公开(公告)号：US20150073152A1

公开(公告)日：2015-03-12

申请号：US14540838

申请日：2014-11-13

申请人： BASF SE

发明人： Markus BOLD ,  Christian LENNARTZ ,  Martina PRINZ ,  Hans-Werner SCHMIDT ,  Mukundan THELAKKAT ,  Markus BAETE ,  Christian NEUBER ,  Wolfgang KOWALSKY ,  Christian SCHILDKNECHT ,  Hans-Hermann JOHANNES

IPC分类号： H01L51/00

CPC分类号： H01L51/0085 ,  B01J31/2265 ,  B01J31/2273 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/18 ,  B01J2531/57 ,  B01J2531/60 ,  B01J2531/70 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/828 ,  C07F15/0033 ,  C09B57/00 ,  C09B57/10 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1018 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/18 ,  C09K2211/185 ,  H01L51/0081 ,  H01L51/5016 ,  H01L51/5096 ,  Y02P20/582

摘要： Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a n complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.

摘要翻译： 在有机发光二极管中使用式（I）的过渡金属配合物，其中：M1是金属原子; 卡宾是卡宾配体; L是单阴离子或双阴离子配体; K是选自磷化氢的不带电荷的单齿或双齿配体; CO; 吡啶 与M1形成n络合物的腈和共轭二烯; n是卡宾配体的数目，至少为1; m是配体L的数目，其中m可以是0或≥1; o是配体K的数目，其中o可以是0或≥1; 其中总和n + m + o取决于金属原子的氧化态和配位数以及配体卡宾，L和K的配位数，以及配体卡宾和L上的电荷，条件是n 包含这些过渡金属络合物的OLED，包含这些过渡金属络合物的发光层，包含该发光层的OLED，包含根据本发明的OLED的器件和特定的过渡金属络合物，其包含 至少两个卡宾配体。