Method of terminating oxymethylene polymerization
    1.
    发明授权
    Method of terminating oxymethylene polymerization 有权
    终止甲醛聚合的方法

    公开(公告)号:US06576740B1

    公开(公告)日:2003-06-10

    申请号:US10031124

    申请日:2002-01-09

    IPC分类号: C08F600

    CPC分类号: C08G2/06 C08G2/28

    摘要: A polyoxymethylene having enhanced thermal stability and resistance to depolymerization is obtained by using an alkylated melamine compound of formula (1) as a polymerization terminating agent in a polymerization of formaldehyde or a cyclic oligomer thereof and an optional comonomer in the presence of an acid catalyst: wherein, R1 to R6 are each independently H, C1-4 alkyl or CH2OR7; R7 is H, C1-4 alkyl or R8COOR9; R8 is —(CH2)n—, n being an integer of 1 to 4; and R9 is C1-4 alkyl.

    摘要翻译: 通过在甲酸或其环状低聚物和任选的共聚单体的聚合反应中,在酸催化剂存在下,使用式(1)的烷基化三聚氰胺化合物作为聚合终止剂获得具有增强的热稳定性和抗解聚性的聚甲醛: 其中,R 1至R 6各自独立地为H,C 1-4烷基或CH 2 OR 7; R7是H,C1-4烷基或R8COOR9; R8为 - (CH2)n-,n为1〜4的整数, 且R 9为C 1-4烷基。