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公开(公告)号:US12152146B2
公开(公告)日:2024-11-26
申请号:US17259015
申请日:2018-08-15
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Enzhong Zhang , Lianzhou Chen , Shaomin Sun , Xinxin Sun , Shaoqing Gu , Jianhua Tang , Jonathan D. Zook
Abstract: Disclosed is a curable composition and cured products thereof. The curable composition includes a vinyl polysiloxane component, a hydrogen polysiloxane component, a polymerization catalyst, and an expandable graphite component comprising moisture. Cured products of the curable composition include foamed cells having a uniform size and distribution in the cured product. This can help to increase the water proofing and flame retardant properties of the cured product.
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公开(公告)号:US11041049B2
公开(公告)日:2021-06-22
申请号:US16308697
申请日:2017-06-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: William H. Moser , Erik M. Townsend , Brian S. Lam , Jonathan D. Zook , Susan E. DeMoss , Sheng Ye , Andrew R. Davis , Michael D. Swan
IPC: C08G75/04 , C09J181/02 , C08G75/045 , C09K3/10 , C08G75/12 , C08L81/02 , C08G75/32 , C07D277/82 , B64C3/34 , B64C1/12 , B64C1/14
Abstract: A dual curable thiol-ene composition comprising a polythiol, an unsaturated compound, a photoinitiator, an organic hydroperoxide (thermal initiator) and optionally a nitrogen-containing base, such as e.g. an N-heterocyclic compound (together with the organic hydroperoxide a redox initiator system). A cross-linked polymer prepared therefrom. A method of making such a polymer. A cured sealant comprising such a polymer. The sealant is preferably for use in aerospace.
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公开(公告)号:US10858558B2
公开(公告)日:2020-12-08
申请号:US16340365
申请日:2017-11-03
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Erik M. Townsend , Sheng Ye , Jonathan D. Zook , Michael D. Swan
IPC: C08F2/46 , C08F2/50 , C08G61/04 , C09J181/02 , C08K5/17 , C09K3/10 , C08L81/02 , C08K5/00 , C08K5/14
Abstract: Provided are sealant compositions that include a first component and second component. The first component contains a polysulfide, a polythioether, or a copolymer or combination thereof containing pendant or terminal thiol groups, while the second in component contains an ethylenically-unsaturated compound and either the first or second component further contains a photoinitiator. Alternatively, the second component can contain a polyepoxide and either the first or second component can contain a photolatent base and a photosensitizer. The first or second component further contains a colorant that substantially reflects or substantially transmits light over the wavelength range from 350 nm to 500 nm. These compositions can provide cure-on-demand sealant formulations that comply with Class B sealant regulations on color, provide an acceptable depth of cure, and allow two-part mixing to be easily distinguishable.
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公开(公告)号:US20200347873A1
公开(公告)日:2020-11-05
申请号:US16932720
申请日:2020-07-18
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jonathan D. Zook , Larry S. Hebert , Michael D. Swan , Sheng Ye , Susan E. DeMoss , Robin E. Wright
Abstract: The present disclosure provides methods and articles useful in sealing fasteners, including seal caps and methods of their use, and in particular light weight seal caps having higher dielectric breakdown strength, lower weight, and/or lower wall thickness. In some embodiments, the seal caps according to the present invention are made of a material having a dielectric breakdown strength of greater than 1.0 kV/mm, in some embodiments greater than 15.0 kV/mm, and in some embodiments greater than 50.0 kV/mm. In some embodiments, the seal caps according to the present invention are thin-walled, having an average wall thickness of less than 1.5 mm and in some embodiments less than less than 0.5 mm. In some embodiments, the seal cap comprises a polyurethane polymer, a polythioether polymer, a polysulfide polymer, a fluorinated thermoplastic polymer, a THV polymer, a fluorinated thermoset polymer, an engineering thermoplastic, and/or a PEEK polymer.
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公开(公告)号:US20190144610A1
公开(公告)日:2019-05-16
申请号:US16308697
申请日:2017-06-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: William H. Moser , Erik M. Townsend , Brian S. Lam , Jonathan D. Zook , Susan E. DeMoss , Sheng Ye , Andrew R. Davis , Michael D. Swan
IPC: C08G75/045 , C09K3/10 , C09J181/02
Abstract: A dual curable thiol-ene composition comprising a polythiol, an unsaturated compound, a photoinitiator, an organic hydroperoxide (thermal initiator) and optionally a nitrogen-containing base, such as e.g. an N-heterocyclic compound (together with the organic hydroperoxide a redox initiator system). A cross-linked polymer prepared therefrom. A method of making such a polymer. A cured sealant comprising such a polymer. The sealant is preferably for use in aerospace.
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公开(公告)号:US20190144127A1
公开(公告)日:2019-05-16
申请号:US16245601
申请日:2019-01-11
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jonathan D. Zook , Larry S. Hebert , Michael D. Swan , Sheng Ye , Susan E. DeMoss , Robin E. Wright
Abstract: A lightning protective seal cap comprising a seal cap that defines an interior, and a quantity of an uncured sealant that is curable by the application of actinic radiation so as to bind the seal cap to a fastener. The interior of the seal cap contains the quantity of uncured sealant, the seal cap is positionable over the fastener such that at least a portion of the fastener resides in the interior of the seal cap, and when the seal cap is in position over the fastener, the sealant containing seal cap prevents electrical arcing to the fastener from a lightning strike.
