丁二烯/异戊二烯共聚物嵌段，以及其制备方法。 本发明的多嵌段互聚物在同一分子中具有共轭二烯和单乙烯基芳族单体的无规共聚物的橡胶嵌段和选自丁二烯均聚物，异戊二烯均聚物和丁二烯/异戊二烯共聚物的嵌段的橡胶嵌段，因此具有优异的性能 两种橡胶，可广泛用作具有优异性能平衡的综合橡胶材料，本方法可以简单地在单个反应器中原位制备上述一体化橡胶材料。

公开(公告)号：US06372853B1

公开(公告)日：2002-04-16

申请号：US09627105

申请日：2000-07-27

申请人： Yang Li ,  Dingyi Hong ,  Mingchu Gu ,  Jinzong Yang ,  Yurong Wang ,  Hongde Xu ,  Xingjun Lu ,  Zhanxia Lv ,  Yongjun Lu ,  Yuchun Song

发明人： Yang Li ,  Dingyi Hong ,  Mingchu Gu ,  Jinzong Yang ,  Yurong Wang ,  Hongde Xu ,  Xingjun Lu ,  Zhanxia Lv ,  Yongjun Lu ,  Yuchun Song

IPC分类号： C08F29704

CPC分类号： C08F297/046

摘要： The present invention relates to butadiene/isoprene/monovinyl aromatic monomer heptablock copolymers having the following symmetric structure: Z-XZ-X-Y-X-XZ-Z wherein Z represents a polymer block of monovinyl aromatic monomer, X and Y, being different from each other, represent polymer blocks of butadiene or isoprene, XZ represents a tapered copolymer block of monovinyl aromatic monomer and butadiene or isoprene, and wherein the content of the recurring units derived from monovinyl aromatic monomer is 10 to 50 percent by weight, the content of the recurring units derived from butadiene is 10-75 percent by weight and the content of the recurring units derived from isoprene is 10-75 percent by weight, all based on the weight of the block copolymer, and methods for the preparation thereof.

摘要翻译： 本发明涉及具有以下对称结构的丁二烯/异戊二烯/单乙烯基芳族单体七嵌段共聚物：其中Z表示单乙烯基芳族单体的聚合物嵌段，X和Y彼此不同，表示丁二烯或异戊二烯的聚合物嵌段XZ 表示单乙烯基芳族单体和丁二烯或异戊二烯的渐缩共聚物嵌段，其中衍生自单乙烯基芳族单体的重复单元的含量为10〜50重量％，衍生自丁二烯的重复单元的含量为10-75％ 重量，衍生自异戊二烯的重复单元的含量为10-75重量％，均基于嵌段共聚物的重量及其制备方法。