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131 条记录 (耗时 0.023 秒)

    Green preparation method for trifluorochloroethylene
    2.
    发明授权
    Green preparation method for trifluorochloroethylene 有权

    公开(公告)号：US09682907B1

    公开(公告)日：2017-06-20

    申请号：US15325895

    申请日：2014-12-09

    申请人： CHANGSHU 3F FLUORINE CHEMICAL CO., LTD.

    发明人： Linxu Si ,  Pingzhong Zhang ,  Hexiang Gu

    IPC分类号： C07C17/23 ,  C07C21/18 ,  B01J31/12

    CPC分类号： C07C21/18 ,  B01J31/12 ,  B01J31/121 ,  C07C17/23

    摘要： A process for preparing trifluorochloroethylene including: in a multi-tubular reactor, hydrogenation reacting 1,1,2-trifluoro-1,2,2-trichloroethane directly with a catalyst potassium zinc trihydride to obtain trifluorochloroethylene, wherein the catalytic reaction is performed at a temperature of 250-350° C. and a pressure of 0.7-1.0 MPa for 10-20 seconds. The conventional process in which zinc powder is used for dechlorination or hydrogen is used for dechlorination through hydrogenation with the action of a noble metal catalyst is avoided in the process disclosed herein. The present process substantially reduces the production cost of trifluorochloroethylene, and substantially increases the product yield, which can be up to 99% or more.

    Process for manufacturing neohexene
    3.
    发明授权
    Process for manufacturing neohexene 失效
    制备新己烯的方法

    公开(公告)号：US08119852B2

    公开(公告)日：2012-02-21

    申请号：US12448216

    申请日：2007-12-11

    申请人： Jean Marie Basset ,  Francois Stoffelbach ,  Mostafa Taoufik ,  Jean Thivolle-Cazat

    发明人： Jean Marie Basset ,  Francois Stoffelbach ,  Mostafa Taoufik ,  Jean Thivolle-Cazat

    IPC分类号： C07C6/04

    CPC分类号： C10L1/06 ,  B01J21/04 ,  B01J31/121 ,  B01J37/0209 ,  B01J2531/66 ,  C07C6/04 ,  C07C2521/04 ,  C07C2531/12 ,  C07C11/107

    摘要： The present invention relates to a process for manufacturing neohexene, comprising contacting isobutene with a supported catalyst comprising a tungsten compound chosen from tungsten hydrides, organometallic tungsten compounds and organometallic tungsten hydrides, and a support comprising an oxide of aluminum, so as to form a reaction mixture comprising neohexene, and preferably separating neohexene from the reaction mixture, so as to isolate it. The contacting leads to the direct production of neohexene, in particular in a single (reaction) stage and with a high molar selectivity for neohexene. The contacting can be performed at a temperature of 50 to 600 ° C., under a total absolute pressure of 0.01 to 100 MPa.

    摘要翻译： 本发明涉及一种制备新己烯的方法，包括使异丁烯与包含选自氢化钨，有机金属钨化合物和有机金属氢化钨的钨化合物的负载催化剂和包含铝氧化物的载体接触，以形成反应 包含新己烯的混合物，优选从反应混合物中分离新己烯，以便将其分离。 接触导致新己烯的直接生产，特别是在单一（反应）阶段和对新己烯的高摩尔选择性。 接触可以在50〜600℃的温度下，在0.01〜100MPa的绝对压力下进行。

    New type of catalytic materials based on active metal-hydrogen-electronegative element complexes for hydrogen transfer
    7.
    发明申请
    New type of catalytic materials based on active metal-hydrogen-electronegative element complexes for hydrogen transfer 审中-公开
    基于氢转移的活性金属 - 氢 - 电负性元素络合物的新型催化材料

    公开(公告)号：US20060099127A1

    公开(公告)日：2006-05-11

    申请号：US10519644

    申请日：2003-06-25

    申请人： Alicja Zaluska ,  Leszek Zaluski

    发明人： Alicja Zaluska ,  Leszek Zaluski

    IPC分类号： C01B6/13

    CPC分类号： C01B3/0031 ,  B01J31/121 ,  B01J31/28 ,  B01J31/32 ,  B01J31/36 ,  B01J31/38 ,  B01J31/403 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0036 ,  B01J2231/60 ,  C01B3/0026 ,  C01B3/0078 ,  Y02E60/327 ,  Y02E60/328 ,  Y02P20/584

    摘要： The present invention relates to a composition of matter prepared in accordance with a method comprising the steps of: (a) combining a substance selected from the group consisting of: metal or metalloid, or an alloy thereof, or a compound thereof, or an homogeneous or inhomogeneous combination of at least two of the metal or metalloid, the alloy thereof, or the compound thereof, with a source of hydrogen, to form a first intermediate, (b) milling the first intermediate to effect reaction between the substance and the hydrogen to form a second intermediate, (c) combining the second intermediate with a source of an electronegative element, to form a third intermediate, and (d) milling the third intermediate to effect reaction between the second intermediate and the electronegative element. The composition of matter could be used as a hydrogen transfer facilitator or catalyst to enhance the kinetics of hydrogenation and dehydrogenation reactions.

