公开(公告)号：US5811589A

公开(公告)日：1998-09-22

申请号：US552851

申请日：1995-11-03

申请人： Antonius J. J. M. Teunissen ,  Johannes G. De Vries ,  Onko J. Gelling ,  Cornelis Lensink

发明人： Antonius J. J. M. Teunissen ,  Johannes G. De Vries ,  Onko J. Gelling ,  Cornelis Lensink

IPC分类号： B01J31/22 ,  C07B61/00 ,  C07C45/50 ,  C07C67/313 ,  C07C67/333 ,  C07C67/347 ,  C07C69/533 ,  C07C69/67 ,  C07C45/00

CPC分类号： C07C45/50 ,  C07C67/347

摘要： Process for the preparation of a linear aldehyde organic compound by hydroformylation (b) starting from an internally unsaturated functionalised organic compound whereby first (a) a portion of the internally unsaturated functionalized organic compound is isomerized to a terminally unsaturated functionalised organic compound in the presence of a suitable isomerization catalyst, wherein following the isomerization step (a), the hydroformylation (b) is effected in the presence of carbon monoxide, hydrogen and a catalyst which preferentially catalyzes the hydroformylation reaction of the terminally unsaturated functionalised organic compound to the linear aldehyde organic compound, the internally unsaturated functionalised organic compound remaining practically unhydroformylated, whereupon (c) the linear aldhyde organic compound is separated out of the mixture and (d) the remainder of the unsaturated functionalised organic compound-containing mixture is recirculated to the isomerization step (a).

摘要翻译： 通过加氢甲酰化制备线性醛有机化合物的方法（b）从内部不饱和官能化的有机化合物开始，由此首先（a）一部分内部不饱和官能化的有机化合物在存在下被异构化为末端不饱和官能化的有机化合物 合适的异构化催化剂，其中在异构化步骤（a）之后，加氢甲酰基化（b）在一氧化碳，氢气和催化剂的存在下进行，其优先催化末端不饱和官能化有机化合物与直链醛有机物的加氢甲酰化反应 化合物，内部不饱和官能化的有机化合物几乎保持未形成甲酰化，因此（c）线性醛酸有机化合物从混合物中分离出来，（d）剩余的不饱和官能化的含有机化合物的混合物再循环到异构化st ep（a）。