摘要:
A method of determining or predicting a value P.sub.x of a property of a material X, which is a feed to a process or a property of a product of a process from said material or yield of said process, which method comprises measuring the absorption D.sub.i x of said material at more than one wavelength in the region 600-2600 nm, comparing the said absorptions or a derivative thereof with absorptions D.sub.i m or derivatives thereof at the same wavelength for a number of standards S in a bank for which the said property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m said standard having the smallest average value of the absolute difference at each wavelength i between the absorption D.sub.i x (or derivative thereof) for the material and the absorption D.sub.i m (or derivative thereof) for the standards S.sub.m to obtain P.sub.x, with averaging of said properties or yields P.sub.m when more than one standard S.sub.m is chosen, and wherein said process is at least one of polymerization, an oligomerization or an organic reaction in which at least one of the reactant and a product is a functionalized compound.
摘要:
A method of determining or predicting a value P.sub.x of a property (e.g. octane number) of a material X or a property of a product of a process from the material or yield of the process for example a blending, separation, or chemical (e.g. polymerization) process, which method comprises measuring the absorption D.sub.ix of the material at more than one wavelength in the region 600-2600 nm, comparing the the signals indicative of the absorptions or a derivative thereof with signals indicative of absorptions D.sub.im or derivatives thereof at the same wavelength for a number of standards S in a bank for which the property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m the standard having the smallest average value of the absolute difference at each wavelength i between the signal for the material and the signal for the standard S.sub.m to obtain P.sub.x, with averaging of the properties or yields P.sub.m when more than one standard S.sub.m is chosen. If desired the method can be used as such to control the process by comparison of P.sub.m with the desired value and adjustment of the process to minimize deviations from P.sub.m ; in an alternative process the signal (or function thereof) of the standard(s) with the smallest average value of the absolute difference may be used directly to control the process.
摘要:
An apparatus for on-line measuring physical property data of hydrocarbon products such as octane number, cetane number, density, vapour pressure and the like or gasoline/alcohol ratio, comprising means for providing (N)IR radiation in a predetermined spectral range; means for transmitting light at selected wavelengths in the (N)IR spectral region; means for delivering light from said transmitting means to a hydrocarbon product line; means for allowing an optical path length in the hydrocarbon product line; means for detecting the light transmitted through the said optical path; means for providing the obtained signal to be input to processing equipment for spectral analysis and correlating the spectral data to the physical property data of hydrocarbon products such as octane number, cetane number, density, vapour pressure and the like or gasoline/alcohol ratio.
摘要:
A method of determining or predicting a value P.sub.x of a property of a feed X to a steam cracking process or yield of said process, which method comprises measuring the absorption D.sub.ix of said material at more than one wavelength in the region 600-2600 nm, comparing signals indicative of said adsorptions or a mathematical function thereof with signals indicative of absorptions D.sub.im or mathematical function thereof at the same wavelength for a number of standards S in a bank for which the said property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m said standard having the smallest average value of the absolute difference at each wavelength i between the signal for the material and the signal for the standard S.sub.m to obtain P.sub.x, with averaging of said properties or yields P.sub.m when more than one standard S.sub.m is chosen. If desired the method can be used as such to control the steam cracking process by comparison of P.sub.m with the desired value and adjustment of the process to minimize deviations from P.sub.m ; in an alternative process the signal (or function thereof) of the standard(s) with the smallest average value of the absolute difference may be used directly to control the process.
摘要:
A method of determining or predicting a value P.sub.x of a property of a material X, which is a feed to a process or a property of a product of a process from said material or yield of said process, which method comprises measuring the absorption D.sub.i x of said material at more than one wavelength in the region 600-2600 nm, comparing the said absorptions or a derivative thereof with absorptions D.sub.i m or derivatives thereof at the same wavelength for a number of standards S in a bank for which said property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m said standard having the smallest average value of the absolute difference at each wavelength i between the absorption D.sub.i x (or derivative thereof) for the material and the absorption D.sub.i m (or derivative thereof) for the standard S.sub.m to obtain P.sub.x, with averaging of said properties or yields P.sub.m when more than one standard S.sub.m is chosen, and wherein said material X is a composition comprising part of a lubricating oil fraction obtainable from a vacuum distillation of oil.
摘要:
A method of determining or predicting a value P.sub.x of a property (e.g. octane number) of a material X or a property of a product of a process from said material or yield of said process, which method comprises measuring the absorption D.sub.ix of said material at more than one wavelength in the region 600-2600 nm, comparing the said absorptions or a derivative thereof with absorptions D.sub.im or the derivatives thereof at the same wavelength for a number of standards S in a bank for which the said property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m said standard having the smallest average value of the absolute difference at each wavelength i between the absorption D.sub.i x (or derivative thereof) for the material and the absorption D.sub.i m (or derivative thereof) for the standard S.sub.m to obtain the P.sub.x, with averaging of said properties or yields P.sub.m when more than one standard S.sub.m is chosen.
摘要:
The present invention relates to a continuous process for the polymerization of an alpha-olefin having from 2 to 12 carbon atoms, which is carried out in a gas phase polymerization reactor by bringing a gaseous reaction mixture, containing the alpha-olefin to be polymerized, into contact with a catalyst system of the Ziegler-Natta type consisting of a solid catalyst comprising at least one compound of a transition metal belonging to groups IV, V or VI of the Periodic Table, of the elements, and of a cocatalyst comprising at least one organometallic compound of a metal belonging to groups II or III of the Periodic Table in which the polymerization reactor is fed with alpha-olefin at a constant rate.
摘要:
A surgical retractor assembly that utilizes a tubular shaft and a connection nub. A pivot joint connects one end of the tubular shaft to the connection nub. The pivot joint enables the connection nub to move relative the tubular shaft along a path that is coplanar to the axis of the tubular shaft. Together, the tubular shaft and the connection nub create an elongated element that can be introduced into a small incision. A retractor blade is provided. A bearing joint extends from the retractor blade. The retractor blade and bearing joint are introduced into a surgical site independent of the elongated element. Within the surgical site, the connection nub interconnects with the bearing joint, therein joining the retractor blade to the tubular shaft and a handle.
摘要:
A surgical retractor assembly that utilizes a tubular shaft and a connection nub. A pivot joint connects one end of the tubular shaft to the connection nub. The pivot joint enables the connection nub to move relative the tubular shaft along a path that is coplanar to the axis of the tubular shaft. Together, the tubular shaft and the connection nub create an elongated element that can be introduced into a small incision. A retractor blade is provided. A bearing joint extends from the retractor blade. The retractor blade and bearing joint are introduced into a surgical site independent of the elongated element. Within the surgical site, the connection nub interconnects with the bearing joint, therein joining the retractor blade to the tubular shaft and a handle.
摘要:
The octane number of a product is directly determined from its near infrared (NIR) absorption spectrum in the wave number spectral range of from 6667 to 3840 centimeter .sup.-1. A number (n) of frequencies is selected within this range, and the (n) absorbance values are correlated with the octane number by using a multivariate regression analysis.