    摘要翻译： 本发明涉及一种根据包括以下步骤的方法制备的物质组合物：（a）将选自以下的物质组合：金属或准金属或其合金或其化合物，或均匀的 或至少两种金属或准金属，其合金或其化合物与氢源的不均匀组合，以形成第一中间体，（b）研磨第一中间体以实现物质与氢之间的反应 形成第二中间体，（c）将第二中间体与电负性元素的源组合，形成第三中间体，和（d）研磨第三中间体以实现第二中间体与电负性元素之间的反应。 物质组成可用作氢转移促进剂或催化剂，以增强氢化和脱氢反应的动力学。

    New type of catalytic materials based on active metal-hydrogen-electronegative element complexes involving hydrogen transfer
    10.
    发明申请
    New type of catalytic materials based on active metal-hydrogen-electronegative element complexes involving hydrogen transfer 有权
    基于涉及氢转移的活性金属 - 氢 - 电负性元素络合物的新型催化材料

    公开(公告)号：US20050002856A1

    公开(公告)日：2005-01-06

    申请号：US10746742

    申请日：2003-12-24

    申请人： Alicja Zaluska ,  Leszek Zaluski

    发明人： Alicja Zaluska ,  Leszek Zaluski

    IPC分类号： B01J20/02 ,  B01J31/14 ,  B01J31/26 ,  B01J31/28 ,  B01J35/02 ,  B01J37/00 ,  B01J37/04 ,  C01B3/00 ,  C01B6/00 ,  C01B6/02 ,  C01B6/04 ,  C01B6/24 ,  H01M8/065 ,  B01J27/14 ,  B01J23/00 ,  B01J23/74 ,  B01J27/02 ,  C01B3/02

    CPC分类号： C01B3/0031 ,  B01J31/121 ,  B01J31/28 ,  B01J31/32 ,  B01J31/36 ,  B01J31/38 ,  B01J31/403 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0036 ,  B01J2231/60 ,  C01B3/0026 ,  C01B3/0078 ,  Y02E60/327 ,  Y02E60/328 ,  Y02P20/584

    摘要： The present invention relates to a hydrogen storage composition prepared in accordance with a method comprising: (a) combining (i) a metalliferous material selected from the group consisting of: (A) metal or a metalloid, or an alloy thereof, or a compound thereof, or an homogeneous or an inhomogeneous combination of at least two of a metal or a metalloid, or an alloy thereof, or a compound thereof, or (B) a hydride of any of: a metal or a metalloid, or alloy thereof, or a compound thereof, or an homogeneous or an inhomogeneous combination of a metal or a metalloid, or an alloy thereof, or a compound thereof, with ii) a liquid consisting essentially of any of: water, at least one alcohol, or a mixture of water and at least one alcohol, to form a first intermediate; and (b) milling the first intermediate for form an hydrogen transfer facilitator; (c) combining the hydrogen transfer facilitator with a second metalliferous material selected from the group consisting of: (A) a metal or a metalloid, or an alloy thereof, or a compound thereof, or an homogeneous or inhomogeneous combination of at least two of a metal or a metalloid, or an alloy thereof, or a compound thereof, or (B) a hydride of any of: a metal or a metalloid, or an alloy thereof, or a compound thereof, or an homogeneous or inhomogeneous combination of at least two of a metal or a metalloid, or an alloy thereof, or a compound thereof, such combining effecting sufficient contact between the hydrogen transfer facilitator and the second metalliferous material so that the hydrogen transfer facilitator is configured to effect absorption or desorption of hydrogen by the second metalliferous material.

    摘要翻译： 本发明涉及一种储氢组合物，该储氢组合物是根据以下方法制备的，该方法包括：（a）将（i）金属材料选自：（A）金属或准金属或其合金，或化合物 或金属或准金属或其合金或其化合物中的至少两种的均匀或不均匀的组合，或（B）以下任何一种的金属或准金属或其合金的氢化物， 或其化合物，或金属或准金属或其合金或其化合物的均匀或不均匀组合，以及ii）基本上由以下物质组成的液体：水，至少一种醇或混合物 的水和至少一种醇形成第一中间体; 和（b）研磨第一中间体以形成氢转移促进剂; （c）将氢转移促进剂与选自以下的第二含金属材料组合：（A）金属或准金属或其合金或其化合物，或其中的至少两种的均匀或不均匀组合 金属或准金属或其合金，或其化合物，或（B）以下任何一种的金属或准金属或其合金或其化合物的氢化物，或其中的均匀或不均匀组合 至少两种金属或准金属或其合金或其化合物，这种结合在氢转移促进剂和第二含金属材料之间实现充分的接触，使得氢转移促进剂被配置为通过以下方式实现氢的吸收或解吸 第二种含金属材料。