Abstract:
Supported Ziegler-Natta ethylene polymerisation procatalyst comprising special bi-(oxygen containing ring) compounds as internal donor, as well as a process for preparing the same and use of such a procatalyst for preparing a catalyst system used in the polymerisation of ethylene for producing high molecular weight polyethylenes.
Abstract:
The present invention is concerned with a process for polymerizing ethylene or copolymerizing ethylene and at least one alpha-olefin comonomer in the presence of a supported polymerization catalyst in a multi-stage process in which the last polymerization stage is a gas phase reactor, the use of said process for reducing particle carry-over in the last polymerization stage and the use of a supported polymerization catalyst with a certain median particle size to polymerize an ethylene homo- or copolymer in said multi-stage process with a span of its particle size distribution which can be predicted from the median particle size of the catalyst.