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公开(公告)号:US20160069378A1
公开(公告)日:2016-03-10
申请号:US14783916
申请日:2014-04-15
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jonathan D. Zook , Larry S. Hebert , Michael D. Swan , Sheng Ye , Susan E. DeMoss , Robin E. Wright
Abstract: The present disclosure provides methods and articles useful in sealing fasteners, including seal caps and methods of their use, and in particular light weight seal caps having higher dielectric breakdown strength, lower weight, and/or lower wall thickness. In some embodiments, the seal caps according to the present invention are made of a material having a dielectric breakdown strength of greater than 1.0 kV/mm, in some embodiments greater than 15.0 kV/mm, and in some embodiments greater than 50.0 kV/mm. In some embodiments, the seal caps according to the present invention are thin-walled, having an average wall thickness of less than 1.5 mm and in some embodiments less than less than 0.5 mm In some embodiments, the seal cap comprises a polyurethane polymer, a polythioether polymer, a polysulfide polymer, a fluorinated thermoplastic polymer, a THV polymer, a fluorinated thermoset polymer, an engineering thermoplastic, and/or a PEEK polymer.
Abstract translation: 本公开提供了用于密封紧固件的方法和制品,包括密封盖及其使用方法,特别是具有较高介电击穿强度,较低重量和/或较低壁厚度的轻质密封帽。 在一些实施例中,根据本发明的密封盖由具有大于1.0kV / mm的绝缘击穿强度,在一些实施例中大于15.0kV / mm的绝缘击穿强度的材料制成,并且在一些实施例中大于50.0kV / mm 。 在一些实施例中,根据本发明的密封盖是薄壁的,其平均壁厚小于1.5mm,在一些实施例中小于0.5mm。在一些实施例中,密封帽包括聚氨酯聚合物, 聚硫醚聚合物,多硫化物聚合物,氟化热塑性聚合物,THV聚合物,氟化热固性聚合物,工程热塑性塑料和/或PEEK聚合物。
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公开(公告)号:US20140065339A1
公开(公告)日:2014-03-06
申请号:US14036024
申请日:2013-09-25
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jonathan D. Zook , Dewey L. Mullins, II , Stephane E. Pyrek , David W. A. Jordan
IPC: C09J7/02
CPC classification number: C09J7/02 , C09J7/00 , C09J7/10 , C09J7/20 , C09J2481/00 , Y10S206/813 , Y10T428/1334 , Y10T428/1352 , Y10T428/1476 , Y10T428/2835 , Y10T428/2839 , Y10T428/31533
Abstract: A uniformly premixed sealant is extruded into a packaging form and allowed to pressure equilibrate prior to freezing. Upon warming the sealant begins to cure. The storage of the preformed sealant formulation under cold conditions arrests the activity of cure catalysts and accelerators mixed therethrough. The sealant is readily extruded into a preform shape containing a lightweight filler. A release film is provided to avoid contact with the sealant preformed in a shape during application to a substrate.
Abstract translation: 将均匀预混合的密封剂挤出成包装形式,并使其在冷冻之前平衡。 加温后,密封剂开始固化。 在冷条件下将预制密封剂制剂的储存阻止了通过其混合的固化催化剂和促进剂的活性。 密封剂易于挤出成包含轻质填料的预制件形状。 提供了一种隔离膜,以避免与在施加到基底期间以形状预先形成的密封剂接触。
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公开(公告)号:US20210061483A1
公开(公告)日:2021-03-04
申请号:US17097573
申请日:2020-11-13
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jonathan D. Zook , Larry S. Hebert , Michael D. Swan , Sheng Ye , Susan E. DeMoss , Robin E. Wright
Abstract: A lightning protective seal cap comprising a seal cap that defines an interior, and a quantity of an uncured sealant that is curable by the application of actinic radiation so as to bind the seal cap to a fastener. The interior of the seal cap contains the quantity of uncured sealant, the seal cap is positionable over the fastener such that at least a portion of the fastener resides in the interior of the seal cap, and when the seal cap is in position over the fastener, the sealant containing seal cap prevents electrical arcing to the fastener from a lightning strike.
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公开(公告)号:US10815408B2
公开(公告)日:2020-10-27
申请号:US16336169
申请日:2017-10-02
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jonathan D. Zook , David A. Ylitalo , Alla Yankovsky , Audrey B. Nguyen , Susan E. DeMoss
IPC: C08L81/04 , C09K3/10 , C08G75/14 , C09J181/04 , C08G75/02
Abstract: Provided are two-component curable compositions and methods thereof. The composition includes a base component comprised of a curable resin and a first compressible filler dispersed therein. The composition further includes a curative component comprised of a curing agent and a second compressible filler dispersed therein. The base and curative components react with each other upon mixing to provide a crosslinked network. When used with automated metering pumps, the compressibility of the base and curing agent components can be matched, allowing for a constant mix ratio despite variability in applied pressure.
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