摘要:
This invention relates to a method for on-line decoking of flame-cracking reactors whereby decoking is achieved without interruption of the normal operation of such reactors and without the necessity to change feed equipment and/or disassemble reactor components. While maintaining the temperature of the effluent at 1000.degree. C. to 2000.degree. C., the flow of the hydrocarbon feedstock in the reactor is periodically stopped for a time sufficient to reduce the carbon deposits to an acceptable level.
摘要:
In a process for the thermal cracking of hydrocarbons by the introduction of liquid petroleum feedstock in atomized form into a stream of hot combustion products formed by the combustion of fuel and oxidant in successive burner and mixing zone, constricting throat zone, a velocity acceleration diffuser zone and secondary cracking and reaction zone along the path of hot combustion product stream flow, an improvement is disclosed which comprises: effecting initial mixing, vaporization and cracking of said atomized liquid petroleum feedstock in said stream of hot combustion products in said burner and mixing zone maintained at subsonic velocity flow; effecting substantially complete mixing and vaporization in said constricting throat zone wherein said stream is maintained, at exit, at sonic velocity flow; passing said stream through a velocity acceleration diffuser zone maintained at supersonic velocity flow; passing said stream through a shock region produced by cross-sectional expansion of a diffuser zone; and effecting a final thermal cracking conversion in said stream in a subsonic velocity additional cracking reaction zone before quenching of said stream.
摘要:
An integrated partial oxidation-thermal cracking process is disclosed for the more complete utilization of all chemical values in crude oil feedstocks employed in the concurrent production of synthesis gas and an olefin-rich stream comprising the steps of: burning, at a high temperature, streams of fuel and oxygen in the presence of superheated steam to form a reducing stream of hot combustion products; injecting a crude oil distillate fraction stream into said reducing stream of hot combustion products; passing the resulting injected stream to a reaction zone to effect thermal cracking of said crude oil distillate fraction steam and reaction products; thermally quenching said stream; removing pitch and fractionating to provide at least one stream of hydrocarbon oil and an olefin rich gas stream; separating carbon dioxide and any contained hydrogen sulfide from said olefin rich gas stream; separating streams of synthesis gas, methane and ethylene from said olefin rich gas stream; and recycling fractions of said methane stream as fuel to said burning step.