公开(公告)号：US3656916A

公开(公告)日：1972-04-18

申请号：US3656916D

申请日：1970-04-08

Applicant: BASF AG

Inventor： SCHIEDERMAIER RICHARD ,  WINTERSBERGER KARL ,  WUNSCH GERD

IPC: C01B21/098 ,  C01B21/52 ,  C01B25/00

CPC classification number: C01B21/0986

Abstract: Phosphonitrilic chlorides having the general formula: PNCl2)n where n denotes an integer of at least 3 and which contain a high proportion of trimeric and tetrameric cyclic phosphonitrilic chlorides are prepared by reaction of phosphorus pentachloride with ammonia in an inert solvent. The solution should contain not more than 5 moles of phosphorus pentachloride per liter. Ammonia is introduced at a rate not exceeding 0.12 liter per minute per mole of the phosphorus pentachloride contained in the whole solution until one tenth to one third of the total amount of ammonia required has been introduced.

Abstract translation: 具有以下通式的膦酰氯：PNCl2）n其中n表示至少3的整数，并且含有高比例的三聚和四聚环状膦酰氯是通过在惰性溶剂中与五氯化磷反应制备的。 该溶液每升应含有不超过5摩尔的五氯化磷。 以不超过0.12升/分钟的摩尔量，每摩尔包含在整个溶液中的五氯化磷的量引入氨，直到引入所需氨的总量的十分之一至三分之一。

公开(公告)号：US3658487A

公开(公告)日：1972-04-25

申请号：US3658487D

申请日：1970-04-10

Applicant: BASF AG

Inventor： WUNSCH GERD ,  SCHIEDERMAIER RICHARD ,  WINTERSBERGER KARL

IPC: C01B21/098 ,  C01B21/52 ,  C01B25/00

CPC classification number: C01B21/0986

Abstract: Phosphonitrilic chlorides having the formula (PNCl2)n where n denotes an integer of at least 3, are obtained by reacting chlorine and ammonia simultaneously with elementary phosphorus in an inert solvent.

Abstract translation: 通过使氯和氨与惰性溶剂中的元素磷同时反应，得到具有式（PNCI 2）n的膦酰氯，其中n表示至少3的整数。