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1.发明授权公开(公告)号：US08846962B2
公开(公告)日：2014-09-30
申请号：US13520042
申请日：2010-12-29
IPC分类号： C07C51/16 , C07C51/353 , C07C51/245
CPC分类号： C07C51/09 , B01D15/361 , C07C51/245 , C07C51/353 , C07C51/44 , C07C67/31 , C07C67/42 , C07C53/126 , C07C55/02
摘要： There is described a continuous process for the oxidative cleavage of derivatives of unsaturated carboxylic acids for the production of saturated carboxylic acids and their derivatives comprising the steps of: a) feeding to a first reactor at least a derivative of an unsaturated carboxylic acid, an oxidizing compound and a catalyst capable of catalyzing the oxidation reaction of the olefinic double bond to obtain an intermediate compound containing vicinal diols, and of b) feeding to a second reactor said intermediate compound, a compound containing oxygen and a catalyst capable of catalyzing the oxidation reaction of the vicinal diols to carboxylic groups, to obtain saturated monocarboxylic acids (i) and derivatives of saturated carboxylic acids with more than one acid function (ii); c) separating the saturated monocarboxylic acids (i) from the derivatives of carboxylic acids having more than one acid function (ii).
摘要翻译： 描述了用于产生饱和羧酸及其衍生物的不饱和羧酸衍生物的氧化断裂的连续方法，包括以下步骤：a）将至少不饱和羧酸的衍生物，氧化的 化合物和能够催化烯属双键的氧化反应的催化剂，得到含有连位二醇的中间体化合物，以及b）向第二反应器进料所述中间体化合物，含氧的化合物和能够催化氧化反应的催化剂 （i）和具有多于一个酸官能团的饱和羧酸衍生物（ii）; c）将饱和一元羧酸（i）与具有多于一个酸官能团的羧酸衍生物（ii）分离。
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2.发明申请公开(公告)号：US20120302778A1
公开(公告)日：2012-11-29
申请号：US13520042
申请日：2010-12-29
IPC分类号： C07C51/16 , C07C53/126
CPC分类号： C07C51/09 , B01D15/361 , C07C51/245 , C07C51/353 , C07C51/44 , C07C67/31 , C07C67/42 , C07C53/126 , C07C55/02
摘要： There is described a continuous process for the oxidative cleavage of derivatives of unsaturated carboxylic acids for the production of saturated carboxylic acids and their derivatives comprising the steps of: a) feeding to a first reactor at least a derivative of an unsaturated carboxylic acid, an oxidizing compound and a catalyst capable of catalyzing the oxidation reaction of the olefinic double bond to obtain an intermediate compound containing vicinal diols, and of b) feeding to a second reactor said intermediate compound, a compound containing oxygen and a catalyst capable of catalyzing the oxidation reaction of the vicinal diols to carboxylic groups, to obtain saturated monocarboxylic acids (i) and derivatives of saturated carboxylic acids with more than one acid function (ii); c) separating the saturated monocarboxylic acids (i) from the derivatives of carboxylic acids having more than one acid function (ii).
