摘要:
A method for providing hydrogen gas includes providing a liquid hydrogen carrier material, removing oxygen-carrying and/or sulfur-carrying and/or halogen-containing components from the liquid hydrogen carrier material, releasing hydrogen gas by catalytic dehydrogenation of the purified hydrogen carrier material, and conditioning the released hydrogen gas.
摘要:
A process of treating a feed in an adsorption separation zone comprising at least two adsorbent beds and a trim bed is disclosed. The process comprises displacing feed from a first adsorbent bed to a trim bed by feeding a desorbent from a second adsorbent bed to the first adsorbent bed while displacing spent desorbent from the trim bed. After discontinuing the first adsorbent bed displacement, an adsorber trim fluid to the first adsorbent bed to recover the remaining treated feed in the head. After discontinuing adsorber trim fluid to the first adsorbent bed; a trim displacement fluid is passed to the trim bed to displace feed from the trim bed.
摘要:
Embodiments of the present disclosure describe a metal-organic framework (MOF) composition comprising a plurality of metal clusters, wherein the metal is chromium; and one or more tetratopic ligands; wherein the metal clusters and ligands associate to form a MOF with soc topology. A method of making a MOF comprising contacting a template MOF of formula Fe-soc-MOF and a reactant including chromium in a presence of dimethylformamide sufficient to replace Fe with Cr and form an exchanged MOF of formula Cr-soc-MOF. A method of sorbing water vapor comprising exposing a Cr-soc-MOF to an environment; and sorbing water vapor using the Cr-soc-MOF.
摘要:
A process is provided to remove impurities including water, mercaptans, carbonyl sulfide and hydrogen sulfide from hydrocarbon streams containing from 100 to 900 ppm light olefins. In the process, a compound bed containing multiple layers of molecular sieves is used to remove the specific impurities. In situations when the regeneration gas may contain sulfur compounds, a sulfur guard bed may be used to treat the regeneration gas prior to regenerating the compound adsorbent bed.
摘要:
Disclosed is a process for the regeneration of an adsorber (A1). The adsorber (A1) is regenerated by contact with a gaseous stream (S2) and the outflow of the adsorber (A1) comprising condensate of stream (S2) and organic composition (OC1) collected in a device. After regeneration of the adsorber (A1) the stream (S2) in the adsorber (A1) is replaced completely or at least partially by the content of the device. Then the adsorber (A1) is fed with organic composition comprising at least one olefin, at least one alkane and at least one compound containing oxygen and/or sulfur.
摘要:
Disclosed is an improved process for recovering condensable components from a gas stream, in particular, hydrocarbons from a gas stream such as natural gas. The present process uses solid adsorbent media to remove said hydrocarbons wherein the adsorbent media is regenerated in a continuous fashion in a heated continuous counter-current regeneration system, wherein said heated regenerated adsorbent media is cooled prior to reuse.
摘要:
Disclosed are embodiments of a method of regenerating a desiccant in an off-line treater of a polyolefin production process. The method may include a heating phase followed by a cooling phase. The heating phase may involve use of a regenerating gas made from heating a treated a recycle stream of the polyolefin production process to regenerate desiccant in an off-line treater. The cooling phase may involve thermosyphoning the regenerating gas, nitrogen, an olefin-free diluent, or combinations thereof in a closed-convection loop of the off-line treater.
摘要:
Method for treating water by filtration on a bed of granular material in order to reduce its content in contaminants, said method comprising the steps for: making said water travel in transit in a reactor containing said bed in a upward flow at a speed that does not permit the fluidization of said bed but permits said material to migrate, as and when the filtration takes place, towards the lower part of said reactor, continuously removing a fouled granular material at the foot of the reactor, by means of a piping into which a gas is insufflated, said fouled granular material being constituted by granular material and contaminants adsorbed on said granular material; continuously or intermittently carrying out the physical cleansing of said fouled granular material thus removed, so as to obtain a cleansed granular material essentially rid of said contaminants; reinjecting the granular material thus cleansed into an upper part of said bed; characterized in that the granular material is an adsorbent granular material and in that it comprises: a continuous or intermittent step for the discharging, during the filtration, of a part of the fouled granular material removed at the foot of the reactor; and a continuous or intermittent step for the introduction into the reactor, during the filtration, of fresh granular material in a quantity sufficient to compensate for the part of granular material discharged.
摘要:
The present invention relates to systems and methods for regenerating β-cyclodextrin (β-CD) adsorbent after it has been used in a water decontamination process. The regeneration process of the present invention is based on treating β-CD with ozone gas, i.e., ozonation. In one embodiment, the regeneration process of the present invention comprises the steps of providing a β-CD adsorbent that has been used in a water decontamination process and removing at least a portion of the contaminants from the β-CD adsorbent by contacting the contaminants bound to the β-CD adsorbent with a gas comprising ozone.