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公开(公告)号：US20220098136A1
公开(公告)日：2022-03-31
申请号：US17433118
申请日：2019-02-22
申请人： BP P.L.C. , BP (CHINA) HOLDINGS LTD
摘要： A process for dehydrating methanol to dimethyl ether product in the presence of a catalyst and a promoter, wherein the catalyst is at least one aluminosilicate zeolite, and the promoter is selected from one or more compounds of Formula I: (I) wherein each of X and any or all of the Y's may independently be selected from hydrogen, halide, a substituted or unsubstituted hydrocarbyl substituent, or a compound of the formula —CHO, —CO2R, —COR, or —OR, where R is hydrogen or a substituted or unsubstituted hydrocarbyl substituent, and wherein the molar ratio of promoter to methanol is maintained at less than 1.
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公开(公告)号：US20200262774A1
公开(公告)日：2020-08-20
申请号：US16645610
申请日：2018-08-23
申请人： BP P.L.C. , BP (CHINA) HOLDINGS LTD
IPC分类号： C07C41/09
摘要： A process for dehydrating methanol to dimethyl ether product in the presence of an aluminosilicate zeolite catalyst and a promoter selected from (i) aldehyde of formula R1CHO (Formula I) in which R1 is hydrogen, a C1-C11 alkyl group or a C3-C11 alkyl group in which 3 or more carbon atoms are joined to form a ring; or (ii) acetal derivative of an aldehyde of Formula I; and the molar ratio of promoter to methanol is maintained at 0.1 or less.
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公开(公告)号：US20220185755A1
公开(公告)日：2022-06-16
申请号：US17433135
申请日：2019-02-22
申请人： BP P.L.C. , BP (CHINA) HOLDINGS LTD
摘要： A process for dehydrating methanol to dimethyl ether product in the presence of a catalyst and a promoter, wherein the catalyst is at least one aluminosilicate zeolite, wherein:—the aluminosilicate zeolite is selected from: (i) a zeolite having a 2-dimensional framework structure comprising at least one channel having a 10-membered ring, and having a maximum free sphere diameter of at least 4.8 Angstroms; (ii) a zeolite having a 3-dimensional framework structure comprising at least one channel having a 10-membered ring; or (iii) a zeolite comprising at least one channel having a 12-membered ring;—the promoter is selected from one or more compounds of Formula I: (I) wherein Y is selected from a C1-C4 hydrocarbyl substituent, and wherein each of X and any or all of the Z's may independently be selected from hydrogen, halide, a substituted or unsubstituted hydrocarbyl substituent, or a compound of the formula —CHO, —CO2R, —COR, or —OR, where R is hydrogen or a substituted or unsubstituted hydrocarbyl substituent, and wherein the molar ratio of promoter to methanol is maintained at less than 1.
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