摘要:
1. A PROCESS OF PREPARING FIBERS OF POLYOLEFINS COMPRISING POLYMERIZING AN OLEFIN IN THE PRESENCE OF A COORDINATION CATALYST SYSTEM IN A REACTION MEDIUM WHOSE SOLUBILITY PARAMETER IS SUCH THAT ($S-$P)2 IS LESS THAN ABOUT 3.0 CAL./CC. AND AT A TEMPERATURE LESS THAN THE MELT DISSOLUTION TEMPERATURE OF THE POLYOLEFIN TO BE FORMED, AND SUBJECTING SAID POLYMERIZATION SOLUTION TO A POSITIVE SHEAR STRESS OF GREATER THAN ABOUT ZERO POUND (FORCE)/ SQUARE FOOT UP TO ABOUT 0.1 POUND (FORCE)/SQUARE FOOT DURING POLYMERIZATION, THE MAGNITUDE OF SAID SHEAR STRESS BEING SUFFICIENTLY GREAT TO PRECIPITATE THE POLYOLEFIN AS A FIBROUS GEL HAVING A FIBRILLAR STRUCTURE OF FIBROUS POLYOLEFIN IN WHICH THE INTERCONNECTING CAPILLARY SPACES ARE FILLED WITH REACTION MEDIUM, SAID MAGNITUDE SHEAR STRESS BEING LESS THAN THAT AMOUNT WHICH WOULD CAUSE THE DIRECT FORMATION OF A SUBSTANTIAL AMOUNT OF DISCRETE FIBERS DIRECTLY RECOVERABLE WITHOUT REQUIRING FURTHER PROCESSING STEPS, AND SUBSEQUENTLY SUBJECTING SAID FIBROUS GEL FORMED DURING POLYMERIZATION TO A SHEAR STRESS OF GREATER THAN ABOUT 0.1 POUND (FORCE)/SQUARE FOOT, THEREBY PRODUCING DISCRETE, DIRECTLY RECOVERABLE, POLYOLEFIN FIBERS WITHOUT REQUIRING FURTHER PROCESSING STEPS.
摘要:
1. A PROCESS FOR DETERMINING THE PROPORTION OF MONOMERS IN A COPOLYMER, WHEREIN THE MONOMERS HAVE DIFFERENT DIELECTRIC CONSTANTS, SAID PROCESS COMPRISING CONTACTING A CAPACITIVE DETECTOR RESPONSIVE TO THE DIELECTRIC CONSTANT OF FLUIDS WITH A FLUID STREAM OF SAID COPOLYMER IN A ZONE OF RELATIVELY CONSTANT TEMPERATURE AND PRESSURE,
MEASURING THE CAPACITANCE OF THE CAPACITIVE DETECTOR WHILE IN CONTACT WITH THE FLUID STREAM AND COMPARING THE VALUE OF THE CAPACITANCE SO MEASURED WITH A PREDETERMINED REFERENCE VALUE.
摘要:
THE INTERPOLYMERIZATION OF ETHYLENE AND PROPYLENE ALONE OR WITH OTHER DIFFERENT MONOMERS COPOLYMERIZABLE THEREWITH IN THE PRESENCE OF A ZIEGLER POLYMERIZATION CATALYST TO FORM A SOLID POLYMER. THE ETHYLENE AND PROPYLENE MUST BE PRESENT IN RELATIVE PROPORTIONS RANGING BETWEEN 10:90% AND 90:10% BY WEIGHT. PREFERRED ZIEGLER CATALYSTS ARE THOSE FORMED BY MIXING AN ORGANO-METAL COMPOUND, SUCH AS AN ORGANO ALUMINUM COMPOUND, AS FOR EXAMPLE, AN ALUMINUM TRIALKYL, OR AN ALUMINUM ALKYL HALIDE WITH A COMPOUND SUCH AS A SALT OF A METAL OF GROUP IV-B, V-B, OR VI-B OF THE PERIODIC SYSTEM, INCLUDING THORIUM AND URANIUM.
摘要:
A TWO-STAGE METHOD OF GRAFTING ON EPM OR EPDM RUBBER TO MAKE A TOUGH, IMPACT-RESISTANT GUM PLASTIC: (I) A PORTION ONLY OF RESIN FORMING MONOMER (E.G., STYRENE, ACRYLONITRILE) IS FIRST "PREGRAFTED" IN SOLUTION ON THE EPM OR EPDM RUBBER SPINE; (II) THE REMAINING AMOUNT OF RESIN-FORMING MONOMER IS COMBINED WITH THE LIGHTLY GRAFTED RUBBER, AND SUBJECTED TO FURTHER GRAFT POLYMERIZATION TO PRODUCE THE FINAL GUM PLASTIC. NEW GRAFT COPOLYMERS OF RESIN-FORMING MONOMERS ON ETHYLENE/PROPYLENE/5-ETHYLIDENE-2 - NORBORNENE TERPOLYMER RUBBER ARE ALSO DISCLOSED.
摘要:
In a process in which a C5 fraction from a cracked naphtha or gas oil is polymerised with the help of a Friedel-Crafts catalyst to produce a petroleum resin, the C5 fraction is first heated to a temperature of 160* to 250*C for a period of up to 5 hours and is then held at a temperature in the range 100* to 160*C for a further period of up to 5 hours.
