公开(公告)号：US10899689B2

公开(公告)日：2021-01-26

申请号：US16063734

申请日：2016-12-14

Applicant: Arkema France

Inventor： Abdelatif Baba-Ahmed ,  Bertrand Collier ,  Dominique Deur-Bert ,  Laurent Wendlinger

IPC: C07C17/386 ,  C07C17/383 ,  C07C21/18 ,  C07C19/10 ,  C09K5/04

Abstract: The invention concerns a method for purifying 2-chloro-3,3,3-trifluoropropene (1233xf) from a first composition comprising 2-chloro-3,3,3-trifluoropropene and at least one of the compounds chosen from the group consisting of E-1-chloro-3,3,3-trifluoro-1-propene (1233zd E), 1,1,1,3,3-pentafluoropropane (245fa) and 1,1,1,3,3,3-hexafluoropropane (236fa), said method comprising the steps of bringing said first composition into contact with at least one organic extractant in order to form a second composition; extractive distillation of said second composition in order to form a third composition comprising at least one of the compounds chosen from the group consisting of E-1-chloro-3,3,3-trifluoro-1-propene (1233zd E), 1,1,1,3,3-pentafluoropropane (245fa) and 1,1,1,3,3,3-hexafluoropropane (236fa), and said organic extractant; and a stream comprising 2-chloro-3,3,3-trifluoropropene.

公开(公告)号：US10550054B2

公开(公告)日：2020-02-04

申请号：US14773645

申请日：2014-02-24

Applicant: ARKEMA FRANCE

Inventor： Philippe Bonnet ,  Bertrand Collier ,  Dominique Deur-Bert ,  Laurent Wendlinger

IPC: C01B7/19 ,  C07C21/18 ,  C09K5/04 ,  C09K3/30

Abstract: An azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoropropene and one or more (hydro)halogen-carbon compounds including between 1 and 3 carbon atoms. Also, a preferred azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoropropene, and one or more compounds selected from among 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-l-chloropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro, 1,1,1,2-tetrafluoropropane.

公开(公告)号：US10532966B2

公开(公告)日：2020-01-14

申请号：US15861873

申请日：2018-01-04

Applicant: Arkema France

Inventor： Philippe Bonnet ,  Bertrand Collier ,  Dominique Deur-Bert ,  Dominique Garrait ,  Anne Pigamo ,  Laurent Wendlinger

IPC: C07C17/00 ,  C07C17/20 ,  C07C17/21 ,  C07C17/25 ,  B01J7/00

Abstract: A method for producing a fluorinated compound comprises: the provision of a gaseous flow comprising hydrofluoric acid; the provision of at least one liquid flow of a chlorinated compound and the vapourisation thereof by mixing with the gaseous flow, the resulting mixture being a gaseous mixture; and the catalytic reaction of the chlorinated compound with hydrofluoric acid in a gaseous phase and the collection of a product flow. The invention also relates to a facility for carrying out the method.

公开(公告)号：US20190127302A1

公开(公告)日：2019-05-02

申请号：US16225172

申请日：2018-12-19

Applicant: Arkema France

Inventor： Dominique Deur-Bert ,  Laurent Wendlinger ,  Bertrand Collier

IPC: C07C19/01 ,  C07C17/20 ,  C07C17/25

Abstract: The invention relates to a composition comprising at least 99% by weight of 1,1,1,2,3-pentachloropropane, and comprising at least one compound chosen from a list of additional compounds consisting of trichloropropanes, tetrachloropropanes, pentachloropropanes other than 1,1,1,2,3-pentachloropropane, hexachloropropanes, heptachloropropanes, dichloropropenes, trichloropropenes, tetrachloropropenes, pentachloropropenes and hexachloropropene, said compound being present in the composition in a weight content of less than or equal to 500 ppm.The invention also relates to the use of this composition for manufacturing 2,3,3,3-tetrafluoropropene.

公开(公告)号：US20190127301A1

公开(公告)日：2019-05-02

申请号：US16227137

申请日：2018-12-20

Applicant: Arkema France

Inventor： Anne Pigamo ,  Dominique Deur-Bert ,  Laurent Wendlinger ,  Bertrand Collier

IPC: C07C17/20 ,  C07C19/01 ,  C07C17/21

Abstract: The invention first relates to a composition comprising at least 99 wt. % of 1,1,1,3,3ºpentachloropropane and at least one compound selected from a list of additional compounds consisting of dichloropropanes, trichloropropanes, tetrachloropropanes, pentachloropropanes different from 1,1,1,3,3ºpentachloropropane, hexachloropropanes, heptachloropropanes, chloropropenes, dichloropropenes, trichloropropenes, tetrachloropropenes, pentachloropropenes and hexachloropropene, the weight content of said compound in the composition being lower than or equal to 500 ppm.

公开(公告)号：US20180354875A1

公开(公告)日：2018-12-13

申请号：US16102320

申请日：2018-08-13

Applicant: Arkema France

Inventor： Philippe Bonnet ,  Bertrand Collier ,  Dominque Deur-Bert ,  Laurent Wendlinger

IPC: C07C21/18 ,  C01B7/19

CPC classification number: C07C21/18 ,  C01B7/191 ,  C09K3/30 ,  C09K5/044

Abstract: An azeotropic or quasi-azeotropic composition including hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene and optionally one or more (hydro)halogen-carbon compounds including between 1 and 3 carbon atoms. Also, a preferred azeotropic or quasi-azeotropic composition including hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene, and optionally one or more compounds selected from among 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro,1,1,1,2-tetrafluoropropane.

