公开(公告)号：US5414065A

公开(公告)日：1995-05-09

申请号：US262981

申请日：1994-06-21

申请人： Hideo Sawada ,  Keiji Komoto ,  Masahiro Sano ,  Yutaka Enokida ,  Mitani Motohiro ,  Takeo Matsumoto ,  Masaharu Nakayama ,  Masato Okajima

发明人： Hideo Sawada ,  Keiji Komoto ,  Masahiro Sano ,  Yutaka Enokida ,  Mitani Motohiro ,  Takeo Matsumoto ,  Masaharu Nakayama ,  Masato Okajima

IPC分类号： C08F4/32 ,  C08F4/34 ,  C08F30/08

CPC分类号： C08F4/34

摘要： A polymer comprising fluoroalkyl group has a structure in which one or two parts of the fluoroalkyl group at the one or both ends of the molecule are linked to a part of alkylene groups or alkylene groups substituted with halogen, a part of alkylene group substituted with functional groups, such as halogen, cyano group, alkylsulfonic acid group, amidoalkylsulfonic acid group, carboxylic acid group, carboxyl group, oxycarbonyl group, ether group, epoxy group and the like, and/or a part of silicone group. A method of preparation of the polymer comprising fluoroalkyl group contains reaction of a fluoroalkanoyl peroxide with a monomer comprising the functional group or a monomer comprising silicone group. A surface active agent comprises fluoroalkyl group and caroxylic acid salt group. A surface treatment agent comprises the polymer comprising fluoroalkyl group, hydrolysis products thereof, hydrolytic condensation products thereof, and mixtures thereof. A coating composition comprises the polymer comprising fluoroalkyl group. The polymer comprising fluoroalkyl group has excellent water repellency, oil repellency and weatherability because the fluoroalkyl group is introduced into the molecule through carbon-carbon linkage.

摘要翻译： 包含氟烷基的聚合物具有这样的结构，其中分子的一个或两个末端的一个或两个部分的氟烷基与一部分被卤素取代的亚烷基或亚烷基连接，一部分被官能 卤素，氰基，烷基磺酸基，酰氨基烷基磺酸基，羧酸基，羧基，氧羰基，醚基，环氧基等的基团和/或硅氧烷基的一部分。 包含氟烷基的聚合物的制备方法包括氟代烷酰基过氧化物与包含官能团的单体或包含硅氧烷基团的单体的反应。 表面活性剂包括氟代烷基和羧酸盐基团。 表面处理剂包括含氟烷基的聚合物，其水解产物，其水解缩合产物及其混合物。 涂料组合物包含含氟烷基的聚合物。 包含氟烷基的聚合物由于通过碳 - 碳键将氟代烷基引入到分子中，具有优异的拒水性，拒油性和耐候性。

公开(公告)号：US5324803A

公开(公告)日：1994-06-28

申请号：US959372

申请日：1992-10-13

申请人： Hideo Sawada ,  Keiji Komoto ,  Masahiro Sano ,  Yutaka Enokida ,  Motohiro Mitani ,  Takeo Matsumoto ,  Masaharu Nakayama ,  Masato Okajima

发明人： Hideo Sawada ,  Keiji Komoto ,  Masahiro Sano ,  Yutaka Enokida ,  Motohiro Mitani ,  Takeo Matsumoto ,  Masaharu Nakayama ,  Masato Okajima

IPC分类号： C08F4/32 ,  C08F4/34 ,  C08F30/08

CPC分类号： C08F4/34

摘要： A polymer comprising fluoroalkyl group has a structure in which one or two parts of the fluoroalkyl group at the one or both ends of the molecule are linked to a part of alkylene groups or alkylene groups substituted with halogen, a part of alkylene group substituted with functional groups, such as halogen, cyano group, alkylsulfonic acid group, amidoalkylsulfonic acid group, carboxylic acid group, carboxyl group, oxycarbonyl group, ether group, epoxy group and the like, and/or a part of silicone group. A method of preparation of the polymer comprising fluoroalkyl group contains reaction of a fluoroalkanoyl peroxide with a monomer comprising the functional group or a monomer comprising silicone group. A surface active agent comprises fluoroalkyl group and caroxylic acid salt group. A surface treatment agent comprises the polymer comprising fluoroalkyl group, hydrolysis products thereof, hydrolytic condensation products thereof, and mixtures thereof. A coating composition comprises the polymer comprising fluoroalkyl group. The polymer comprising fluoroalkyl group has excellent water repellency, oil repellency and weatherability because the fluoroalkyl group is introduced into the molecule through carbon-carbon linkage.

摘要翻译： 包含氟烷基的聚合物具有这样的结构，其中分子的一端或两端的一个或两个氟代烷基部分与一部分被卤素取代的亚烷基或亚烷基连接，一部分被官能团取代的亚烷基 卤素，氰基，烷基磺酸基，酰氨基烷基磺酸基，羧酸基，羧基，氧羰基，醚基，环氧基等的基团和/或硅氧烷基的一部分。 包含氟烷基的聚合物的制备方法包括氟代烷酰基过氧化物与包含官能团的单体或包含硅氧烷基团的单体的反应。 表面活性剂包括氟代烷基和羧酸盐基团。 表面处理剂包括含氟烷基的聚合物，其水解产物，其水解缩合产物及其混合物。 涂料组合物包含含氟烷基的聚合物。 包含氟烷基的聚合物由于通过碳 - 碳键将氟代烷基引入到分子中，具有优异的拒水性，拒油性和耐候性。