公开(公告)号：US4288634A

公开(公告)日：1981-09-08

申请号：US73664

申请日：1979-09-07

申请人： Tadamori Sakakibara ,  Yoshihisa Matsushima ,  Yukio Nagashima ,  Nobukazu Okamoto ,  Katsumi Kaneko ,  Yohio Ishii ,  Shozo Wada

发明人： Tadamori Sakakibara ,  Yoshihisa Matsushima ,  Yukio Nagashima ,  Nobukazu Okamoto ,  Katsumi Kaneko ,  Yohio Ishii ,  Shozo Wada

IPC分类号： B01J31/12 ,  B01J31/18 ,  B01J31/20 ,  B01J31/24 ,  C07C45/50 ,  C07F15/00

CPC分类号： C07F15/008 ,  B01J31/121 ,  B01J31/1895 ,  B01J31/20 ,  B01J31/2404 ,  C07C45/50 ,  C07F15/00 ,  B01J2531/822

摘要： This invention relates to rhodium compounds having the general formula:HRh(CO)(XR.sub.3).sub.n (YR'.sub.3).sub.3-nwherein X is phosphorus, arsenic or antimony; Y is arsenic or antimony when X is phosphorus, Y is phosphorus or antimony when X is arsenic, or Y is phosphorus, arsenic or antimony when X is antimony; R and R' are aryl groups; and n is an integer of 1 or 2. Further, it relates to a process for the preparation of aldehydes by the hydroformylation of olefins in the presence of a rhodium catalyst, and more particularly for the production of aldehydes by the reaction of olefins such as propylene with carbon monoxide and hydrogen in the presence of HRh(CO)(PPh.sub.3).sub.2 (AsPh.sub.3)/excess PPh.sub.3 and AsPh.sub.3 or HRh(CO)(PPh.sub.3)(AsPh.sub.3).sub.2 /excess PPh.sub.3 and AsPh.sub.3.

摘要翻译： 本发明涉及具有以下通式的铑化合物：其中X是磷，砷或锑的HRh（CO）（XR3）n（YR'3）3-n; 当X是磷时，Y是砷或锑，当X是砷时，Y是磷或锑，或当X是锑时，Y是磷，砷或锑; R和R'是芳基; 并且n是1或2的整数。此外，它涉及通过在铑催化剂存在下烯烃的加氢甲酰化制备醛的方法，更具体地说，涉及通过烯烃如 丙烯与一氧化碳和氢气在HRh（CO）（PPh3）2（AsPh3）/过量的PPh 3和AsPh 3或HRh（CO）（PPh 3）（AsPh 3）2 /过量的PPh 3和AsPh 3的存在下存在。

公开(公告)号：US4397788A

公开(公告)日：1983-08-09

申请号：US238045

申请日：1981-02-25

申请人： Tadamori Sakakibara ,  Yoshihisa Matsushima ,  Yukio Nagashima ,  Nobukazu Okamoto ,  Katsumi Kaneko ,  Yohio Ishii ,  Shozo Wada

发明人： Tadamori Sakakibara ,  Yoshihisa Matsushima ,  Yukio Nagashima ,  Nobukazu Okamoto ,  Katsumi Kaneko ,  Yohio Ishii ,  Shozo Wada

IPC分类号： B01J31/12 ,  B01J31/18 ,  B01J31/20 ,  B01J31/24 ,  C07C45/50 ,  C07F15/00 ,  C07F9/74 ,  C07F9/92

CPC分类号： C07F15/008 ,  B01J31/121 ,  B01J31/1895 ,  B01J31/20 ,  B01J31/2404 ,  C07C45/50 ,  C07F15/00 ,  B01J2531/822

摘要： This invention relates to rhodium compounds having the general formula:HRh(CO)(XR.sub.3).sub.n (YR'.sub.3).sub.3-nwherein X is phosphorus, arsenic or antimony; Y is arsenic or antimony when X is phosphorus, Y is phosphorus or antimony when X is arsenic, or Y is phosphorus, arsenic or antimony when X is antimony; R and R' are aryl groups; and n is an integer of 1 or 2. Further, it relates to a process for the preparation of aldehydes by the hydroformylation of olefins in the presence of a rhodium catalyst, and more particularly for the production of aldehydes by the reaction of olefins such as propylene with carbon monoxide and hydrogen in the presence of HRh(CO)PPh.sub.3).sub.2 (AsPh.sub.3)/excess PPh.sub.3 and AsPh.sub.3 or HRh(CO)(PPh.sub.3)(AsPh.sub.3).sub.2 /excess PPh.sub.3 and AsPh.sub.3.

摘要翻译： 本发明涉及具有以下通式的铑化合物：其中X是磷，砷或锑的HRh（CO）（XR3）n（YR'3）3-n; 当X是磷时，Y是砷或锑，当X是砷时，Y是磷或锑，或当X是锑时，Y是磷，砷或锑; R和R'是芳基; 并且n是1或2的整数。此外，它涉及通过在铑催化剂存在下烯烃的加氢甲酰化制备醛的方法，更具体地说，涉及通过烯烃如 丙烯与一氧化碳和氢气在HRh（CO）PPh3）2（AsPh3）/过量的PPh 3和AsPh 3或HRh（CO）（PPh 3）（AsPh 3）2 /过量的PPh 3和AsPh 3的存在下存在。