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公开(公告)号：US5811589A
公开(公告)日：1998-09-22
申请号：US552851
申请日：1995-11-03
IPC分类号： B01J31/22 , C07B61/00 , C07C45/50 , C07C67/313 , C07C67/333 , C07C67/347 , C07C69/533 , C07C69/67 , C07C45/00
CPC分类号： C07C45/50 , C07C67/347
摘要： Process for the preparation of a linear aldehyde organic compound by hydroformylation (b) starting from an internally unsaturated functionalised organic compound whereby first (a) a portion of the internally unsaturated functionalized organic compound is isomerized to a terminally unsaturated functionalised organic compound in the presence of a suitable isomerization catalyst, wherein following the isomerization step (a), the hydroformylation (b) is effected in the presence of carbon monoxide, hydrogen and a catalyst which preferentially catalyzes the hydroformylation reaction of the terminally unsaturated functionalised organic compound to the linear aldehyde organic compound, the internally unsaturated functionalised organic compound remaining practically unhydroformylated, whereupon (c) the linear aldhyde organic compound is separated out of the mixture and (d) the remainder of the unsaturated functionalised organic compound-containing mixture is recirculated to the isomerization step (a).
摘要翻译： 通过加氢甲酰化制备线性醛有机化合物的方法（b）从内部不饱和官能化的有机化合物开始，由此首先（a）一部分内部不饱和官能化的有机化合物在存在下被异构化为末端不饱和官能化的有机化合物 合适的异构化催化剂，其中在异构化步骤（a）之后，加氢甲酰基化（b）在一氧化碳，氢气和催化剂的存在下进行，其优先催化末端不饱和官能化有机化合物与直链醛有机物的加氢甲酰化反应 化合物，内部不饱和官能化的有机化合物几乎保持未形成甲酰化，因此（c）线性醛酸有机化合物从混合物中分离出来，（d）剩余的不饱和官能化的含有机化合物的混合物再循环到异构化st ep（a）。
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公开(公告)号：US4383127A
公开(公告)日：1983-05-10
申请号：US283148
申请日：1981-07-14
IPC分类号： B01J23/847 , B01J23/89 , C07C37/56 , C07C37/01
CPC分类号： B01J23/8472 , B01J23/8946 , C07C37/56 , Y02P20/52
摘要： The invention relates to a method for the preparation of a substituted or unsubstituted phenol by oxidation of the corresponding substituted or unsubstituted benzoic acid in the gas phase in the presence of a copper and vanadium and/or silver and lithium and/or sodium and/or magnesium containing catalyst and catalysts therefor. The invention particularly relates to the gas phase oxidation of unsubstituted benzoic acid to unsubstituted phenol.
摘要翻译： 本发明涉及通过在铜和钒和/或银和/或锂和/或钠和/或钠和/或钠和/或钠的存在下，在气相中氧化相应的取代或未取代的苯甲酸来制备取代或未取代的苯酚的方法和/或 含镁催化剂及其催化剂。 本发明特别涉及未取代苯甲酸与未取代苯酚的气相氧化。
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3.发明授权
公开(公告)号：US4137259A
公开(公告)日：1979-01-30
申请号：US811321
申请日：1977-06-29
IPC分类号： C07C47/54 , B01J23/00 , B01J23/89 , C07B61/00 , C07C45/00 , C07C45/36 , C07C45/40 , C07C51/00 , C07C51/265 , C07C63/06 , C07C67/00 , C07C51/33 , B01J29/16
CPC分类号： C07C45/40 , B01J23/898 , C07C45/36 , C07C51/265
摘要： A catalyst mass of silver vanadate and iron vanadate, optionally also including at least one rare earth metal vanadate, is used in the vapor phase oxidative conversion of toluene to benzaldehyde and/or benzoic acid using oxygen or ozone and steam according to the disclosed process. Catalyst activity and selectivity are improved.
