公开(公告)号：US4387198A

公开(公告)日：1983-06-07

申请号：US242971

申请日：1980-03-12

申请人： Akihiro Sato ,  Masami Tachibana ,  Kazutsune Kikuta ,  Yoshiharu Higuchi ,  Masazumi Miyajima

发明人： Akihiro Sato ,  Masami Tachibana ,  Kazutsune Kikuta ,  Yoshiharu Higuchi ,  Masazumi Miyajima

IPC分类号： C08F2/00 ,  C08F2/34 ,  C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F10/06 ,  C08F4/02

CPC分类号： C08F10/06 ,  Y10S526/904

摘要： A process for producing .alpha.-olefin polymers characterized by employing an organomagnesium compound in the preparation of a preactivated catalyst therefor is provided. The resulting polymers have particularly a higher rigidity in addition to various superior properties. The process comprises reacting a trivalent metal halide with a divalent metal compound to obtain a solid product (I); reacting this product with an organomagnesium compound, an electron donor (ED) and an electron acceptor (EA), once to 10 times, and at that time, using TiCl.sub.4 at least once as the (EA) to obtain a solid product (II); combining this product with an organoaluminum compound (OAl) and an (ED), and at that time, subjecting a combination of (II) and (OAl) or that of (II), (OAl) and (ED) to polymerization treatment with an .alpha.-olefin, and in the case of the former combination, further adding (ED), to obtain a preactivated catalyst; and polymerizing .alpha.-olefin(s) in the presence of this catalyst.

摘要翻译： 本发明提供一种制备α-烯烃聚合物的方法，其特征在于在制备预活化催化剂中使用有机镁化合物。 除了各种优异的性能之外，所得聚合物具有特别高的刚性。 该方法包括使三价金属卤化物与二价金属化合物反应得到固体产物（I）; 使该产物与有机镁化合物，电子给体（ED）和电子受体（EA）反应一次至10次，此时使用TiCl 4至少一次作为（EA）获得固体产物（II） ; 将该产物与有机铝化合物（OAl）和（ED）组合，然后将（II）和（OAl）或（II），（OAl）和（ED）的组合进行聚合处理， 在前一种组合的情况下，进一步加入（ED）以获得预活化的催化剂; 并在该催化剂存在下聚合α-烯烃。

公开(公告)号：US4368304A

公开(公告)日：1983-01-11

申请号：US231394

申请日：1981-02-04

申请人： Akihiro Sato ,  Toshihiro Uwai ,  Tohru Hanari ,  Kazutsune Kikuta ,  Masazumi Miyajima

发明人： Akihiro Sato ,  Toshihiro Uwai ,  Tohru Hanari ,  Kazutsune Kikuta ,  Masazumi Miyajima

IPC分类号： C08F2/00 ,  C08F2/34 ,  C08F4/00 ,  C08F4/16 ,  C08F4/60 ,  C08F4/64 ,  C08F4/76 ,  C08F10/00 ,  C08F297/08

CPC分类号： C08F297/08 ,  C08F10/00 ,  Y10S526/901 ,  Y10S526/902 ,  Y10S526/904

摘要： A process for producing .alpha.-olefin polymers is provided, which comprises: reacting an organoaluminum compound with an electron donor in a specified ratio in a solvent at a specified temperature to obtain a solid product (I); reacting solid product (I) with TiCl.sub.4 at a specified temperature in a specified ratio of Al/Ti and then removing a liquid portion from the resulting material followed by washing to obtain a solid product (II) having no free TiCl.sub.4 ; reacting solid product (II) with an electron donor and an electron acceptor in a specified ratio at a specified temperature to obtain a solid product (III); and polymerizing .alpha.-olefin(s) in the presence of a catalyst comprising a combination of solid product (III) with an organoaluminum compound. This process provides a catalyst having a high storing and thermal stability and a polymer having a uniform particle size.

摘要翻译： 提供了一种生产α-烯烃聚合物的方法，其包括：在特定温度下，在溶剂中使有机铝化合物与电子给体以规定的比例反应，得到固体产物（I）; 使固体产物（I）在特定温度下以规定比例的Al / Ti使TiCl 4反应，然后从所得材料中除去液体部分，然后洗涤，得到不含游离TiCl 4的固体产物（II）; 使固体产物（II）与规定比例的电子给体和电子受体反应，得到固体产物（III）; 和在包含固体产物（III）与有机铝化合物的组合的催化剂存在下聚合α-烯烃。 该方法提供具有高储存和热稳定性的催化剂和具有均匀粒度的聚合物。