公开(公告)号：US3692885A

公开(公告)日：1972-09-19

申请号：US3692885D

申请日：1969-08-14

Applicant: ALLIED CHEM

Inventor： ANELLO LOUIS G ,  SWEENEY RICHARD F ,  JONES EDWARD S ,  WALSH JOHN T ,  THOMPSON JOHN J JR

IPC: C07F9/09 ,  C07F9/14 ,  C07F9/24 ,  D06M13/292 ,  C07F9/08 ,  D21H1/38

CPC classification number: D06M13/292 ,  C07F9/091 ,  C07F9/14 ,  C07F9/2408

Abstract: This invention relates to novel phosphate esters of the formula

WHEREIN A. R1-R4 are independently fluorine, chlorine or alkyl or haloalkyl groups of one to 10 carbon atoms; B. A is a radical of the formula -(CFR5-CR6R7)- in which R5 and R6 are independently fluorine or hydrogen, and R7 is hydrogen, fluorine, chlorine, bromine or perfluoroalkyl; C. X1-X4 are independently hydrogen, fluorine, chlorine or bromine, provided that X1-X4 do not include more than two chlorine atoms or one bromine atom; D. Z is selected from the group consisting of chlorine, hydroxy, amino, substituted amino and OY wherein Y is a hydrocarbyl or hydroxy-substituted hydrocarbyl, or a water solubilizing cationic ion. E. M IS AN INTEGER FROM 1 TO 10, N IS AN INTEGER FROM 0 TO 10 AND W IS AN INTEGER FROM 1 TO 3. Said phosphate esters are useful for imparting oil and stain repellent properties to various materials, especially to paper.

Abstract translation: 本发明涉及新颖的式（A）的磷酸酯。R1-R4独立地是氟，氯或1-10个碳原子的烷基或卤代烷基; B.A是式（CFR 5 -CR 6 R 7） - 的基团，其中R 5和R 6独立地是氟或氢，并且R 7是氢，氟，氯，溴或全氟烷基; X1-X4独立地是氢，氟，氯或溴，条件是X1-X4不包括两个以上氯原子或一个溴原子; D.Z选自氯，羟基，氨基，取代的氨基和OY，其中Y是烃基或羟基取代的烃基，或水溶性阳离子离子。