摘要翻译： 根据所公开的方法，使用氧钒或臭氧和蒸汽将甲酸银和/或苯甲酸气相氧化转化成钒钒酸银和铁钒酸盐的催化剂组合物，任选地还包括至少一种稀土金属钒酸盐。 催化剂活性和选择性得到改善。
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4.发明授权Hydroformylation process and bidentate phosphite ligand catalysts used therein 失效其中使用的加氢甲酰化方法和二齿亚磷酸酯配体催化剂
公开(公告)号：US5631392A
公开(公告)日：1997-05-20
申请号：US559807
申请日：1995-11-17
IPC分类号： B01J31/28 , B01J31/18 , C07B61/00 , C07C45/50 , C07C47/02 , C07F9/6571 , C07F9/6574 , C07F9/02 , C07F17/02
CPC分类号： C07F9/65746 , B01J31/185 , C07C45/50 , C07C67/347 , B01J2231/321 , B01J2531/80 , B01J2531/822
摘要： The invention relates to a process for preparing an aldehyde compound by hydroformylation of an ethylenically unsaturated organic compound, using a catalyst system which includes a Group VIII metal and a novel bidentate phosphite ligand. The bidentate phosphite ligand has a chemical structure according to formula (1), ##STR1## wherein R.sup.1 and R.sup.3 are respectively substituted or unsubstituted organic groups which may be the same or different, and wherein R.sup.2 is a substituted or unsubstituted tetravalent organic group.
摘要翻译： 本发明涉及通过烯属不饱和有机化合物的羰基化制备醛化合物的方法，该催化剂体系包括第Ⅷ族金属和新型二齿亚磷酸酯配体。 二齿亚磷酸酯配体具有根据式（1）的化学结构，其中R 1和R 3分别是可以相同或不同的取代或未取代的有机基团，并且其中R 2是取代或未取代的四价有机基团 组。
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公开(公告)号：US5357043A
公开(公告)日：1994-10-18
申请号：US993008
申请日：1992-12-18
申请人： Hubertus J. A. V. Delahaye , Johan T. Tinge , Adelbert A. H. Drinkenburg , Antonius J. J. M. Teunissen , Willem Klop
发明人： Hubertus J. A. V. Delahaye , Johan T. Tinge , Adelbert A. H. Drinkenburg , Antonius J. J. M. Teunissen , Willem Klop
IPC分类号： C07C227/18 , C07K5/075 , C07K3/04 , C07K3/08
CPC分类号： C07C227/18 , C07K5/0613
摘要： The invention relates to a process for the preparation of an oligopeptide or amino acid alkyl ester.HCl salt, the alkyl group being methyl, ethyl, isopropyl or n-propyl, by converting an oligopeptide.HCl salt or amino acid.HCl salt with an alkanol corresponding to the alkyl group under the influence of an acid catalyst, 0.01-0.5 mol HCl relative to the oligopeptide.HCl salt or amino acid.HCl salt in combination with an acid ion exchange resin being used as acid catalyst.
摘要翻译： 本发明涉及一种制备寡肽或氨基酸烷基酯盐酸盐的方法，所述烷基为甲基，乙基，异丙基或正丙基，通过将寡肽HCl盐或氨基酸HCl盐与 在酸催化剂的影响下相当于烷基的烷醇，0.01-0.5mol HCl相对于寡肽.HCl盐或氨基酸.HCl盐与酸性离子交换树脂组合用作酸催化剂。
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公开(公告)号：US5527950A
公开(公告)日：1996-06-18
申请号：US365478
申请日：1994-12-28
IPC分类号： B01J31/22 , C07B61/00 , C07C67/313 , C07C67/347 , C07C69/67 , C07C67/36 , C07C69/66
CPC分类号： C07C67/347
摘要： The invention relates to a process for the preparation of a 5-formylvalerate ester by hydroformylating a mixture of pentenoate esters in the presence of a catalyst system which catalyst system comprises a metal from group 8-10 of the Periodic Table of Elements and a mono- or multidentate organic phosphorous ligand, wherein the mixture of pentenoate esters contains less than 500 ppm hydroperoxide compounds.