摘要:
SUBSTANTIALLY GEL-FREE, HIGH MOLECULAR WEIGHT, HIGH UNSATURATION COPOLYMERS OF ISOBUTYLENE AND CONJUGATED DIENES HAVING A NUMBER AVERAGE MOLECULAR WEIGHT OF AT LEAST 120,000 AND A MOLE PERCENT OF UNSATURATION OF AT LEAST 5% AND THE PROCESS FOR PREPARING SAID POLYMERS WHICH COMPRISES CARRYING OUT THE POLYMERIZATION IN A HOMOGENOUS PHASE, INTRODUCING THE CATALYST COMPRISING AN ALUMINUM HALIDE TO THE SYSTEM IN A SOLUBLE FORM AND CARRYING THE REACTION OUT AT A TEMPERATURE OF LESS THAN -100*C.
摘要:
COPOLYMERS OF ETHYLENE WITH VINYL MONOMERS, WHICH ARE DERIVATIVES OF VINYLTIN OF THE GENERAL FORMULA
CH2=CHSNR1R2R3
WHEREIN R1, R2, R3 ARE THE SAME OR DIFFERENT RADICALS: ALKYLS WITH THE NUMBER OF CARBON ATOMS FROM 1 TO 6, OR PHENYL, THE CONTENT OF ( -CH2-CH(SNR1R2R3)-) LINKS IN THE CPOLYMER BEING 1-30 MOL. PERCENT, AND THAT OF (-CH2-CH2- ) LINKS, 99-70 MOL. PERCENT. SAID COPOLYMERS ARE PRODUCED BY A METHOD WHICH INCUDED COPOLYMERIZING ETHYLENE WITH DERIVATIVES OF VINYLTIN OF THE ABOVESPECIFIED GENERAL FORMULA AT A MOLAR RATIO OF ETHYLENE TO ORGANOVINYLTIN MONOMERS EQUAL TO 20-98:80-2 RESPECTIVELY, UNDER A PRESSURE OF 50-3000 ATM., AT A TEMPERATURE OF 50-300* C., IN THE PRESENCE OF INITIATORS OF FREERADICAL TYPE. THE COPOLYMERS THUS PRODUCED CAN BE USED AS ANTIWEAR ADDITIONS TO LUBRICANTS.
摘要:
A PROCESS FOR THE PREPARATION OF POLYETHYLENE WHICH COMPRISES POLYMERIZING ETHYLENE IN SOLUTION PHASE (THE SOLUTION PHASE EXCLUDES A POLYMER OR COPOLYMER EXISTING IN SOLID PHASE, BUT INCLUDED SUCH POLYMER IN MOLTEN STATE), IN A POLYMERIZATION SOLVENT OF LINEAR OR CYCLIC PENTANE, HEXANE, OR HEPTANE IN THE PRESENCE OF A CARRIER-SUPPORTING ZIEGLER CATALYST, WHILE MAINTAINING THE POLYMER CONCENTRATION IN THE POLYMERIZATION SYSTEM AT NOT HIGHER THAN 20% BY WEIGHT AND CONTROLLING THE POLYMERIZATION TEMPERATURE BY FORCEDLY CIRCULATING AN INERT GAS THROUGH THE POLYMERIZATION ZONE; SUBJECTING THE LIQUID PHASE REACTION PRODUCT CONTAINING THE FORMED ETHYLENE POLYMER OR COPOLYMER IN MOLTEN STATE TO A LOWER PRESSURE NOT HIGHER THAN THE POLYMERIZATION PRESSURE, WHICH ALLOWS VAPORI-
ZATION OF THE SOLVENT IN THE LIQUID PHASE, TO EVAPORATE AND SEPARATE THE SOLVENT; AND RECOVERING THE SOFTENED OR MOLTEN STATE ETHYLENE POLYMER OR COPOLYMER FROM WHICH THE SOLVENT HAS BEEN REMOVED.
摘要:
IN ACCORDANCE WITH CERTAIN OF ITS ASPECTS, THE NOVEL METHOD OF THIS INVENTION FOR RECOVERING UNREACTED HIGHER ALPHA-OLEFIN FROM A LIQUID EFFUENT EXITING A POLYMERIZATION REACTION CONTAINING CATALYST, UNREACTED ETHYLENE, UNREACTED HIGHER ALPHA-OLEFIN, AND A CEMENT OF ETHYLENEHIGHER ALPHA-OLEFIN COPOLYMER IN A LIQUID DILUENT-SOLVENT WHEREIN SAID HIGHER ALPHA-OLEFIN HAS A BOILING POINT AT LEAST 50*C. BELOW THE BOILING POINT OF SAID DILUENT-SOLVENT MAY COMPRISE: (A) WITHDRAWING SAID LIQUID EFFUENT FROM SAID POLYMERIZATION REACTION; (B) DIRECTLY FLASHING SAID LIQUID EFFUENT THEREBY SEPARATING, AS OVERHEAD, DILUENT-SOLVENT AND UNREACTED ETHYLENE AND UNREACTED HIGHER ALPHA-OLEFIN AND, AS BOTTOMS, A CONCENTRATED POLYMER CEMENT CONTAINING A MINOR PORTION OF UNREACTED HIGHER ALPHA-OLEFIN; (C) RECOVERING SAID UNREACTED HIGHER ALPHA-OLEFIN; AND (D) RECOVERING SAID CONCENTRATED POLYMER CEMENT.
摘要:
The preparation of interpolymers of ethylene by interpolymerization of ethylene, an unsaturated organo silane and a monoolefin and with or without a polyene in the presence of a Ziegler type catalyst, particularly to produce uniquely modified polymers from the post-reaction between nucleophiles and the hydrolyzable groups that remain attached to the silicon atom in the interpolymer.