Abstract:
A supported catalyst composition comprising a metal catalyst nanodispersed in a support that is a hard disordered carbon or carbon glass; or a partially graphitized or disordered carbon intercalation complex; or nullhouse-of-cardsnull transition metal dichalcogenide such as molybdenum disulfide (MoS2). Also disclosed are embodiments based on the above supported catalyst compositions, wherein the metal catalyst is Pt or Pt alloy, and wherein the nullporesnull comprised in the support are engineered to provide selective access to H2, but not to larger molecules, such as CO or H2O. Disclosed are methods for improving catalyst utilization, resistance to poisoning, and resistance of catalyst supports to corrosion-as well as products related thereto. Also disclosed is an MEA that comprises the supported, nanodispersed Pt and Pt alloy catalyst compositions of this invention, and a fuel cell that contains such an MEA.
Abstract:
An ion-exchange membrane may be continuously coated by depositing a catalyst composition on a release surface, drying the catalyst at an elevated temperature and then transferring the dried catalyst layer onto an ion-exchange membrane by applying pressure at a different elevated temperature. Also disclosed is an apparatus for thus continuously coating an ion-exchange membrane. The catalyst coated membrane is of particular use in polymer electrolyte membrane (PEM) fuel cells for which a membrane electrode assembly may be prepared by bonding fluid distribution layers to the catalyst coated membrane.