摘要翻译： 本发明涉及通过在催化剂体系的存在下加氢甲酰化戊烯酸酯的混合物来制备5-甲酰基戊酸酯的方法，催化剂体系包含元素周期表第8-10族的金属， 或多齿有机磷配体，其中戊烯酸酯的混合物含有少于500ppm的氢过氧化物。
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公开(公告)号：US5710306A
公开(公告)日：1998-01-20
申请号：US616747
申请日：1996-03-15
申请人： Carina S. Snijder , Antonius J. J. M. Teunissen , Carolina B. Hansen , Rafael Shapiro , James M. Garner
发明人： Carina S. Snijder , Antonius J. J. M. Teunissen , Carolina B. Hansen , Rafael Shapiro , James M. Garner
IPC分类号： B01J31/22 , B01J31/18 , C07B61/00 , C07C45/50 , C07C47/00 , C07C51/14 , C07C67/347 , C07C67/38 , C07C69/716 , C07F9/145 , C07F9/146
CPC分类号： C07F9/146 , B01J31/185 , B01J31/1855 , C07C51/14 , C07C67/347 , C07F9/145 , B01J2231/321 , B01J2531/822
摘要： A process to prepare a multidentate phosphite compound according to the general formula (1) ##STR1## in which n is 2-6, R is an n-valent organic group and R.sup.1 and R.sup.2 are fused aromatic ring systems with 2 or more rings, which rings are substituted on the ortho position relative to the oxygen atom only with hydrogen, by first preparing a phosphorochloridite compound from a R.sup.1 --OH and R.sup.2 --OH alcohol compound and a phosphorus chloride compound and subsequently contacting the phosphorochloridite compound with an alcoholic compound according to R--(OH).sub.n, wherein the phosphorochloridite is prepared by performing the two steps in a solvent: a) contacting a compound with the general formula: ##STR2## in which R.sup.3 and R.sup.4 are C.sub.1 -C.sub.4 alkyl groups, with the R.sup.1 OH and R.sup.2 OH compounds, and b) contacting the resulting compound of step (a) which has the formula (3): ##STR3## with HY, wherein Y is a halogen.
摘要翻译： 制备根据通式（1）
的多齿亚磷酸酯化合物的方法，其中n是2-6，R是n价有机基团，R 1和R 2是具有2个或更多个环的稠合芳香环体系， 这些环仅在与氢气相对于氧原子的邻位上被取代，首先由R1-OH和R2-OH醇化合物和氯化磷化合物制备磷酰氯化合物，随后将其与醇化合物接触， 其中通过在溶剂中进行两个步骤来制备磷酰氯：a）使具有以下通式的化合物：其中R 3和R 4是C 1 -C 4烷基， 与R1OH和R2OH化合物反应，b）使所得到的具有式（3）的步骤（a）的化合物与式（3）与HY结合，其中Y是卤素。 -
公开(公告)号：US4775755A
公开(公告)日：1988-10-04
申请号：US829491
申请日：1986-02-14
IPC分类号： C07B61/00 , B01J23/00 , B01J23/44 , C07D239/26
CPC分类号： C07D239/26
摘要： The invention provides a process for the preparation of pyrimidine, 2-methyl- and/or 2-ethylpyrimidine, characterized in that for pyrimidine a nitrogen reactant, chosen from the reaction product of formamide with 1,3-diaminopropane in the liquid phase, 1-amino-3-formamidopropane, 1,4,5,6-tetrahydropyrimidine and/or 1,3-diformamidopropane, that for 2-methylpyrimidine 1-amino-3-acetamidopropane, 2-methyl-1,4,5,6-tetrahydropyrimidine and/or 1,3-diacetamidopropane, and that for 2-ethylpyrimidine 1-amino-3-propionamidopropane, 2-ethyl-1,4,5,6-tetrahydropyrimidine and/or 1,3-dipropionamidopropane is/are contacted with a palladium-containing catalyst, this being effected in the gas phase at a temperature between 200.degree. and 550.degree. C. and in the presence of a carbon monoxide-hydrogen reactant, and that pyrimidine, 2-methyl-and/or 2-ethyl-pyrimidine is recovered from the reaction mixture obtained.
