公开(公告)号：US4021463A

公开(公告)日：1977-05-03

申请号：US616448

申请日：1975-09-24

Applicant: Rudolf Kummer ,  Kurt Schwirten ,  Hans-Dieter Schindler, deceased ,  by Maria Elisabeth Schindler ,  by Ute Lang ,  by Rainer Schindler, heirs-at-law

Inventor： Rudolf Kummer ,  Kurt Schwirten ,  Hans-Dieter Schindler, deceased ,  by Maria Elisabeth Schindler ,  by Ute Lang ,  by Rainer Schindler, heirs-at-law

IPC: B01J31/40 ,  B01J38/00 ,  B01J38/68 ,  C07B61/00 ,  C07C45/00 ,  C07C45/50 ,  C07C47/02 ,  C07C67/00 ,  C07F9/50 ,  C07F15/00

CPC classification number: B01J31/20 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/4038 ,  B01J31/4046 ,  B01J31/4053 ,  C07C45/50 ,  B01J2231/321 ,  B01J2531/822 ,  B01J2531/827 ,  B01J31/0201 ,  Y02P20/584

Abstract: Regeneration and separation of catalysts Me(CO)(PR.sub.3).sub.2 Hal(I) and HMe(CO)(PR.sub.3).sub.3 (II), where Me is rhodium or iridium, Hal is halogen and R denotes the same or different hydrocarbon radicals, from distillation residues of hydroformylation mixtures by treating said residues with aqueous acids and peroxides, mixing the resulting Me salt solutions with water-soluble organic solvents and with a phosphine PR.sub.3 and, in the case of the preparation of compound I, with a hydrohalic acid or an alkali metal halide, reacting the solutions at from 0.degree. to 150.degree. C. and from 1 to 250 bars in case I with carbon monoxide or compounds eliminating carbon monoxide and in case II additionally with hydrogen, and separating the resulting compound I or II.

Abstract translation: 催化剂Me（CO）（PR3）2Hal（I）和HMe（CO）（PR3）3（II）的再生​​和分离，其中Me是铑或铱，Hal是卤素，R表示相同或不同的烃基， 通过用酸和过氧化物水溶液处理所述残余物，将所得Me盐溶液与水溶性有机溶剂和磷化氢PR 3混合，并且在制备化合物I的情况下，用氢卤酸或 碱金属卤化物，在0℃至150℃和1至250巴条件下使溶液与一氧化碳或除去一氧化碳的化合物反应，另外在II情况下另外加氢，并分离所得的化合物I或II。

公开(公告)号：US4071563A

公开(公告)日：1978-01-31

申请号：US669844

申请日：1976-03-24

Applicant: Rudolf Kummer ,  Kurt Schwirten ,  Hans-Dieter Schindler, deceased ,  by Ute Lang nee Schindler, heir-at-law ,  by Rainer Schindler, heir-at-law

Inventor： Rudolf Kummer ,  Kurt Schwirten ,  Hans-Dieter Schindler, deceased ,  by Ute Lang nee Schindler, heir-at-law ,  by Rainer Schindler, heir-at-law

IPC: C07C45/49 ,  C07C45/51 ,  C07C47/20

CPC classification number: C07C45/512 ,  C07C45/49 ,  C07C45/515

Abstract: Pent-4-en-1-al is manufactured by passing an acetaldehyde-acetal of the general formula ##STR1## where R is allyl or alkyl of 1 to 3 carbon atoms, in the gas phase and at from 350.degree. to 450.degree. C, over an active-surface catalyst.

Abstract translation: Pent-4-en-1-al是通过在气相和350至450℃下通过通式为“IMAGE”的乙醛缩醛，其中R为烯丙基或1至3个碳原子的烷基 ，在活性表面催化剂上。