公开(公告)号：US3483164A

公开(公告)日：1969-12-09

申请号：US3483164D

申请日：1965-10-21

Applicant: ALLIED CHEM

Inventor： BARTON OLIVER A ,  GRIFFIN WILLIAM D ,  LUND RICHARD B ,  VITRONE JOHN ,  OSER ZALIK

IPC: C07C37/16 ,  C07C37/62 ,  C08G59/08 ,  C08G59/32 ,  C08G30/04

CPC classification number: C07C37/16 ,  C07C37/62 ,  C08G59/08 ,  C08G59/3218 ,  C07C39/15 ,  C07C39/367

公开(公告)号：US3567786A

公开(公告)日：1971-03-02

申请号：US3567786D

申请日：1967-07-31

Applicant: ALLIED CHEM

Inventor： BOSTIAN LOGAN C ,  GRIFFIN WILLIAM D ,  OSER ZALIK

IPC: C07C29/50 ,  C07C31/14 ,  C07C73/06

CPC classification number: C07C29/50 ,  C07C33/20

Abstract: THE PRODUCTION OF TERTIARY ALCOHOLS BY OXIDIZING A TERTIARY ALIPHATIC CARBON ATOM IN ANORGANIC COMPOUND IN WHICH SAID TERTIARY CARBON ATOM IS ATTACHED TO ONE CARBON OF A CARBOCYCLIC ARYL NUCLEUS, TO ONE HYDROGEN ATOM, TO TWO OTHER SATURATED CARBON ATOMS EACH IN TURN ATTCHED ONLY TO A MEMBER OF THE GROUP CONSISTING OF CARBON ATOMS AND HYDROGEN ATOMS, IN LIQUID PHASE WITH A GAS CONTAINING ELEMENTAL OXYGEN AND WITH AQUEOUS CAUSTIC OF THE GROUP CONSISTING OF SODIUM HYDROXIDE AND POTASSIUM HYDROXIDE IN CONCENTRATIONS OF ABOUT 40-90 WEIGHT PERCENT IN THE AQUEOUS SOLUTION AND IN PROPORTIONS OF ABOUT 20-400 GRAMS OF THE AQUEOUS CAUSTIC SOLUTION PER 100 ML. OF THE COMPOUNDS, AT TEMPERATURES IN THE RANGE OF ABOUT 100* C.-300*C.