公开(公告)号：US20090281211A1

公开(公告)日：2009-11-12

申请号：US12296457

申请日：2007-12-18

申请人： Adrie A. Van Der Huizen ,  Marc S. Sonderman ,  Arwin W. Van Der Waal ,  Wouter De Jong ,  Anton Nicolai

发明人： Adrie A. Van Der Huizen ,  Marc S. Sonderman ,  Arwin W. Van Der Waal ,  Wouter De Jong ,  Anton Nicolai

IPC分类号： C04B24/28

CPC分类号： C08J3/07 ,  C08J2309/00 ,  Y10S516/925

摘要： A process of producing an artificial latex, comprising the steps: (a) cement formation, wherein a rubber is dissolved in a suitable hydrocarbon solvent; (b) emulsification of the cement formed in step (a), together with an aqueous soap solution, thus forming an oil-in-water emulsion; (c) hydrocarbon solvent removal, resulting in a latex of the rubber having particles of a median particle size in the range of from about 0.5 to 2.0 μm, and optionally (d) latex concentration, forming an artificial latex with a higher solids content, characterized in that in step (b) a premix is formed first, which is subsequently homogenized into an oil-in-water emulsion, and wherein the premix is formed by mixing the cement with the aqueous soap solution at a volume ratio of 1:1.5 to 1:3 using at least one homogenizer comprising a stator and a rotor, that is operated at a tip speed of the outer ring of the rotor in the range of from 8 to 16 m/s, and wherein the premix is subsequently homogenized in a rotor/stator homogenizer operated at a tip speed of the outer ring of the rotor in the range of from 16 to 35 m/s.

摘要翻译： 一种制造人造胶乳的方法，包括以下步骤：（a）水泥形成，其中将橡胶溶解在合适的烃溶剂中; （b）将步骤（a）中形成的粘固剂与皂水溶液一起乳化，从而形成水包油乳液; （c）烃溶剂去除，得到具有中等粒度在约0.5至2.0μm范围内的颗粒的橡胶胶乳和任选的（d）胶乳浓度，形成具有较高固体含量的人造胶乳， 其特征在于，在步骤（b）中首先形成预混物，随后将其均化为水包油乳液，并且其中通过以1:1的体积比将水泥与水性皂溶液混合而形成预混物 使用至少一种包括定子和转子的均化器，其在转子的外圈的尖端速度下在8至16m / s的范围内操作，并且其中将预混合物随后均化为 转子/定子匀浆器以转子外圈的尖端速度在16至35m / s的范围内操作。

公开(公告)号：US08163838B2

公开(公告)日：2012-04-24

申请号：US12296457

申请日：2007-12-18

申请人： Adrie A. Van Der Huizen ,  Marc S. Sonderman ,  Arwin W. Van Der Waal ,  Wouter De Jong ,  Anton Nicolai

发明人： Adrie A. Van Der Huizen ,  Marc S. Sonderman ,  Arwin W. Van Der Waal ,  Wouter De Jong ,  Anton Nicolai

IPC分类号： C04B24/28

CPC分类号： C08J3/07 ,  C08J2309/00 ,  Y10S516/925

摘要： A process of producing an artificial latex, comprising the steps: (a) cement formation, wherein a rubber is dissolved in a suitable hydrocarbon solvent; (b) emulsification of the cement formed in step (a), together with an aqueous soap solution, thus forming an oil-in-water emulsion; (c) hydrocarbon solvent removal, resulting in a latex of the rubber having particles of a median particle size in the range of from about 0.5 to 2.0 μm, and optionally (d) latex concentration, forming an artificial latex with a higher solids content, characterized in that in step (b) a premix is formed first, which is subsequently homogenized into an oil-in-water emulsion, and wherein the premix is formed by mixing the cement with the aqueous soap solution at a volume ratio of 1:1.5 to 1:3 using at least one homogenizer comprising a stator and a rotor, that is operated at a tip speed of the outer ring of the rotor in the range of from 8 to 16 m/s, and wherein the premix is subsequently homogenized in a rotor/stator homogenizer operated at a tip speed of the outer ring of the rotor in the range of from 16 to 35 m/s.

摘要翻译： 一种制造人造胶乳的方法，包括以下步骤：（a）水泥形成，其中将橡胶溶解在合适的烃溶剂中; （b）将步骤（a）中形成的粘固剂与皂水溶液一起乳化，从而形成水包油乳液; （c）烃溶剂去除，得到具有中值粒度在约0.5-2.0μm范围内的颗粒的橡胶胶乳和任选的（d）胶乳浓度，形成具有较高固体含量的人造胶乳， 其特征在于，在步骤（b）中首先形成预混物，随后将其均化为水包油乳液，并且其中通过以1:1的体积比将水泥与水性皂溶液混合而形成预混物 使用至少一种包括定子和转子的均化器，其在转子的外圈的尖端速度下在8至16m / s的范围内操作，并且其中将预混合物随后均化为 转子/定子匀浆器以转子外圈的尖端速度在16至35m / s的范围内操作。

公开(公告)号：US20090209698A1

公开(公告)日：2009-08-20

申请号：US12293491

申请日：2007-03-26

申请人： Adrie A. Van Der Huizen ,  Jean Furton ,  Arwin W. Van Der Waal

发明人： Adrie A. Van Der Huizen ,  Jean Furton ,  Arwin W. Van Der Waal

IPC分类号： C08L9/10

CPC分类号： C08J3/07 ,  C08J2307/00 ,  C08J2321/00

摘要： A process for the preparation of an aqueous rubber emulsion (artificial latex), comprising the steps: (a) size reduction of the rubber, whereby granules are produces with shorter dissolving time; (b) cement formation, wherein the granules of step (a) are dissolved in a suitable hydrocarbon solvent; (c) preparation of an aqueous soap solution; (d) emulsification of the cement formed in step (b), using the aqueous soap solution prepared in step (c), thus forming an oil in water emulsion; (e) hydrocarbon solvent removal, resulting in an aqueous emulsion of the rubber, and optionally (f) emulsion concentration, forming an artificial latex with a higher solids content, wherein in step (a) the size reduction is carried out using a chopper and/or granulator characterized in that a soap is used as processing aid, preferably identical to the soap used in steps (c) and (d).

摘要翻译： 一种制备水性橡胶乳液（人造胶乳）的方法，包括以下步骤：（a）缩小橡胶的尺寸，由此产生具有较短溶解时间的颗粒; （b）水泥形成，其中步骤（a）的颗粒溶解在合适的烃溶剂中; （c）制备肥皂水溶液; （d）使用步骤（c）中制备的水性皂溶液使步骤（b）中形成的水​​泥乳化，从而形成水包油乳液; （e）烃溶剂去除，得到橡胶的水性乳液，和任选地（f）乳液浓缩，形成具有较高固体含量的人造胶乳，其中在步骤（a）中，使用切碎机进行尺寸减小， /或造粒机，其特征在于使用肥皂作为加工助剂，优选与步骤（c）和（d）中使用的皂相同。