公开(公告)号：US20160368843A1

公开(公告)日：2016-12-22

申请号：US14902247

申请日：2014-06-25

Applicant: BASF SE

Inventor： Joaquim Henrique TELES ,  Joachim SIMON ,  Martine DEHN ,  Manuel DANZ ,  Richard DEHN

IPC: C07C29/16

CPC classification number: C07C29/16 ,  C07C29/095 ,  C07C29/88 ,  C07C31/125

Abstract: The invention relates to a method for producing 2,3,5-trimethyl benzoquinone or a compound containing 2,3,5-trimethyl benzoquinone, the method comprising the following steps: Oxidation of 2,3,6-trimethylphenol with oxygen or an oxygen-containing gas in a two- or multi-phase reaction medium in the presence of a catalyst or catalyst system containing at least one copper (II)-halide to a mixture containing 2,3,5-trimethyl benzoquinone, characterized in that the reaction medium contains water and at least one secondary aliphatic acyclic alcohol having 6 or more, preferably 7 or more, carbon atoms.

Abstract translation: 本发明涉及一种生产2,3,5-三甲基苯醌或含有2,3,5-三甲基苯醌的化合物的方法，该方法包括以下步骤：用氧或氧气氧化2,3,6-三甲基苯酚 在含有至少一种卤化铜（II）的催化剂或催化剂体系的存在下，在含有2,3,5-三甲基苯醌的混合物存在下，在两相或多相反应介质中存在的气体，其特征在于反应 介质含有水和至少一种具有6个或更多个，优选7个或更多个碳原子的仲脂族无环醇。

公开(公告)号：US20160368887A1

公开(公告)日：2016-12-22

申请号：US14902231

申请日：2014-06-25

Applicant: BASF SE

Inventor： Richard DEHN ,  Michael KRAUS ,  Martine DEHN ,  Manuel DANZ ,  Joaquim Henrique TELES

IPC: C07D311/72 ,  C07C50/04 ,  C07C46/08

CPC classification number: C07D311/72 ,  C07C46/08 ,  C07C50/02 ,  C07C50/04

Abstract: The invention relates to a method for producing 2,3,5-trimethyl benzoquinone or a compound containing 2,3,5-trimethyl benzoquinone, the method comprising the following steps: Oxidation of 2,3,6-trimethylphenol with oxygen or an oxygen-containing gas in a two-or multi-phase reaction medium in the presence of a catalyst or catalyst system containing at least one copper (II)-halide to a mixture containing 2,3,5-trimethyl benzoquinone, characterized in that the reaction medium contains water and at least one secondary aliphatic acyclic alcohol having 6 or more, preferably 7 or more, carbon atoms.

Abstract translation: 本发明涉及一种生产2,3,5-三甲基苯醌或含有2,3,5-三甲基苯醌的化合物的方法，该方法包括以下步骤：用氧或氧气氧化2,3,6-三甲基苯酚 在含有至少一种卤化铜（II）的催化剂或催化剂体系的存在下，在含有2,3,5-三甲基苯醌的混合物存在下，在二相或多相反应介质中存在的气体，其特征在于反应 介质含有水和至少一种具有6个或更多个，优选7个或更多个碳原子的仲脂族无环醇。

公开(公告)号：US20240010597A1

公开(公告)日：2024-01-11

申请号：US18021570

申请日：2021-08-09

Applicant: BASF SE

Inventor： Jessica Nadine HAMANN ,  Joaquim Henrique TELES ,  Peter Georg OHLEMUELLER ,  Friedemann GAITZSCH ,  Shelue LIANG ,  Stefan RITTINGER ,  Frauke THRUN ,  Richard DEHN

IPC: C07C51/235 ,  C07C51/44

CPC classification number: C07C51/235 ,  C07C51/44

Abstract: A process for the preparation of a color stable C6-12 saturated aliphatic carboxylic acid in which (1) the corresponding aldehyde is oxidized with molecular oxygen to obtain the crude saturated aliphatic carboxylic acid in a liquid mixture, (2) molecular oxygen removed from the crude saturated aliphatic carboxylic acid mixture, and (3) the saturated aliphatic carboxylic acid separated from the molecular oxygen depleted mixture by distillation as a color stable product.

公开(公告)号：US20190040005A1

公开(公告)日：2019-02-07

申请号：US16073941

申请日：2017-01-30

Applicant: BASF SE

Inventor： Richard DEHN ,  Ahmad DEHESTANI ,  Klemens MASSONNE ,  Steffen WAGLÖHNER ,  Joaquim Henrique TELES ,  Thomas SCHAUB ,  Till Christian BRÜGGEMANN ,  Carlos TELLAECHE HERRANZ ,  Oliver TRAPP ,  Jedrzej WYSOCKI

IPC: C07D201/10 ,  C07B43/02 ,  C07B43/06

Abstract: The present invention relates to a process for preparing C4-C15 lactams, in which a C1-C10-alkyl nitrite is reacted with a C4-C15-cycloalkane and is illuminated with a light-emitting diode during the reaction. This forms a C4-C15-cyclohexanone oxime which is then converted further to a C4-C15 lactam; the C1-C10 alcohol formed is recycled into the preparation of the C1-C10-alkyl nitrite.

公开(公告)号：US20230017999A1

公开(公告)日：2023-01-19

申请号：US17781405

申请日：2020-11-23

Applicant: BASF SE

Inventor： Jaroslaw Michael MORMUL ,  Dieter KOLASSA ,  Dominic RIEDEL ,  Joaquim Henrique TELES ,  Ansgar Gereon ALTENHOFF ,  Richard DEHN ,  Peter OECHSLE

IPC: C07C209/84

Abstract: The present invention relates to a process for purification of a mixture comprising water, N-alkyl-hydroxylammonium salts and some byproducts wherein from the mixture water and byproducts are distilled off until the purity of N-alkyl-hydroxylammonium salts in the residue is 95% or higher and additionally keeping the water content during and after the distillation ≥40 wt.-% according to the residue.

公开(公告)号：US20180201599A1

公开(公告)日：2018-07-19

申请号：US15676398

申请日：2017-08-14

Applicant: BASF SE

Inventor： Richard DEHN ,  Michael KRAUS ,  Martine DEHN ,  Manuel DANZ ,  Joaquin Henrique TELES

IPC: C07D311/72 ,  C07C50/04 ,  C07C46/08 ,  C07C50/02

CPC classification number: C07D311/72 ,  C07C46/08 ,  C07C50/02 ,  C07C50/04

Abstract: The invention relates to a method for producing 2,3,5-trimethyl benzoquinone or a compound containing 2,3,5-trimethyl benzoquinone, the method comprising the following steps: Oxidation of 2,3,6-trimethylphenol with oxygen or an oxygen-containing gas in a two- or multi-phase reaction medium in the presence of a catalyst or catalyst system containing at least one copper (II)-halide to a mixture containing 2,3,5-trimethyl benzoquinone, characterized in that the reaction medium contains water and at least one secondary aliphatic acyclic alcohol having 6 or more, preferably 7 or more, carbon atoms.