公开(公告)号：US09580352B2

公开(公告)日：2017-02-28

申请号：US14685953

申请日：2015-04-14

Applicant: AvanStrate Inc.

Inventor： Akihiro Koyama ,  Satoshi Ami ,  Manabu Ichikawa

IPC: C03C3/091 ,  C03B25/00

CPC classification number: C03C3/091 ,  C03B25/00

Abstract: A substrate for p-Si TFT flat panel displays made of a glass having a high low-temperature-viscosity characteristic temperature and manufactured while avoiding erosion/wear of a melting tank during melting through direct electrical heating. The glass substrate comprises 52-78 mass % of SiO2, 3-25 mass % of Al2O3, 3-15 mass % of B2O3, 3-20 mass % of RO, wherein RO is total amount of MgO, CaO, SrO, and BaO, 0.01-0.8 mass % of R2O, wherein R2O is total amount of Li2O, Na2O, and K2O, and 0-0.3 mass % of Sb2O3, and substantially does not comprise As2O3, wherein the mass ratio CaO/RO is equal to or greater than 0.65, the mass ratio (SiO2+Al2O3)/B2O3 is in a range of 7-30, and the mass ratio (SiO2+Al2O3)/RO is equal to or greater than 5. A related method involves melting glass raw materials blended to provide the glass composition; a forming step of forming the molten glass into a flat-plate glass; and an annealing step of annealing the flat-plate glass.

Abstract translation: 一种由具有高低温粘度特性温度的玻璃制成的p-Si TFT平板显示器基板，并且在通过直接电加热熔化期间避免熔化槽的侵蚀/磨损而制造。 所述玻璃基板包含52-78质量％的SiO 2，3-25质量％的Al 2 O 3，3-15质量％的B 2 O 3，3-20质量％的RO，其中RO是MgO，CaO，SrO和BaO的总量 ，0.01-0.8质量％的R 2 O，其中，R 2 O为Li 2 O，Na 2 O，K 2 O的总量，Sb 2 O 3为0〜0.3质量％，基本上不包含As 2 O 3，CaO / （SiO2 + Al2O3）/ B2O3的质量比（SiO 2 + Al 2 O 3）/ B 2 O 3在7〜30的范围内，质量比（SiO 2 + Al 2 O 3）/ RO等于或大于5.相关方法包括将玻璃原料混合 提供玻璃组成; 将熔融玻璃形成平板玻璃的成形工序; 以及退火平板玻璃的退火步骤。

公开(公告)号：US09321671B2

公开(公告)日：2016-04-26

申请号：US14277822

申请日：2014-05-15

Applicant: AvanStrate Inc.

Inventor： Akihiro Koyama ,  Satoshi Ami ,  Manabu Ichikawa

IPC: C03C3/091 ,  C03C3/093 ,  G02F1/1333

CPC classification number: C03C3/091 ,  C03C3/093 ,  G02F2001/133302 ,  G02F2202/104

Abstract: A glass substrate for p-Si TFT flat panel displays that is composed of a glass comprising 52-78 mass % of SiO2, 3-25 mass % of Al2O3, 3-15 mass % of B2O3, 3-25 mass % of RO, wherein RO is total amount of MgO, CaO, SrO, and BaO, 0.01-1 mass % of Fe2O3, and 0-0.3 mass % of Sb2O3, and substantially not comprising As2O3, the glass having a mass ratio (SiO2+Al2O3)/B2O3 in a range of 7-30 and a mass ratio (SiO2+Al2O3)/RO equal to or greater than 6. A method for manufacturing a glass substrate involves: a melting step of obtaining a molten glass by melting, by employing at least direct electrical heating, glass raw materials blended so as to provide the aforementioned glass composition; a forming step of forming the molten glass into a flat-plate glass; and an annealing step of annealing the flat-plate glass.

Abstract translation: 一种用于p-Si TFT平板显示器的玻璃基板，由玻璃构成，包括SiO 2为52-78质量％，Al 2 O 3为3〜25质量％，B 2为3〜15质量％，RO为3〜25质量％ 其中RO为MgO，CaO，SrO和BaO的总量，Fe2O3为0.01-1质量％，Sb2O3为0-0.3质量％，并且实质上不包含As2O3，玻璃的质量比（SiO 2 + Al 2 O 3）/ B2O3的范围为7〜30，质量比（SiO 2 + Al 2 O 3）/ RO为6以上。玻璃基板的制造方法包括：熔融步骤，通过熔融获得熔融玻璃，至少使用 直接电加热，玻璃原料混合以提供上述玻璃组合物; 将熔融玻璃形成平板玻璃的成形工序; 以及退火平板玻璃的退火步骤。

公开(公告)号：US09242890B2

公开(公告)日：2016-01-26

申请号：US14015495

申请日：2013-08-30

Applicant: AvanStrate Inc.

