Process for manufacturing butadiene-isoprene copolymer
    2.
    发明授权
    Process for manufacturing butadiene-isoprene copolymer 失效
    制备丁二烯 - 异丙苯共聚物的方法

    公开(公告)号:US3649607A

    公开(公告)日:1972-03-14

    申请号:US3649607D

    申请日:1969-05-06

    CPC分类号: C08F236/04 C08F4/7095

    摘要: BUTADIENE-ISOPRENE COPOLYMER HAVING A BUTADIENE UNIT OF AT LEAST 90% OF CIS-1,4 STRUCTURE AND AN ISOPRENE UNIT OF AT LEAST 95% OF 1,4-STRUCTURE IS PRODUCED BY COPOLYMERIZING BUTADIENE AND ISOPRENE BY MEANS OF THREE COMPONENT CATALYST CONSISTING OF (A) A COMPOUND SELECTED FROM THE GROUP CONSISTING OF AN ORGANIC CARBOXYLIC ACID SALT AND AN ORGANIC COMPLEX COMPOUND OF NICKEL, (B) A COMPOUND SELECTED FROM THE GROUP CONSISTING OF BORON TRIFLUORIDE AND ITS COMPLEX COMPOUND WITH AN OXYGENCONTAINING ORGANIC COMPOUND AND (C) AN ORGANOMETALLIC COMPOUND SELECTED FROM THE GROUP CONSISTING OF TRIALKYLALUMINUM, DIALKYLZINC, ALKYLLITHIUM AND DIALKYLALKOXYALUMINUM, BUTADIENE/ISOPRENE FEED RATIO BEING IN THE RANGE OF 90/10-70/30 (MOLE RATIO), THE MOLE RATIO OF SAID (C)-COMPONENT TO SAID (A)-COMPONENT BEING AT LEAST 0.5 AND THE MOLE RATIO OF SAID (C)-COMPONENT TO SAID (B)-COMPONENT BEING WITHIN THE RANGE OF 0.5 TO 2.0.