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公开(公告)号：US07611631B2
公开(公告)日：2009-11-03
申请号：US11631898
申请日：2005-07-07
申请人： Akifusai Ohnishi , Nobuaki Fujiwara , Hideki Doi , Toyokazu Matsunami , Hiroshi Tsubota , Toshiaki Muratani , Shoji Nishikawa , Shinichi Yamasaki , Takamichi Honma
发明人： Akifusai Ohnishi , Nobuaki Fujiwara , Hideki Doi , Toyokazu Matsunami , Hiroshi Tsubota , Toshiaki Muratani , Shoji Nishikawa , Shinichi Yamasaki , Takamichi Honma
CPC分类号： C22B58/00 , B01J20/26 , B01J20/261 , B01J41/04 , B01J41/14 , C22B3/42 , Y02P10/234
摘要： The invention provides an indium adsorbent that can cause indium to be adsorbed, and a simple and inexpensive indium fractioning method for isolating and recovering high-purity indium from an acid solution whose primary component is hydrochloric acid and that contains indium. A primary component of the indium adsorbent is an anion-exchange resin that has a crosslinked structure produced by the copolymerization of styrene or acrylamide and divinylbenzene, and at least one of a quaternary ammonium group and a tertiary ammonium group, and that is provided with an acid-adsorbing ability. An acid solution whose primary component is hydrochloric acid and that includes indium is brought into contact with the anion-exchange resin to cause indium to be adsorbed to the anion-exchange resin.
摘要翻译： 本发明提供了可以引起铟吸附的铟吸附剂，以及用于从主要组分为盐酸并含有铟的酸溶液中分离和回收高纯度铟的简单且便宜的铟分级方法。 铟吸附剂的主要组分是具有通过苯乙烯或丙烯酰胺与二乙烯基苯共聚制得的交联结构和季铵基和叔铵基中的至少一种的阴离子交换树脂，并且其具有 酸吸附能力。 使主要成分为盐酸且包含铟的酸溶液与阴离子交换树脂接触，使铟吸附到阴离子交换树脂上。
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公开(公告)号：US20080038188A1
公开(公告)日：2008-02-14
申请号：US11631898
申请日：2005-07-07
申请人： Akifusai Ohnishi , Nobuaki Fujiwara , Hideki Doi , Toyokazu Matsunami , Hiroshi Tsubota , Toshiaki Muratani , Shoji Nishikawa , Shinichi Yamasaki , Takamichi Honma
发明人： Akifusai Ohnishi , Nobuaki Fujiwara , Hideki Doi , Toyokazu Matsunami , Hiroshi Tsubota , Toshiaki Muratani , Shoji Nishikawa , Shinichi Yamasaki , Takamichi Honma
CPC分类号： C22B58/00 , B01J20/26 , B01J20/261 , B01J41/04 , B01J41/14 , C22B3/42 , Y02P10/234
摘要： The invention provides an indium adsorbent that can cause indium to be adsorbed, and a simple and inexpensive indium fractioning method for isolating and recovering high-purity indium from an acid solution whose primary component is hydrochloric acid and that contains indium. A primary component of the indium adsorbent is an anion-exchange resin that has a crosslinked structure produced by the copolymerization of styrene or acrylamide and divinylbenzene, and at least one of a quaternary ammonium group and a tertiary ammonium group, and that is provided with an acid-adsorbing ability. An acid solution whose primary component is hydrochloric acid and that includes indium is brought into contact with the anion-exchange resin to cause indium to be adsorbed to the anion-exchange resin.
摘要翻译： 本发明提供了可以引起铟吸附的铟吸附剂，以及用于从主要组分为盐酸并含有铟的酸溶液中分离和回收高纯度铟的简单且便宜的铟分级方法。 铟吸附剂的主要组分是具有通过苯乙烯或丙烯酰胺与二乙烯基苯共聚制得的交联结构和季铵基和叔铵基中的至少一种的阴离子交换树脂，并且其具有 酸吸附能力。 使主要成分为盐酸且包含铟的酸溶液与阴离子交换树脂接触，使铟吸附到阴离子交换树脂上。
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3.发明授权公开(公告)号：US07264733B2
公开(公告)日：2007-09-04
申请号：US10488390
申请日：2002-08-29
IPC分类号： C02F1/62 , C02F101/20
CPC分类号： C22B15/0093 , C02F1/001 , C02F1/20 , C02F1/5236 , C02F1/66 , C02F2101/20 , C02F2103/16 , C02F2103/346 , C02F2209/265 , C22B3/44 , C22B7/006 , C22B11/042 , Y02P10/214 , Y02P10/234 , Y02P10/236 , Y10S210/912
摘要： A method and apparatus for treating heavy-metal-containing wastewater using a sulfidizing agent. Sulfidizing treatment is carried out by adding a sulfidizing agent to heavy-metal-containing wastewater, while detecting hydrogen sulfide gas generated from the wastewater, such as to maintain a state in which hydrogen sulfide gas is just starting to be generated from the wastewater. When separately recovering each of a plurality of metals from wastewater in which are mixed ions of the plurality of metals, there is repeated for each of the metals a process in which the acidity of the wastewater is adjusted to within a range suitable for the metal to be separated out and recovered, a sulfidizing reaction is carried out on that metal, and the metal sulfide produced is precipitated and filtered off.
摘要翻译： 一种使用硫化剂处理含重金属的废水的方法和装置。 硫化处理是通过在含重金属的废水中加入硫化剂，同时检测由废水产生的硫化氢气体，从而保持从废水开始生成硫化氢气体的状态。 当从其中是多种金属的混合离子的废水中分别回收多种金属中的每一种时，对于每种金属，重复将废水的酸度调节到适合于金属的范围内的方法 分离出并回收，对该金属进行硫化反应，使所生成的金属硫化物析出并过滤。
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