公开(公告)号：US09834499B2

公开(公告)日：2017-12-05

申请号：US14987347

申请日：2016-01-04

Applicant: ARKEMA FRANCE

Inventor： Anne Pigamo ,  John Wismer ,  Bertrand Collier ,  Philippe Bonnet

IPC: C07C17/20 ,  C07C17/25 ,  C07C17/38 ,  C07C17/383

CPC classification number: C07C17/206 ,  C07B2200/09 ,  C07C17/25 ,  C07C17/38 ,  C07C17/383 ,  C07C21/18

Abstract: A production process for the production of E-1-chloro-3,3,3-trifluoropropene, the process including at least one stage during which 1,3,3,3-tetrachloropropene reacts with anhydrous hydrofluoric acid in the liquid phase, in the absence of a catalyst, with an HF/1,1,3,3-tetrachloropropene molar ratio between 3 and 20 inclusive, at a temperature between 50° C. and 150° C. inclusive and an absolute pressure of between 1 and 20 bar inclusive.

公开(公告)号：US09650551B2

公开(公告)日：2017-05-16

申请号：US14651855

申请日：2013-12-06

Applicant: ARKEMA FRANCE

Inventor： Bertrand Collier ,  Dominique Deur-Bert ,  Laurent Wendlinger

IPC: C09K5/04 ,  C09K3/00 ,  H01B3/56

CPC classification number: C09K5/08 ,  C07C21/18 ,  C09K3/00 ,  C09K5/044 ,  C09K5/045 ,  C09K2205/122 ,  C09K2205/126 ,  C09K2205/22 ,  C09K2205/32 ,  H01B3/56

Abstract: A composition including the compound HFO-1234yf and at least one other, additional, compound selected from HCFC-240db, HCFO-1233xf, HCFC-243db, HCFO-1233zd, HCC-40, HCFC-114a, HCFC-115, HCFC-122, HCFC-23, HCFC-124, HCFC-124a, HFC-125, HCFC-133a, HCFC-142, HCFC-143, HFC-52a, HCFC-243ab, HCFC-244eb, HFC-281ea, HCO-1110, HCFO-1111, HCFO-1113, HCFO-1223xd, and HCFO-1224xe. A composition including the compound HFO-1234yf and at least two compounds selected from HFO-1234ze, HFC-245cb, HFC-134a, HCFC-115, HFC-152a, HCC-40 and HFO-1243zf.

公开(公告)号：US11247952B2

公开(公告)日：2022-02-15

申请号：US16973253

申请日：2019-06-06

Applicant: ARKEMA FRANCE

Inventor： Bertrand Collier ,  Dominique Deur-Bert ,  Anne Pigamo ,  Audrey Riehl ,  Laurent Wendlinger

IPC: C07C21/18 ,  B01J8/04 ,  C07C17/20

Abstract: A process for producing 2,3,3,3-tetrafluoropropene comprises the steps: i) in a first adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing 2-chloro-3,3,3-trifluoropropene into contact with hydrofluoric acid in the gas phase in the presence of a catalyst to produce a stream A comprising 2,3,3,3-tetrafluoropropene, HF and unreacted 2-chloro-3,3,3-trifluoropropene; and ii) in a second adiabatic reactor comprising a fixed bed composed of an inlet and an outlet, bringing hydrofluoric acid into contact in the gas phase, optionally in the presence of a catalyst, with at least one chlorinated compound to produce a stream B comprising 2-chloro-3,3,3-trifluoropropene. The stream A obtained in step i) feeds said second reactor. The inlet temperature of the fixed bed of one of said first or second reactors is between 300° C. and 400° C. The longitudinal temperature difference between the inlet and the outlet of the fixed bed in question is less than 20° C.

公开(公告)号：US11225445B2

公开(公告)日：2022-01-18

申请号：US17260146

申请日：2019-07-16

Applicant: ARKEMA FRANCE

Inventor： Bertrand Collier ,  Anne Pigamo ,  Nicolas Brusadelli

IPC: C07C17/20 ,  C07C21/18 ,  C07C17/25

Abstract: A process for the production of trans-1-chloro-3,3,3-trifluoropropene comprises the steps of: i) providing a reactor comprising a cover, a bottom, sidewalls connecting said bottom and said cover, at least one reagent supply line and at least one line for drawing off the products formed, said reactor further containing a liquid phase A; ii) providing a stream B comprising hydrofluoric acid heated to a temperature T1 of from 100° C. to 170° C. and providing a stream C comprising 1,1,3,3-tetrachloropropene and/or 1,3,3,3-tetrachloropropene; stream B and stream C supplying said reactor via said at least one reagent supply line; iii) reacting, in liquid phase A, stream B with stream C to form a stream D comprising trans-1-chloro-3,3,3-trifluoropropene. Step iii) is carried out at a temperature T2 of between 50° C. and 110° C., and the temperature difference between temperature T1 and temperature T2 is greater than 30° C.