Conductive medium for openhole logging and logging while drilling
    1.
    发明授权
    Conductive medium for openhole logging and logging while drilling 失效
    用于裸眼测井和采伐的导电介质

    公开(公告)号:US06308788B1

    公开(公告)日:2001-10-30

    申请号:US09514680

    申请日:2000-02-28

    IPC分类号: C09K706

    CPC分类号: G01V3/20 C09K8/32

    摘要: A method of electrically logging subterranean wells using a conductive fluid in which the conductive fluid includes a miscible combination of an oleaginous fluid, a polar organic solvent, and an electrolytic salt. The electrolytic salt or brine of the salt is present in a concentration sufficient to permit the electrical logging of the subterranean well. The medium may further include gelling agent, weight material, surfactant, or corrosion inhibitors. The polar organic solvent may preferably be a oil soluble glycol or glycol ether such as ethylene glycol, diethylene glycol, propylene glycol, polypropylene glycol, and the like. The electrolytic salt or brine is preferably a quaternary amine salt having the formula: wherein R is an alkyl having 8 to 18 carbon atoms, R′ is 2 to 6 carbon atoms alkyl group, B is hydrogen, oxyalkyl having 1 to 4 carbon atoms or alkyl having 1 to 4 carbon atoms, A is hydrogen or alkyl with 1 to 4 carbon atoms, x+y=1 to 15, z is 0 to 3, and M− is a counter anion; or combinations thereof.

    摘要翻译: 一种使用导电流体对地下井进行电测井的方法,其中导电流体包括油性流体,极性有机溶剂和电解盐的可混合组合。 盐的电解盐或盐水的存在浓度足以允许对地下井进行电测井。 介质还可以包括胶凝剂,重量材料,表面活性剂或腐蚀抑制剂。 极性有机溶剂可以优选为油溶性二醇或二醇醚,例如乙二醇,二甘醇,丙二醇,聚丙二醇等。 电解盐或盐水优选为具有下式的季胺盐:其中R为具有8至18个碳原子的烷基,R'为2至6个碳原子的烷基,B为氢,具有1至4个碳原子的烷氧基烷基或 具有1至4个碳原子的烷基,A是氢或具有1至4个碳原子的烷基,x + y = 1至15,z为0至3,M-为抗衡阴离子; 或其组合。

    Conductive medium for openhold logging and logging while drilling
    2.
    发明授权
    Conductive medium for openhold logging and logging while drilling 失效
    导电介质,用于钻孔时的露天采伐和采伐

    公开(公告)号:US06405809B2

    公开(公告)日:2002-06-18

    申请号:US09757570

    申请日:2001-01-10

    IPC分类号: C09K706

    摘要: A method of electrically logging subterranean wells using a conductive fluid includes a miscible combination of an oleaginous fluid, a polar organic solvent, an electrolytic salt, and a carbon dioxide buffer. The electrolytic salt or brine of the salt is present in a concentration sufficient to permit the electrical logging of the subterranean well. The polar organic solvent may be an oil soluble glycol or glycol ether such as ethylene glycol, diethylene glycol, propylene glycol, polypropylene glycol, and the like. The electrolytic salt or brine preferably includes a quaternary amine salt having the formula: wherein R is an alkyl having 8 to 18 carbon atoms, R′ is 2 to 6 carbon atoms alkyl group, B is hydrogen, oxyalkyl having 1 to 4 carbon atoms or alkyl having 1 to 4 carbon atoms, A is hydrogen or alkyl with 1 to 4 carbon atoms, x+y=1 to 15, z is 0 to 3, and M is a counter anion; or combinations thereof. The carbon dioxide buffer is preferably a trialkylanol amine.

    摘要翻译: 使用导电流体电测井地下井的方法包括油性流体,极性有机溶剂,电解盐和二氧化碳缓冲液的可混合组合。 盐的电解盐或盐水的存在浓度足以允许对地下井进行电测井。 极性有机溶剂可以是油溶性二醇或二醇醚,例如乙二醇,二甘醇,丙二醇,聚丙二醇等。 电解盐或盐水优选包括具有下式的季胺盐:其中R是具有8至18个碳原子的烷基,R'是2至6个碳原子的烷基,B是氢,具有1至4个碳原子的烷氧基或 具有1至4个碳原子的烷基,A为氢或具有1至4个碳原子的烷基,x + y = 1至15,z为0至3,M为抗衡阴离子; 或其组合。 二氧化碳缓冲液优选为三烷基醇胺。

    Oil based well fluids with high solids content
    3.
    发明授权
    Oil based well fluids with high solids content 失效
    油基井液,固体含量高

    公开(公告)号:US06770602B2

    公开(公告)日:2004-08-03

    申请号:US10062854

    申请日:2002-01-31

    IPC分类号: C09K706

    CPC分类号: C09K8/36 C09K2208/18

    摘要: A fluid having utility in subterranean wells is formulated to include: an oleaginous fluid; and a solids tolerance agent having the formula: in which R is a C6 to C20 aliphatic group and R′ is a C2 to C6 aliphatic group and x has a value from about 1 to about 10. Preferably R′ is selected from ethyl and isopropyl and R is an unsaturated aliphatic group. The fluid is formulated such that the oleaginous fluid is from about 30% to about 99% by volume of said fluid. In one illustrative embodiment, the oleaginous fluid is composed from about 5% to about 100% by volume of the oleaginous fluid of a material selected from a group consisting of diesel oil, mineral oil, synthetic oil, esters, ethers, acetals, di-alkylcarbonates, olefins, and combinations of these and similar fluids. A non-oleaginous fluid may also be included in the formulation that is from about 1% to about 70% by volume of said fluid. The non-oleaginous fluid is preferably selected from sea water, a brine containing organic or inorganic dissolved salts, a liquid containing water-miscible organic compounds, and combinations thereof. Also included in the fluid formulation may be weighting agents, fluids loss agents, viscosity agents and other similar agents utilized in the formulation of oil-based and invert emulsion drilling fluids.

    摘要翻译: 在地下井中具有效用的流体被配制成包括:含油流体; 和具有下式的固体耐受剂:其中R是C6至C20脂族基团,R'是C2至C6脂族基团,x具有约1至约10的值。优选地,R'选自乙基和异丙基 并且R是不饱和脂族基团。 流体被配制成使得含油流体占所述流体的约30体积%至约99体积%。 在一个说明性实施方案中,含油流体由选自柴油,矿物油,合成油,酯,醚,缩醛,二缩水甘油醚的材料的约5体积%至约100体积%的油质流体组成, 烷基碳酸酯,烯烃,以及这些和类似流体的组合。 制剂中也可以包含约1%至约70%体积的所述流体的非含油液体。 非油质流体优选选自海水,含有机或无机溶解盐的盐水,含有水混溶性有机化合物的液体及其组合。 还包括在流体配方中可以是增稠剂,流体损失剂,粘度剂和用于油基和反相乳液钻井液配方中的其它类似物质。