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公开(公告)号：US20060148979A1
公开(公告)日：2006-07-06
申请号：US10546362
申请日：2004-10-12
申请人： Makio Mori , Takayuki Fukutomi , Takashi Shirokawa , Tomoaki Sugiyama , Shinya Takeda , Toshiaki Masuda , Yoshiaki Shirakabe
发明人： Makio Mori , Takayuki Fukutomi , Takashi Shirokawa , Tomoaki Sugiyama , Shinya Takeda , Toshiaki Masuda , Yoshiaki Shirakabe
IPC分类号： C08L9/00
CPC分类号： C08J9/32 , B60C1/00 , B60C15/06 , B60C17/00 , C08J2321/00 , C08L21/00 , C08L33/02 , C08L33/18 , C08L2666/04
摘要： A rubber composition containing 100 parts by weight of a diene-based rubber and 0.5 to 25 parts by weight of a heat expandable microcapsule composed of a thermoplastic resin particle having a substance enclosed therein, capable of vaporizing or expanding due to heat to thereby generate a gas, wherein a shell of the heat expandable microcapsule comprises a thermoplastic resin obtained by polymerization from, as a main component of a monomer, a nitrile-based monomer (I), a monomer (II) having an unsaturated double bond and carboxyl group in the molecule thereof, a monomer (III) having two or more polymerizable double bonds and, optionally, a copolymerizable monomer (IV) for adjusting the expansion characteristics, and a pneumatic tire using the same, whereby the tire weight is decreased and the ice traction thereof is improved.
摘要翻译： 一种橡胶组合物，其含有100重量份的二烯系橡胶和0.5〜25重量份的热塑性树脂颗粒，所述热塑性树脂颗粒由其内包含的物质组成，所述热塑性树脂颗粒能够由于热而蒸发或膨胀，从而产生 气体，其中，所述热膨胀性微胶囊的壳包含由作为单体的主要成分的腈系单体（I），具有不饱和双键和羧基的单体（II）聚合得到的热塑性树脂 其分子，具有两个或多个可聚合双键的单体（III）和任选的用于调节膨胀特性的可共聚单体（IV），以及使用该单体的充气轮胎，由此轮胎重量降低，并且冰牵引力 改善了。
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公开(公告)号：US06984347B2
公开(公告)日：2006-01-10
申请号：US10923811
申请日：2004-08-24
CPC分类号： B01J13/14 , Y10T428/2987
摘要： Thermo-expansive microcapsules comprising a shell of a polymer produced by polymerizing a mixture of monomers, which comprises (I) a nitrile monomer, (II) a monomer having an unsaturated double bond and carboxyl groups in a molecule, (III) a monomer having two or more of polymerizable double bonds in a molecule, and optionally, (IV) a monomer different from and copolymerizable with the monomers (I), (II) and (III) and a blowing agent encapsulated in the shell. The volume retention of the expanded microcapsules of the thermo-expansive microcapsules is 50% or more after loaded with 15 MPa.
摘要翻译： 包含通过聚合单体混合物制备的聚合物的壳的热膨胀微胶囊，其包含（I）腈单体，（II）分子中具有不饱和双键的单体和羧基，（III）具有 分子中的两个或更多个可聚合双键，和任选地（Ⅳ）与单体（I），（II）和（III）不同且可共聚的单体和包封在壳中的发泡剂。 热膨胀微胶囊的膨胀微胶囊的体积保留率在加载15MPa后为50％以上。
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公开(公告)号：US20090105394A1
公开(公告)日：2009-04-23
申请号：US12253311
申请日：2008-10-17
申请人： Takamasa Kitamura , Makio Mori , Naoki Kushida , Toshiaki Masuda , Kenichi Kitano , Yoshiaki Shirakabe
发明人： Takamasa Kitamura , Makio Mori , Naoki Kushida , Toshiaki Masuda , Kenichi Kitano , Yoshiaki Shirakabe
IPC分类号： C08L21/00
CPC分类号： C08K9/10 , C08J9/32 , C08J2203/22 , C08J2321/00 , C08L21/00 , C08L51/00 , C08L51/003 , C08L2666/24 , C08L2666/02 , C08L2666/04
摘要： A rubber composition for a tire containing (i) 100 parts by weight of a diene-based rubber and (ii) 0.5 to 25 parts by weight of a heat-expandable microcapsule including a shell, and a substance capable of vaporizing or expanding under heating to thereby generate a gas and a nonpolar oil, both encapsulated in the shell,wherein the shell is made of a thermoplastic resin obtained by polymerization of a nitrile-based monomer (I), a monomer (II) having an unsaturated double bond and a carboxyl group in the molecule thereof, an optional monomer (III) having two or more polymerizable double bonds, and an optional copolymerizable monomer (IV) for adjusting the expansion properties.
