Clay-catalyzed synthesis of aryl-substituted fatty acids and fatty
esters and compositions related thereto
    3.
    发明授权
    Clay-catalyzed synthesis of aryl-substituted fatty acids and fatty esters and compositions related thereto 失效
    芳基取代脂肪酸和脂肪酯的粘土催化合成及其相关组合物

    公开(公告)号:US5440059A

    公开(公告)日:1995-08-08

    申请号:US161826

    申请日:1993-12-02

    摘要: A novel method for preparing an aryl-substituted fatty acid or fatty ester is disclosed. According to the method, an olefinic composition selected from among mono-unsaturated fatty acids, mono-unsaturated fatty esters and mixtures thereof is introduced to a reaction zone comprising a liquid aromatic hydrocarbon and a catalytic amount of a clay catalyst to produce a reaction that is allowed to proceed for a time and at a temperature sufficient to produce a reaction product comprising a desired yield of aryl-substituted fatty acid or fatty ester. Preferably, the introduction of the olefinic composition is conducted slowly, such as over a period of one to four, more preferably, two to four, hours. Related methods and compositions, including xylylstearic acid, are also disclosed.

    摘要翻译: 公开了一种制备芳基取代脂肪酸或脂肪酯的新方法。 根据该方法,将选自单不饱和脂肪酸,单不饱和脂肪酸酯及其混合物的烯烃组合物引入到包含液体芳族烃和催化量的粘土催化剂的反应区中,以产生 允许进行一段时间并在足以产生包含所需产率的芳基取代的脂肪酸或脂肪酯的反应产物的温度下进行。 优选地,缓慢地进行烯烃组合物的引入,例如在1-4的时间内,更优选的是2-4小时。 还公开了相关方法和组合物,包括二甲苯基硬脂酸。

    Synthesis of aryl-substituted aliphatic acids
    4.
    发明授权
    Synthesis of aryl-substituted aliphatic acids 失效
    芳基取代脂肪酸的合成

    公开(公告)号:US5034161A

    公开(公告)日:1991-07-23

    申请号:US226242

    申请日:1988-07-18

    IPC分类号: C07C51/353

    CPC分类号: C07C51/353

    摘要: A method for preparation of aryl-substituted aliphatic hydrocarbons is disclosed. The method comprises reacting in the presence of a solid superacid resin catalyst an unsaturated aliphatic hydrocarbon in liquid form with an aromatic hydrocarbon that is susceptible to Friedel-Crafts reaction. The reaction between the liquid unsaturated aliphatic hydrocarbon and the aromatic hydrocarbon produces a reaction product comprising an aryl-substituted aliphatic hydrocarbon.

    摘要翻译: 公开了一种制备芳基取代的脂族烃的方法。 该方法包括在固体超强酸树脂催化剂存在下使液体形式的不饱和脂族烃与易于进行Friedel-Crafts反应的芳族烃反应。 液体不饱和脂族烃与芳族烃之间的反应产生包含芳基取代的脂族烃的反应产物。

    Preparation of .DELTA.-2 tetrahydropyrimidines
    6.
    发明授权
    Preparation of .DELTA.-2 tetrahydropyrimidines 失效
    “-2四氢去酰亚胺的制备

    公开(公告)号:US4146714A

    公开(公告)日:1979-03-27

    申请号:US802347

    申请日:1977-06-01

    摘要: A process of converting 2,3,4,5-tetrahydropyrimidines (.DELTA.-1) having at least one hydrogen in the 2-position to 3,4,5,6-tetrahydropyrimidines (.DELTA.-2), which comprises hydrogenating and dehydrogenating said .DELTA.-1 tetrahydropyrimidines. Such hydrogenating and dehydrogenating may be done in either two sequential steps or in one step.Said .DELTA.-1 tetrahydropyrimidines can also be converted to .DELTA.-2 tetrahydropyrimidines by heating in the essential absence of a solvent, and preferably under basic conditions.In addition, corresponding hexahydropyrimidines can be converted to corresponding .DELTA.-2 tetrahydropyrimidines by dehydrogenation.This invention also relates to the use of .DELTA.-2 tetrahydropyrimidines, particularly as corrosion inhibitors.