Inventor： Akihiro Koyama ,  Mikiko Hashimoto

IPC: C03C3/091

CPC classification number: C03C3/091

Abstract: Provided is a glass composition suitable for a glass substrate for a flat panel display such as a liquid crystal display. This glass composition has high thermal stability, and is substantially free of BaO but has a low devitrification temperature. It is suitable for the production of a glass substrate by a downdraw process. This glass composition contains, in terms of mass %: 54 to 62% of SiO2; 4 to 11% of B2O3; 15 to 20% of Al2O3; 2 to 5% of MgO; 0 to 7% of CaO; 0 to 13.5% of SrO; 0 to 1% of K2O; 0 to 1% of SnO2; and 0 to 0.2% of Fe2O3, and is substantially free of BaO. In this glass composition, the total content of alkaline earth metal oxides (MgO+CaO +SrO) is 10 to 18.5 mass %. The devitrification temperature of the glass composition is 1200° C. or lower.

Abstract translation: 提供一种适用于液晶显示器等平板显示器的玻璃基板的玻璃组合物。 该玻璃组合物具有高的热稳定性，并且基本上不含BaO但具有低失透温度。 适用于通过下拉工艺生产玻璃基板。 该玻璃组合物以质量％计含有54〜62％的SiO 2， 4〜11％的B2O3; 15〜20％的Al2O3; 2〜5％的MgO; 0〜7％的CaO; 0〜13.5％的SrO; 0〜1％K2O; 0〜1％的SnO2; 和0〜0.2％的Fe 2 O 3，并且基本上不含BaO。 在该玻璃组合物中，碱土类金属氧化物（MgO + CaO + SrO）的总含量为10〜18.5质量％。 玻璃组合物的失透温度为1200℃以下。

公开(公告)号：US09469564B2

公开(公告)日：2016-10-18

申请号：US14276843

申请日：2014-05-13

Applicant: AvanStrate Inc.

Inventor： Akihiro Koyama ,  Satoshi Ami ,  Manabu Ichikawa

IPC: C03C3/085 ,  C03C3/091 ,  C03C3/093 ,  H01L51/00 ,  G02F1/1333

CPC classification number: C03C3/091 ,  C03C3/093 ,  G02F2001/133302 ,  H01L51/0096

Abstract: A flat panel display glass substrate according to the present invention includes a glass comprising, as expressed in mol %, 55-80% SiO2, 3-20% Al2O3, 3-15% B2O3, 3-25% RO (the total amount of MgO, CaO, SrO, and BaO), and substantially no As2O3, and Sb2O3. The devitrification temperature of the glass is 1250° C. or less. The glass substrate has a heat shrinkage rate of 75 ppm or less. The heat shrinkage rate is calculated from the amount of shrinkage of the glass substrate measured after a heat treatment which is performed at a temperature rising and falling rate of 10° C./min and at 550° C. for 2 hours by the heat shrinkage rate (ppm)={the amount of shrinkage of the glass substrate after the heat treatment/the length of the glass substrate before the heat treatment}×106.

Abstract translation: 根据本发明的平板显示器玻璃基板包括玻璃，其以摩尔％表示，为55-80％SiO 2，3-20％Al 2 O 3，3-15％B 2 O 3，3-25％RO（总量 MgO，CaO，SrO和BaO），并且基本上不含As2O3和Sb2O3。 玻璃的失透温度为1250℃以下。 玻璃基板的热收缩率为75ppm以下。 热收缩率由热处理后测定的玻璃基板的收缩量，以10℃/分钟和550℃的升温和降温率，通过热收缩率进行2小时计算 速率（ppm）= {热处理后的玻璃基板的收缩量/热处理前的玻璃基板的长度}×106。

公开(公告)号：US20140031192A1

公开(公告)日：2014-01-30

申请号：US13744537

申请日：2013-01-18

Applicant: AVANSTRATE, INC.

Inventor： Junji Kurachi ,  Akihiro Koyama ,  Yoichi Hachitani

IPC: C03C3/091

CPC classification number: C03C3/091 ,  Y10T428/1095

Abstract: A glass substrate for a display, which is formed of a glass having a light weight and having high refinability with decreasing environmental burdens, the glass comprising, by mass %, 50 to 70% of SiO2, 5 to 18% of B2O3, 10 to 25% of Al2O3, 0 to 10% of MgO, 0 to 20% of CaO, 0 to 20% of SrO, 0 to 10% of BaO, 5 to 20% of RO (in which R is at least one member selected from the group consisting of Mg, Ca, Sr and Ba), and over 0.20% but not more than 2.0% of R′2O (in which R′ is at least one member selected from the group consisting of Li, Na and K), and containing, by mass %, 0.05 to 1.5% of oxide of metal that changes in valence number in a molten glass, and substantially containing none of As2O3, Sb2O3 and PbO.

