公开(公告)号：US06998172B2

公开(公告)日：2006-02-14

申请号：US10064791

申请日：2002-08-16

申请人： Boris A. Movchan ,  Yuriy E. Rudoy ,  Leonella M. Nerodenko ,  Ramgopal Darolia ,  Irene Spitsberg ,  Anthony Mark Thompson ,  Curtis Alan Johnson ,  David John Wortman

发明人： Boris A. Movchan ,  Yuriy E. Rudoy ,  Leonella M. Nerodenko ,  Ramgopal Darolia ,  Irene Spitsberg ,  Anthony Mark Thompson ,  Curtis Alan Johnson ,  David John Wortman

IPC分类号： B32B3/26

CPC分类号： C23C28/3215 ,  C23C8/02 ,  C23C14/06 ,  C23C28/321 ,  C23C28/345 ,  C23C28/3455 ,  F01D5/284 ,  F01D5/288 ,  F05D2300/2118 ,  F05D2300/224 ,  F05D2300/2285 ,  Y10T428/249954 ,  Y10T428/249956 ,  Y10T428/249957 ,  Y10T428/249967 ,  Y10T428/249976 ,  Y10T428/249986 ,  Y10T428/24999

摘要： A thermal barrier coating (TBC 26) and method for forming the TBC (26) on a component (10) characterized by a stabilized microstructure that resists grain growth, sintering and pore coarsening or coalescence during high temperature excursions. The TBC (26) contains elemental carbon and/or a carbon-containing gas that increase the amount of porosity (32) initially within the TBC (26) and form additional fine closed porosity (32) within the TBC (26) during subsequent exposures to high temperatures. A first method involves incorporating elemental carbon precipitates by evaporation into the TBC microstructure. A second method is to directly incorporate an insoluble gas, such as a carbon-containing gas, into an as-deposited TBC (26) and then partially sinter the TBC (26) to entrap the gas and produce fine stable porosity within the TBC (26).

摘要翻译： 一种隔热涂层（TBC26）和在组分（10）上形成TBC（26）的方法，其特征在于稳定的微结构，其在高温偏移期间抵抗晶粒生长，烧结和孔粗化或聚结。 TBC（26）含有元素碳和/或含碳气体，其最初在TBC（26）内增加孔隙率（32），并在随后的曝光期间在TBC（26）内形成额外的细闭孔率（32） 到高温。 第一种方法包括通过蒸发将元素碳沉淀物并入到TBC微结构中。 第二种方法是直接将诸如含碳气体的不溶性气体直接掺入沉积的TBC（26）中，然后部分烧结TBC（26）以截留气体并在TBC内产生精细的稳定孔隙（ 26）。

公开(公告)号：US06808799B2

公开(公告)日：2004-10-26

申请号：US10064785

申请日：2002-08-16

申请人： Ramgopal Darolia ,  Boris A. Movchan ,  Yuriy E. Rudoy ,  Leonella M. Nerodenko ,  Irene Spitsberg ,  David John Wortman

发明人： Ramgopal Darolia ,  Boris A. Movchan ,  Yuriy E. Rudoy ,  Leonella M. Nerodenko ,  Irene Spitsberg ,  David John Wortman

IPC分类号： B32B326

CPC分类号： C23C28/3215 ,  C23C14/06 ,  C23C28/321 ,  C23C28/345 ,  C23C28/3455 ,  C23C30/00 ,  F01D5/288 ,  F05D2300/15 ,  Y10T428/249954 ,  Y10T428/249956 ,  Y10T428/249957 ,  Y10T428/249976 ,  Y10T428/24999

摘要： A thermal barrier coating, or TBC (26), and method for forming the TBC (26). The TBC (26) is formed of a thermal-insulating material that contains yttria-stabilized zirconia (YSZ) alloyed with at least a third oxide. The TBC (26) is formed to also contain elemental carbon, and may potentially contain carbides and/or a carbon-containing gas that forms from the thermal decomposition of carbon. The TBC (26) is characterized by lower density and thermal conductivity, high temperature stability and improved mechanical properties. To exhibit the desired effect, the third oxide is more particularly one that increases the lattice strain energy of the TBC microstructure as a result of having an ion size that is sufficiently different than a zirconium ion.

摘要翻译： 热障涂层或TBC（26），以及形成TBC（26）的方法。 TBC（26）由包含氧化钇稳定的氧化锆（YSZ）的绝热材料形成，其与至少三种氧化物合金化。 TBC（26）形成为也含有元素碳，并且可能含有从碳的热分解形成的碳化物和/或含碳气体。 TBC（26）的特征在于较低的密度和导热性，高温稳定性和改善的机械性能。 为了表现出期望的效果，由于具有与锆离子充分不同的离子尺寸的结果，第三氧化物更特别地增加了TBC微结构的晶格应变能。

公开(公告)号：US07087266B2

公开(公告)日：2006-08-08

申请号：US10710112

申请日：2004-06-18

申请人： Ramgopal Darolia ,  Boris A. Movchan ,  Yuriy E. Rudoy ,  Leonella M. Nerodenko ,  Irene Spitsberg ,  David John Wortman

发明人： Ramgopal Darolia ,  Boris A. Movchan ,  Yuriy E. Rudoy ,  Leonella M. Nerodenko ,  Irene Spitsberg ,  David John Wortman

IPC分类号： C23C16/32 ,  C23C16/40

CPC分类号： C23C28/3215 ,  C23C14/06 ,  C23C28/321 ,  C23C28/345 ,  C23C28/3455 ,  C23C30/00 ,  F01D5/288 ,  F05D2300/15 ,  Y10T428/249954 ,  Y10T428/249956 ,  Y10T428/249957 ,  Y10T428/249976 ,  Y10T428/24999

摘要： A thermal barrier coating, or TBC, and method for forming the TBC. The TBC is formed of a thermal-insulating material that contains yttria-stabilized zirconia (YSZ) alloyed with at least a third oxide. The TBC is formed to also contain elemental carbon, and may potentially contain carbides and/or a carbon-containing gas that forms from the thermal decomposition of carbon. The TBC is characterized by lower density and thermal conductivity, high temperature stability and improved mechanical properties. To exhibit the desired effect, the third oxide is more particularly one that increases the lattice strain energy of the TBC microstructure as a result of having an ion size that is sufficiently different than a zirconium ion.

摘要翻译： 热障涂层或TBC，以及形成TBC的方法。 TBC由含有与至少第三氧化物合金的氧化钇稳定的氧化锆（YSZ）的绝热材料形成。 TBC形成也含有元素碳，并且可能含有从碳的热分解形成的碳化物和/或含碳气体。 TBC具有较低的密度和导热性，高温稳定性和改善的机械性能。 为了表现出期望的效果，由于具有与锆离子充分不同的离子尺寸的结果，第三氧化物更特别地增加了TBC微结构的晶格应变能。