公开(公告)号：US5721072A

公开(公告)日：1998-02-24

申请号：US683558

申请日：1996-07-15

申请人： Yuji Mototani ,  Yuri Kojima ,  Shigeto Noya ,  Junichi Asaoka

发明人： Yuji Mototani ,  Yuri Kojima ,  Shigeto Noya ,  Junichi Asaoka

IPC分类号： H01M4/62 ,  C22C18/00 ,  H01M4/06 ,  H01M4/24 ,  H01M4/42 ,  H01M6/06 ,  H01M6/22

CPC分类号： H01M4/244

摘要： An alkaline battery using a mercury free zinc alloy powder as an anode active material is disclosed. It has a gelled anode which comprises silicon and zinc alloy powder containing at least one of a) aluminum and b) calcium, c) bismuth in combination with calcium.

摘要翻译： 公开了一种使用无汞锌合金粉末作为负极活性材料的碱性电池。 它具有凝胶体阳极，其包含含有a）铝和b）钙，c）铋与钙的组合中的至少一种的硅和锌合金粉末。

公开(公告)号：US5587254A

公开(公告)日：1996-12-24

申请号：US419054

申请日：1995-04-07

申请人： Yuri Kojima ,  Yuji Mototani ,  Junichi Asaoka

发明人： Yuri Kojima ,  Yuji Mototani ,  Junichi Asaoka

IPC分类号： H01M4/06 ,  H01M4/62 ,  H01M6/22 ,  H01M4/24

CPC分类号： H01M6/22

摘要： Vibration and shock resistance of alkaline batteries provided with a gel type negative electrode comprising a zinc alloy powder, a gelling agent and an alkaline electrolyte can be improved by using the following three gelling agents in combination in the gel type negative electrode, namely, a crosslinked polyacrylate type water-absorbing polymer having a dispersion viscosity at 25.degree. C. of at least 15,000 cps as a 0.5 wt % aqueous solution and having a particle size of mainly 100-900 microns, a crosslinked and branched type polyacrylic acid or a salt thereof having a dispersion viscosity at 25.degree. C. of at least 15,000 cps as a 0.5 wt % aqueous solution and having a particle size of mainly 100 microns or smaller, and a granular crosslinked and branched type polyacrylic acid or a salt thereof having a dispersion viscosity at 25.degree. C. of at least 15,000 cps as 0.5 wt % aqueous solution and having a particle size of mainly 100-900 microns. The vibration and shock resistance can further be improved by further adding to the gel type negative electrode at least one of oxides, hydroxides and sulfides of a metal selected from indium, tin and bismuth.

摘要翻译： 通过在凝胶型负极中组合使用以下三种胶凝剂，即提供具有包含锌合金粉末，胶凝剂和碱性电解质的凝胶型负极的碱性电池的抗振动和抗冲击性， 聚丙烯酸酯型吸水性聚合物，其在25℃下的分散体粘度为至少15,000cps，为0.5重量％水溶液，粒径主要为100-900微米，交联和支化型聚丙烯酸或其盐 在25℃下的分散粘度为至少15,000cps，为0.5重量％水溶液，粒径为100微米以下，粒径为100μm以下的粒状交联支链型聚丙烯酸或其盐具有分散粘度 在25℃下为至少15,000厘泊，为0.5重量％水溶液，其粒径主要为100-900微米。 通过进一步向凝胶型负极添加选自铟，锡和铋的金属的氧化物，氢氧化物和硫化物中的至少一种，进一步提高了振动和抗冲击性。