Process for the preparation of n,n{40 -di-1-anthraquinonylphthalamide
    1.
    发明授权
    Process for the preparation of n,n{40 -di-1-anthraquinonylphthalamide 失效
    制备N,N {40 -DI-1-四氢喹啉酰胺的方法

    公开(公告)号:US3668225A

    公开(公告)日:1972-06-06

    申请号:US3668225D

    申请日:1969-05-06

    Applicant: ALLIED CHEM

    CPC classification number: C09B1/43

    Abstract: Reaction of a phthalic anhydride with an aminoanthraquinone in the presence of phosphorus oxychloride and/or phosphorus trichloride with perchloroethylene as solvent affords N,N''-dianthraquinonylphthalamide pigment in high yield and in easily isolatable form. In the preparation of N,N''-di-1anthraquinonylphthalamide, presence of an ''''active oxygen''''containing compound in the reaction medium affords a reddishyellow alpha polymorph; absence of an ''''active oxygen''''containing compound affords a novel greenish-yellow beta polymorph.

    Abstract translation: 在磷酰氯和/或三氯化磷与全氯乙烯作为溶剂的存在下,邻苯二甲酸酐与氨基蒽醌的反应以高产率和容易分离的形式提供N,N'-二蒽醌基邻苯二甲酰胺颜料。 在制备N,N'-二-1-蒽醌基邻苯二甲酰胺时,在反应介质中存在“含活性氧”的化合物,得到红黄色的α多晶型物; 不含“活性氧”的化合物提供了一种新的绿黄色β多晶型物。

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