摘要翻译： 本发明提供制备嘧啶，2-甲基 - 和/或2-乙基嘧啶的方法，其特征在于对于嘧啶，选自甲酰胺与液相中的1,3-二氨基丙烷的反应产物的氮反应物为1 2-氨基-3-甲酰胺丙烷，1,4,5,6-四氢嘧啶和/或1,3-二甲酰胺丙烷，2-甲基嘧啶1-氨基-3-乙酰氨基丙烷，2-甲基-1,4,5,6- 四氢嘧啶和/或1,3-二乙酰氨基丙烷，2-乙基嘧啶1-氨基-3-丙酰胺基丙烷，2-乙基-1,4,5,6-四氢嘧啶和/或1,3-二丙酰胺丙烷与 一种含钯催化剂，其在气相中在200-550℃的温度和在一氧化碳 - 氢气反应物存在下进行，而嘧啶，2-甲基 - 和/或2-乙基 从得到的反应混合物中回收 - 嘧啶。
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公开(公告)号：US6018081A
公开(公告)日：2000-01-25
申请号：US843130
申请日：1997-04-28
申请人： Patrick M. Burke , James M. Garner , Wilson Tam , Kristina A. Kreutzer , Antonius J. J. M. Teunissen , Carina S. Snijder , Carolina B. Hansen
发明人： Patrick M. Burke , James M. Garner , Wilson Tam , Kristina A. Kreutzer , Antonius J. J. M. Teunissen , Carina S. Snijder , Carolina B. Hansen
IPC分类号： B01J31/22 , B01J31/18 , C07B61/00 , C07C45/50 , C07C47/02 , C07C47/12 , C07C47/21 , C07C67/347 , C07C67/38 , C07C69/738 , C07C253/30 , C07C255/17 , C07F9/145 , C07F9/6574
CPC分类号： C07F9/65746 , B01J31/185 , C07C253/30 , C07C45/50 , C07C67/347 , C07F9/145 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , B01J2531/827
摘要： A hydroformylation process for preparating a terminal aldehyde involves reacting an ethylenically unsaturated organic compound with carbon monoxide and hydrogen in the presence of a catalyst system iridium or rhodium and a bidentate organic phosphite ligand wherein the two phosphorus atoms of the phopshite ligand are linked with a 2,2'-dihydroxyl-1,1'-binapthalene bridging group having the following structure (Q): ##STR1## in which R.sup.1 and R.sup.2 are substituents other than hydrogen and in which R.sup.3 and R.sup.4 are the same or different substituted monovalent aryl groups and/or any one of OR.sup.3 and OR.sup.4 connected to one phosphorus atom forms an --O--R.sup.5 --O-group, where R.sup.5 is a divalent organic group containing one or two aryl groups.
摘要翻译： 用于制备末端醛的加氢甲酰化方法包括在催化剂体系铱或铑和二齿有机亚磷酸酯配体的存在下使烯属不饱和有机化合物与一氧化碳和氢气反应，其中磷光体配体的两个磷原子与2 具有以下结构（Q）的2'-二羟基-1,1'-联萘桥连基团：其中R 1和R 2是除氢以外的取代基，并且其中R 3和R 4是相同或不同的取代的一价芳基和/或 与一个磷原子连接的OR 3和OR 4中的任何一个形成-O-R 5 -O-基，其中R 5是含有一个或两个芳基的二价有机基团。
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公开(公告)号：US4880929A
公开(公告)日：1989-11-14
申请号：US97657
申请日：1987-09-16
IPC分类号： C07B61/00 , C07D239/06 , C07D239/26
CPC分类号： C07D239/06 , C07D239/26
摘要： The invention relates to a process for preparing a 2-alkyl-1,4,5,6-tetrahydropyrimidine with the formula ##STR1## where R represents a straight or branched chain with 1-8 C-atoms or a phenyl group from 1,3-diaminopropane and an alkanecarboxylic acid, in which the alkyl group of such an acid is the same as the R group described above, wherein the starting materials are reacted in the gas phase in the presence of an oxide catalyst at a temperature of between 250.degree. and 450.degree. C. and from the reaction mixture thus obtained the 2-alkyl-1,4,5,6-tetrahydropyrimidine is recovered.
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