公开(公告)号：US20150141691A1

公开(公告)日：2015-05-21

申请号：US14538060

申请日：2014-11-11

Applicant: BASF SE

Inventor： Walter Disteldorf ,  Jarren Peters ,  Thomas Schäfer ,  Katrin Friese ,  Christoph Übler

IPC: C07C67/08

CPC classification number: C07C67/08 ,  C07C69/80

Abstract: The invention relates to a method for producing carboxylic esters by converting a carboxylic acid or a carboxylic acid anhydride or a mixture thereof with an alcohol in a reaction system comprising one or more reactors, wherein reaction water is distilled as alcohol-water-azeotrope with the vapors, the vapors are at least partially condensed, the condensate is separated into an aqueous phase and an organic phase and said organic phase is supplied at least partially back into said reaction system. Components boiling lower than the alcohol are at least partially removed from said returned organic phase such as wherein components boiling lower than alcohol are evaporated and/or distilled off. An enrichment in the reaction system of by-products boiling lower than alcohol is avoided. Alcohol losses can be minimized by discharge currents.

Abstract translation: 本发明涉及一种通过在包含一个或多个反应器的反应体系中将羧酸或羧酸酐或其混合物与醇反应来制备羧酸酯的方法，其中将反应水作为醇 - 水 - 共沸物与 蒸气，蒸气至少部分冷凝，将冷凝物分离成水相和有机相，并将所述有机相至少部分提供回所述反应体系。 沸点低于醇的组分至少部分地从所述返回的有机相中除去，例如其中沸点低于醇的组分蒸发和/或蒸馏掉。 避免了沸点低于酒精的副产物的反应体系的富集。 酒精损失可以通过放电电流最小化。

公开(公告)号：US09260373B2

公开(公告)日：2016-02-16

申请号：US14538060

申请日：2014-11-11

Applicant: BASF SE

Inventor： Walter Disteldorf ,  Jarren Peters ,  Thomas Schäfer ,  Katrin Friese ,  Christoph Übler

IPC: C07C67/08

CPC classification number: C07C67/08 ,  C07C69/80

Abstract: The invention relates to a method for producing carboxylic esters by converting a carboxylic acid or a carboxylic acid anhydride or a mixture thereof with an alcohol in a reaction system comprising one or more reactors, wherein reaction water is distilled as alcohol-water-azeotrope with the vapors, the vapors are at least partially condensed, the condensate is separated into an aqueous phase and an organic phase and said organic phase is supplied at least partially back into said reaction system. Components boiling lower than the alcohol are at least partially removed from said returned organic phase such as wherein components boiling lower than alcohol are evaporated and/or distilled off. An enrichment in the reaction system of by-products boiling lower than alcohol is avoided. Alcohol losses can be minimized by discharge currents.

Abstract translation: 本发明涉及一种通过在包含一个或多个反应器的反应体系中将羧酸或羧酸酐或其混合物与醇反应来制备羧酸酯的方法，其中将反应水作为醇 - 水 - 共沸物与 蒸气，蒸气至少部分冷凝，将冷凝物分离成水相和有机相，并将所述有机相至少部分提供回所述反应体系。 沸点低于醇的组分至少部分地从所述返回的有机相中除去，例如其中沸点低于醇的组分蒸发和/或蒸馏掉。 避免了沸点低于酒精的副产物的反应体系的富集。 酒精损失可以通过放电电流最小化。

公开(公告)号：US20140357898A1

公开(公告)日：2014-12-04

申请号：US14458481

申请日：2014-08-13

Applicant: BASF SE

Inventor： Shin-Ichiro Kawano ,  Martin Baumgarten ,  Klaus Müllen ,  Peter Murer ,  Thomas Schäfer ,  Moussa Saleh

IPC: C07C25/22 ,  C07C45/28 ,  C07C49/697 ,  H01L51/00 ,  C07C43/29

CPC classification number: C07C25/22 ,  C07C43/29 ,  C07C45/28 ,  C07C49/697 ,  C08G61/02 ,  C08G61/10 ,  C08G61/122 ,  C08G61/123 ,  C08G2261/124 ,  C08G2261/1424 ,  C08G2261/148 ,  C08G2261/3142 ,  C08G2261/5222 ,  C09K11/06 ,  C09K2211/1416 ,  C09K2211/1425 ,  C09K2211/145 ,  C09K2211/1458 ,  C09K2211/1466 ,  H01L51/0035 ,  H01L51/0054 ,  H01L51/0508 ,  H01L51/42 ,  H01L51/5012 ,  Y02E10/549 ,  Y10S428/917 ,  Y10T428/31504 ,  Y10T428/31678

Abstract: The present invention relates to polymers comprising repeating unit(s) of the formula (I), and their use in electronic devices. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high charge carrier mobilities and high temperature stability of the emission color are observed, if the polymers according to the invention are used in polymer light emitting diodes (PLEDs).

Abstract translation: 本发明涉及包含式（I）的重复单元的聚合物及其在电子器件中的用途。 根据本发明的聚合物在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外，如果根据本发明的聚合物用于聚合物发光二极管（PLED）中，则观察到高电荷载流子迁移率和发光颜色的高温稳定性。