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公开(公告)号：US3294631A
公开(公告)日：1966-12-27
申请号：US42201164
申请日：1964-12-29
Applicant: BAYER AG
Inventor： WALTER LORENZ , REIMER COLLN , GERHARD SCHRADER , GUNTER UNTERSTENHOFER
IPC: A01N57/16 , C07F9/6521
CPC classification number: C07F9/65218 , A01N57/16
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2.发明授权Alkyl-or aryl-mercapto-(sulphoxido-, sulphono-) carboxylic acid derivatives of thiophosphoric, thiophosphonic and thiophosphinic acid esters and processes for their production 失效硫代磷酸，硫代膦酸和硫代次膦酸酯的烷基或芳基 - 巯基 - （亚磺酰基，磺酰基）羧酸衍生物及其生产方法
公开(公告)号：US3229000A
公开(公告)日：1966-01-11
申请号：US27608763
申请日：1963-04-26
Applicant: BAYER AG
Inventor： WALTER LORENZ , HANS-GERD SCHICKE , GERHARD SCHRADER
CPC classification number: C07F9/4075 , C07F9/1651 , C07F9/2408 , C07F9/3264 , C07F9/4438
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3.发明授权Alkoxy carbonyl, amino carbonyl and cyano derivatives of alkyl or aryl mercapto, sulphono or sulphoxido ethyl esters of thio-phosphorus acids 失效烷基或芳基巯基的烷氧基羰基，氨基羰基和氰基衍生物，硫代磷酸的磺酰基或亚磺酰基乙酯
公开(公告)号：US3228999A
公开(公告)日：1966-01-11
申请号：US20131962
申请日：1962-06-11
Applicant: BAYER AG
Inventor： HANS-GERD SCHICKE , WALTER LORENZ , GERHARD SCHRADER
CPC classification number: C07F9/4075 , C07C323/00 , C07F9/3264 , C07F9/4438
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公开(公告)号：US3223754A
公开(公告)日：1965-12-14
申请号：US7230560
申请日：1960-11-29
Applicant: BAYER AG
Inventor： REIMER COLIN , GERHARD SCHRADER
IPC: C07F9/40
CPC classification number: C07F9/4006
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公开(公告)号：US3213122A
公开(公告)日：1965-10-19
申请号：US6529660
申请日：1960-10-27
Applicant: BAYER AG
Inventor： GERHARD SCHRADER
CPC classification number: C07F9/40 , A01N57/10 , C07F9/1651 , C07F9/18
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Patent Agency Ranking6.发明授权
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公开(公告)号：US3184465A
公开(公告)日：1965-05-18
申请号：US1195160
申请日：1960-03-01
Applicant: BAYER AG
Inventor： GERHARD SCHRADER
CPC classification number: C07F9/42 , C07F9/44 , C07F9/564 , C07F9/5721 , C07F9/591 , C07F9/6533
Abstract: The invention comprises thionophosphoric acid fluoroamides of formula where R and R1 are C1-6 aliphatic hydrocarbyl or cycloaliphatic hydrocarbyl and R2 is hydrogen or C1-6 aliphatic hydrocarbyl, or R1 and R2 together with the nitrogen may form a heterocyclic ring which may contain further hetero atoms. They are prepared by reacting a thionophosphonic acid difluoride with an amine R1R2NH in the presence of an acid binding agent which may be excess amine reactant. The products are insecticides. Methylthionophosphonic acid difluoride required as a starting material is prepared by adding methylthionophosphonic acid dichloride rapidly to a mixture of antiminous fluoride and sodium fluoride or by the dropwise addition of a chlorobenzene solution of the dichloride to a chlorobenzene/sodium fluoride mixture while heating. Other phosphonic acid difluorides are said to be prepared similarly.ALSO:Insecticidal compositions contain as active ingredient a thionophosphoric acid fluoroamide of formula where R and R1 are C1-6 aliphatic hydrocarbyl or cycloaliphatic hydrocarbyl and R2 is hydrogen or C1-6 aliphatic hydrocarbyl, or R1 and R2 together with the nitrogen may form a heterocyclic ring which may contain further hetero atoms, in admixture with a solid or liquid carrier.
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公开(公告)号：US3076012A
公开(公告)日：1963-01-29
申请号：US14985561
申请日：1961-11-03
Applicant: BAYER AG
Inventor： HANS-GERD SCHICKE , GERHARD SCHRADER
CPC classification number: C07F9/32 , C07F9/3808
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公开(公告)号：US3060217A
公开(公告)日：1962-10-23
申请号：US76572558
申请日：1958-10-07
Applicant: BAYER AG
Inventor： GERHARD SCHRADER
IPC: C07F9/165
CPC classification number: C07F9/1651
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公开(公告)号：US3004980A
公开(公告)日：1961-10-17
申请号：US60799556
申请日：1956-09-05
Applicant: BAYER AG
Inventor： GERHARD SCHRADER
CPC classification number: C07F9/5728 , C07F9/1651
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