Abstract translation: 一种显示器用玻璃基板，其由重量轻且具有降低的环境负荷的高可熔性的玻璃形成，所述玻璃以质量％计含有50〜70％的SiO 2，5〜18％的B 2 O 3，10〜 25％的Al 2 O 3，0〜10％的MgO，0〜20％的CaO，0〜20％的SrO，0〜10％的BaO，5〜20％的RO（其中R为选自 由Mg，Ca，Sr和Ba组成的组）和超过0.20％但不超过2.0％的R'2O（其中R'为选自Li，Na和K中的至少一种）， 并且以质量％计含有熔融玻璃中价数变化的金属氧化物的0.05〜1.5％，并且基本上不含有As 2 O 3，Sb 2 O 3和PbO。

公开(公告)号：US10927034B2

公开(公告)日：2021-02-23

申请号：US15740909

申请日：2016-06-28

Applicant: AvanStrate Inc.

Inventor： Manabu Ichikawa ,  Akihiro Koyama

IPC: C03C3/085 ,  C03C3/087 ,  C03C3/091 ,  C03C3/093 ,  C03B25/04 ,  C03B25/08 ,  G02F1/1368 ,  G02F1/1333

Abstract: A glass substrate that achieves a high strain point while having a low devitrification temperature; and a method for producing the glass substrate. This glass substrate for a display is made of a glass comprising SiO2 and Al2O3, comprising 0% or more to less than 4% B2O3 in mass %, and substantially devoiding Sb2O3, wherein 3×BaO/(MgO+CaO+SrO) is 5 or less, MgO/(CaO+SrO) is 0.36 or greater, the devitrification temperature is 1235° C. or lower, and the strain point is 700° C. or higher. The method comprises: melting, by using at least direct electrical heating, a glass material prepared to have a predetermined composition; forming, into a flat glass sheet, the molten glass that has been melted in the melting step; and annealing the flat glass sheet, wherein a condition for cooling the flat glass sheet is controlled so as to reduce the heat shrinkage rate of the flat glass sheet.

公开(公告)号：US09278880B2

公开(公告)日：2016-03-08

申请号：US14277822

申请日：2014-05-15

Applicant: AvanStrate Inc.

Inventor： Akihiro Koyama ,  Satoshi Ami ,  Manabu Ichikawa

IPC: C03C3/091 ,  C03C3/093 ,  G02F1/1333

Abstract: A glass substrate for p-Si TFT flat panel displays that is composed of a glass comprising 52-78 mass % of SiO2, 3-25 mass % of Al2O3, 3-15 mass % of B2O3, 3-25 mass % of RO, wherein RO is total amount of MgO, CaO, SrO, and BaO, 0.01-1 mass % of Fe2O3, and 0-0.3 mass % of Sb2O3, and substantially not comprising As2O3, the glass having a mass ratio (SiO2+Al2O3)/B2O3 in a range of 7-30 and a mass ratio (SiO2+Al2O3)/RO equal to or greater than 6. A method for manufacturing a glass substrate involves: a melting step of obtaining a molten glass by melting, by employing at least direct electrical heating, glass raw materials blended so as to provide the aforementioned glass composition; a forming step of forming the molten glass into a flat-plate glass; and an annealing step of annealing the flat-plate glass.

公开(公告)号：US08741794B2

公开(公告)日：2014-06-03

申请号：US13744537

申请日：2013-01-18

Applicant: Avanstrate, Inc.

Inventor： Junji Kurachi ,  Akihiro Koyama ,  Yoichi Hachitani

IPC: C03C3/091

CPC classification number: C03C3/091 ,  Y10T428/1095

Abstract: A glass substrate for a display, which is formed of a glass having a light weight and having high refinability with decreasing environmental burdens, the glass comprising, by mass %, 50 to 70% of SiO2, 5 to 18% of B2O3, 10 to 25% of Al2O3, 0 to 10% of MgO, 0 to 20% of CaO, 0 to 20% of SrO, 0 to 10% of BaO, 5 to 20% of RO (in which R is at least one member selected from the group consisting of Mg, Ca, Sr and Ba), and over 0.20% but not more than 2.0% of R′2O (in which R′ is at least one member selected from the group consisting of Li, Na and K), and containing, by mass %, 0.05 to 1.5% of oxide of metal that changes in valence number in a molten glass, and substantially containing none of As2O3, Sb2O3 and PbO.

Abstract translation: 一种显示器用玻璃基板，其由重量轻且具有降低的环境负荷的高可熔性的玻璃形成，所述玻璃以质量％计含有50〜70％的SiO 2，5〜18％的B 2 O 3，10〜 25％的Al 2 O 3，0〜10％的MgO，0〜20％的CaO，0〜20％的SrO，0〜10％的BaO，5〜20％的RO（其中R为选自 由Mg，Ca，Sr和Ba组成的组）和超过0.20％但不超过2.0％的R'2O（其中R'为选自Li，Na和K中的至少一种）， 并且以质量％计含有熔融玻璃中价数变化的金属氧化物的0.05〜1.5％，并且基本上不含有As 2 O 3，Sb 2 O 3和PbO。