摘要翻译： 一种轮胎用橡胶组合物，其含有（i）100重量份的二烯系橡胶和（ii）0.5〜25重量份的包含壳的热膨胀性微囊和能够在加热下蒸发或膨胀的物质 从而产生包封在壳中的气体和非极性油，其中壳由通过腈基单体（I），具有不饱和双键的单体（II）和具有不饱和双键的单体（II））聚合而获得的热塑性树脂 分子中的羧基，具有两个或更多个可聚合双键的任选单体（III）和用于调节膨胀性质的任选的可共聚单体（IV）。
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公开(公告)号：US07902265B2
公开(公告)日：2011-03-08
申请号：US12253311
申请日：2008-10-17
申请人： Takamasa Kitamura , Makio Mori , Naoki Kushida , Toshiaki Masuda , Kenichi Kitano , Yoshiaki Shirakabe
发明人： Takamasa Kitamura , Makio Mori , Naoki Kushida , Toshiaki Masuda , Kenichi Kitano , Yoshiaki Shirakabe
CPC分类号： C08K9/10 , C08J9/32 , C08J2203/22 , C08J2321/00 , C08L21/00 , C08L51/00 , C08L51/003 , C08L2666/24 , C08L2666/02 , C08L2666/04
摘要： A rubber composition for a tire containing (i) 100 parts by weight of a diene-based rubber and (ii) 0.5 to 25 parts by weight of a heat-expandable microcapsule including a shell, and a substance capable of vaporizing or expanding under heating to thereby generate a gas and a nonpolar oil, both encapsulated in the shell, wherein the shell is made of a thermoplastic resin obtained by polymerization of a nitrile-based monomer (I), a monomer (II) having an unsaturated double bond and a carboxyl group in the molecule thereof, an optional monomer (III) having two or more polymerizable double bonds, and an optional copolymerizable monomer (IV) for adjusting the expansion properties.
摘要翻译： 一种轮胎用橡胶组合物，其含有（i）100重量份的二烯系橡胶和（ii）0.5〜25重量份的包含壳的热膨胀性微囊和能够在加热下蒸发或膨胀的物质 从而产生包封在壳中的气体和非极性油，其中壳由通过腈基单体（I），具有不饱和双键的单体（II）和具有不饱和双键的单体（II））聚合而获得的热塑性树脂 分子中的羧基，具有两个或更多个可聚合双键的任选单体（III）和用于调节膨胀性质的任选的可共聚单体（IV）。
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5.发明申请公开(公告)号：US20100204349A1
公开(公告)日：2010-08-12
申请号：US12679661
申请日：2008-10-09
CPC分类号： B01J13/14 , B01J13/18 , B01J13/20 , C08J9/32 , C08J2203/22 , Y10T428/2982 , Y10T428/2998
摘要： Heat-expandable microspheres include a shell of thermoplastic resin and core material encapsulated in the shell. The core material include a blowing agent having a boiling point not higher than the softening point of the thermoplastic resin and a gas migration inhibitor having a boiling point higher than the softening point of the thermoplastic resin. The ratio of the gas migration inhibitor to the core material is at least 1 weight percent and below 30 weight percent. The average particle size of the heat-expandable microspheres ranges from 1 to 100 micrometers.
摘要翻译： 热膨胀性微球包括热塑性树脂的外壳和包封在壳中的芯材料。 核心材料包括沸点不高于热塑性树脂的软化点的发泡剂和沸点高于热塑性树脂的软化点的气体迁移抑制剂。 气体迁移抑制剂与核心材料的比例至少为1重量％且低于30重量％。 热膨胀性微球的平均粒径为1〜100微米。
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6.发明授权公开(公告)号：US08247465B2
公开(公告)日：2012-08-21
申请号：US12679661
申请日：2008-10-09
CPC分类号： B01J13/14 , B01J13/18 , B01J13/20 , C08J9/32 , C08J2203/22 , Y10T428/2982 , Y10T428/2998
摘要： Heat-expandable microspheres include a shell of thermoplastic resin and core material encapsulated in the shell. The core material include a blowing agent having a boiling point not higher than the softening point of the thermoplastic resin and a gas migration inhibitor having a boiling point higher than the softening point of the thermoplastic resin. The ratio of the gas migration inhibitor to the core material is at least 1 weight percent and below 30 weight percent. The average particle size of the heat-expandable microspheres ranges from 1 to 100 micrometers.
摘要翻译： 热膨胀性微球包括热塑性树脂的外壳和包封在壳中的芯材料。 核心材料包括沸点不高于热塑性树脂的软化点的发泡剂和沸点高于热塑性树脂的软化点的气体迁移抑制剂。 气体迁移抑制剂与核心材料的比例至少为1重量％且低于30重量％。 热膨胀性微球的平均粒径为1〜100微米。
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公开(公告)号：US20050026067A1
公开(公告)日：2005-02-03
申请号：US10923811
申请日：2004-08-24
CPC分类号： B01J13/14 , Y10T428/2987
摘要： Thermo-expansive microcapsules comprising a shell of a polymer produced by polymerizing a mixture of monomers, which comprises (I) a nitrile monomer, (II) a monomer having an unsaturated double bond and carboxyl groups in a molecule, (III) a monomer having two or more of polymerizable double bonds in a molecule, and optionally, (IV) a monomer different from and copolymerizable with the monomers (I), (II) and (III) and a blowing agent encapsulated in the shell. The volume retention of the expanded microcapsules of the thermo-expansive microcapsules is 50% or more after loaded with 15 MPa.
摘要翻译： 包含通过聚合单体混合物制备的聚合物的壳的热膨胀微胶囊，其包含（I）腈单体，（II）分子中具有不饱和双键的单体和羧基，（III）具有 分子中的两个或更多个可聚合双键，和任选地（Ⅳ）与单体（I），（II）和（III）不同且可共聚的单体和包封在壳中的发泡剂。 热膨胀微胶囊的膨胀微胶囊的体积保留率在加载15MPa后为50％以上。
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