公开(公告)号：US20170216152A1

公开(公告)日：2017-08-03

申请号：US15324760

申请日：2015-07-07

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Reinhold Hecht ,  Manfred Ludsteck ,  Andrea Stippschild-Boxler ,  Gioacchino Raia ,  Rainer A. Guggenberger

IPC: A61K6/00 ,  A61K6/083

CPC classification number: A61K6/005 ,  A61K6/0017 ,  A61K6/0023 ,  A61K6/0038 ,  A61K6/0088 ,  A61K6/0091 ,  A61K6/02 ,  A61K6/083 ,  C08L33/08 ,  C08L33/10 ,  C08L43/02

Abstract: The present invention relates to a kit of parts comprising Part A and Part B, Part A comprising: ascorbic acid, component(s) comprising an ascorbic acid moiety or derivative(s) thereof, optionally polymerizable component(s) without acidic moieties, optionally polymerizable component(s) with acidic moieties, and optionally filler(s), Part B comprising polymerizable component(s) without acidic moieties, polymerizable component(s) with acidic moieties, transition metal component(s), organic peroxide(s), and optionally filler(s), The invention is also directed to a redox initiator system comprising ascorbic acid, component(s) comprising an ascorbic acid moiety or derivative(s) thereof, transition metal component(s), preferably comprising a copper or iron ion containing salt, organic peroxide(s), preferably comprising a hydroperoxide or di-peroxide. The kit of parts and redox initiator system are particularly useful in the dental field.

公开(公告)号：US10932994B2

公开(公告)日：2021-03-02

申请号：US15324760

申请日：2015-07-07

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Reinhold Hecht ,  Manfred Ludsteck ,  Andrea Stippschild-Boxler ,  Gioacchino Raia ,  Rainer A. Guggenberger

IPC: A61K6/887 ,  A61K6/62 ,  A61K6/30 ,  A61K6/80 ,  C08L33/10 ,  A61K6/61 ,  A61K6/20 ,  A61K6/54 ,  A61K6/76 ,  A61K6/77

Abstract: The present invention relates to a kit of parts comprising Part A and Part B, Part A comprising: ascorbic acid, component(s) comprising an ascorbic acid moiety or derivative(s) thereof, optionally polymerizable component(s) without acidic moieties, optionally polymerizable component(s) with acidic moieties, and optionally filler(s), Part B comprising polymerizable component(s) without acidic moieties, polymerizable component(s) with acidic moieties, transition metal component(s), organic peroxide(s), and optionally filler(s), The invention is also directed to a redox initiator system comprising ascorbic acid, component(s) comprising an ascorbic acid moiety or derivative(s) thereof, transition metal component(s), preferably comprising a copper or iron ion containing salt, organic peroxide(s), preferably comprising a hydroperoxide or di-peroxide. The kit of parts and redox initiator system are particularly useful in the dental field.

公开(公告)号：US20210395419A1

公开(公告)日：2021-12-23

申请号：US17292817

申请日：2019-11-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Andrea Stippschild-Boxler ,  Christoph H. Thalacker ,  Bernd Anich

IPC: C08F222/10 ,  A61K6/71 ,  A61K6/62 ,  A61K6/831 ,  A61K6/84 ,  A61C5/62 ,  C08F4/10 ,  C08F4/34

Abstract: The invention relates to a two-part dual cure dental composition with improved stability toward discoloration and premature polymerization. The dental composition comprises a Base Part and a Catalyst Part, the Base Part comprising polymerizable component(s) without an acidic moiety, optionally polymerizable component(s) with an acidic moiety, filler(s), transition metal component(s), peroxide component(s), stabilizer component(s) comprising a free-radical moiety, the Catalyst Part comprising polymerizable component(s) without an acidic moiety, filler(s), ascorbic acid component, photo-initiator system, stabilizer component(s) comprising a phosphite or sulfite moiety. The dental composition is in particular useful as bulk fill dental composite, dental resin cement, core build-up dental material or self- and dual cure dental adhesive. The invention further relates to an initiator system and the use of a stabilizer comprising a free-radical moiety.