摘要:
BUTADIENE-ISOPRENE COPOLYMER HAVING A BUTADIENE UNIT OF AT LEAST 90% OF CIS-1,4 STRUCTURE AND AN ISOPRENE UNIT OF AT LEAST 95% OF 1,4-STRUCTURE IS PRODUCED BY COPOLYMERIZING BUTADIENE AND ISOPRENE BY MEANS OF THREE COMPONENT CATALYST CONSISTING OF (A) A COMPOUND SELECTED FROM THE GROUP CONSISTING OF AN ORGANIC CARBOXYLIC ACID SALT AND AN ORGANIC COMPLEX COMPOUND OF NICKEL, (B) A COMPOUND SELECTED FROM THE GROUP CONSISTING OF BORON TRIFLUORIDE AND ITS COMPLEX COMPOUND WITH AN OXYGENCONTAINING ORGANIC COMPOUND AND (C) AN ORGANOMETALLIC COMPOUND SELECTED FROM THE GROUP CONSISTING OF TRIALKYLALUMINUM, DIALKYLZINC, ALKYLLITHIUM AND DIALKYLALKOXYALUMINUM, BUTADIENE/ISOPRENE FEED RATIO BEING IN THE RANGE OF 90/10-70/30 (MOLE RATIO), THE MOLE RATIO OF SAID (C)-COMPONENT TO SAID (A)-COMPONENT BEING AT LEAST 0.5 AND THE MOLE RATIO OF SAID (C)-COMPONENT TO SAID (B)-COMPONENT BEING WITHIN THE RANGE OF 0.5 TO 2.0.
摘要:
A PROCESS FOR MANUFACTURING RUBBERY OR PLASTIC BUTADIENE GRAFT-COPOLYMERS HAVING A CIS-1, 4 CONTENT OF AT LEAST 85% AND SUBSTANTIALLY NO GEL, WHICH COMPRISES POLYMERISING BUTADIENE, AND COPOLYMERIZING STYRENE AT A TEMPERATURE OF FROM 80* C. TO 180*C., WITH A CATALYST SYSTEM CONSITING OF (A) AN ORGANIC CARBOXYLIC ACID SALT OF NICKEL, (B) A BORON TRIFLUORIDE ETHERATE AND (C) A TRIALKYLALUMINUM.