摘要翻译： 描述了用于产生饱和羧酸及其衍生物的不饱和羧酸衍生物的氧化断裂的连续方法，包括以下步骤：a）将至少不饱和羧酸的衍生物，氧化的 化合物和能够催化烯属双键的氧化反应的催化剂，得到含有连位二醇的中间体化合物，以及b）向第二反应器进料所述中间体化合物，含氧的化合物和能够催化氧化反应的催化剂 （i）和具有多于一个酸官能团的饱和羧酸衍生物（ii）; c）将饱和一元羧酸（i）与具有多于一个酸官能团的羧酸衍生物（ii）分离。
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公开(公告)号：US08835662B2
公开(公告)日：2014-09-16
申请号：US13520020
申请日：2010-12-29
IPC分类号： C07C51/16 , C07C51/09 , C07C51/245
CPC分类号： C07C51/285 , C07C51/09 , C07C51/16 , C07C51/245 , C07C51/347 , C07C51/353 , C11C1/04 , C07C55/02 , C07C55/18 , C07C53/126
摘要： There is described a continuous process for the oxidative cleavage of vegetable oils containing triglycerides of unsaturated carboxylic acids, for the obtainment of saturated carboxylic acids, comprising the steps of: a) feeding to a first continuous reactor at least a vegetable oil, an oxidizing compound and a catalyst capable of catalyzing the oxidation reaction of the olefinic double bond to obtain an intermediate compound containing vicinal diols, and of b) feeding to a second continuous reactor said intermediate compound, a compound containing oxygen and a catalyst capable of catalyzing the oxidation reaction of the vicinal diols to carboxylic groups, to obtain saturated monocarboxylic acids (i) and triglycerides containing saturated carboxylic acids with more than one acid function (ii); c) separating the saturated monocarboxylic acids (i) from the triglycerides having more than one acid function (ii). d) hydrolyzing in a third reactor the triglycerides having more than one acid function (ii) to obtain glycerol and saturated carboxylic acids with more than one acid function.
摘要翻译： 描述了用于获得饱和羧酸的含有不饱和羧酸甘油三酯的植物油的氧化断裂的连续方法，包括以下步骤：a）将至少一种植物油，氧化化合物 和能够催化烯属双键的氧化反应以获得含邻位二醇的中间体化合物的催化剂，以及b）向第二连续反应器供给所述中间体化合物，含有氧的化合物和能够催化氧化反应的催化剂 （i）和含有多于一个酸官能团的饱和羧酸的甘油三酸酯（ii）; c）将饱和一元羧酸（i）与具有多于一个酸官能度的甘油三酯（ii）分离。 d）在第三反应器中水解具有多于一个酸官能团的甘油三酸酯（ii）以获得具有多于一个酸官能团的甘油和饱和羧酸。
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公开(公告)号：US20120323028A1
公开(公告)日：2012-12-20
申请号：US13520020
申请日：2010-12-29
IPC分类号： C07C51/235
CPC分类号： C07C51/285 , C07C51/09 , C07C51/16 , C07C51/245 , C07C51/347 , C07C51/353 , C11C1/04 , C07C55/02 , C07C55/18 , C07C53/126
摘要： There is described a continuous process for the oxidative cleavage of vegetable oils containing triglycerides of unsaturated carboxylic acids, for the obtainment of saturated carboxylic acids, comprising the steps of: a) feeding to a first continuous reactor at least a vegetable oil, an oxidizing compound and a catalyst capable of catalyzing the oxidation reaction of the olefinic double bond to obtain an intermediate compound containing vicinal diols, and of b) feeding to a second continuous reactor said intermediate compound, a compound containing oxygen and a catalyst capable of catalyzing the oxidation reaction of the vicinal diols to carboxylic groups, to obtain saturated monocarboxylic acids (i) and triglycerides containing saturated carboxylic acids with more than one acid function (ii); c) separating the saturated monocarboxylic acids (i) from the triglycerides having more than one acid function (ii). d) hydrolyzing in a third reactor the triglycerides having more than one acid function (ii) to obtain glycerol and saturated carboxylic acids with more than one acid function.
摘要翻译： 描述了用于获得饱和羧酸的含有不饱和羧酸甘油三酯的植物油的氧化断裂的连续方法，包括以下步骤：a）将至少一种植物油，氧化化合物 和能够催化烯属双键的氧化反应以获得含邻位二醇的中间体化合物的催化剂，以及b）向第二连续反应器供给所述中间体化合物，含有氧的化合物和能够催化氧化反应的催化剂 （i）和含有多于一个酸官能团的饱和羧酸的甘油三酸酯（ii）; c）将饱和一元羧酸（i）与具有多于一个酸官能度的甘油三酯（ii）分离。 d）在第三反应器中水解具有多于一个酸官能团的甘油三酸酯（ii）以获得具有多于一个酸官能团的甘油和饱和羧酸。
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