Thermoplastic elastomer carbon monoxide/olefin copolymers
    1.
    发明授权
    Thermoplastic elastomer carbon monoxide/olefin copolymers 失效
    热塑性弹性体一氧化碳/烯烃共聚物

    公开(公告)号:US06251518B1

    公开(公告)日:2001-06-26

    申请号:US09297919

    申请日:1999-05-12

    IPC分类号: D02G300

    摘要: Linear, thermoplastic, elastomeric copolymers comprise carbon monoxide and at least one olefinic C7- to C20-monomer and have an average molecular weight Mw greater than 15,000 g/mol and a Tg-value of less than −20° C., and comprise carbon monoxide, at least one olefinic C2- to C4-monomer and at least one olefinic C6- to C20-monomer and have an average molecular weight Mw greater than 40,000 g/mol and a Tg-value of less than 20° C.

    摘要翻译: 线性,热塑性弹性体共聚物包括一氧化碳和至少一种烯烃C 7 -C 20单体,其平均分子量Mw大于15,000g / mol,Tg值小于-20℃,并且包含碳 一氧化碳,至少一种烯烃C 2 -C 4单体和至少一种烯烃C 6 -C 20单体,其平均分子量Mw大于40,000g / mol,Tg值小于20℃。

    Production of homocopolymers, co-polymers or block copolymers from cycloolefinicmonomer units
    2.
    发明授权
    Production of homocopolymers, co-polymers or block copolymers from cycloolefinicmonomer units 失效
    由环烯单体单元生产均聚物,共聚物或嵌段共聚物

    公开(公告)号:US06262194B1

    公开(公告)日:2001-07-17

    申请号:US09402541

    申请日:1999-10-06

    IPC分类号: C08F204

    CPC分类号: C08F297/06 C08F32/00

    摘要: The invention relates to the production of homopolymers, co-copolymers or block copolymers from cycloolefinic monomer units characterized in that polymerization occurs in the presence of a catalyst of general formula (I), and optionally in the presence of an additive, wherein the substituents and indices have the following meaning: M is a metal from group VIII B of the periodic table of elements; E1, E2 are independently from each other an element from group V A of the periodic table of elements; Z is a bridging structural unit; Ar stands for annelated aryl units independent of each other; L1, L2 stands for formally uncharged Lewis base ligands; X means monovalent or bivalent anions; k means 1 or 2; l, m, n represent 1 or 2, whereby m×n=1.

    摘要翻译: 本发明涉及由环烯类单体单元生产均聚物,共聚物或嵌段共聚物,其特征在于聚合在通式(I)的催化剂存在下进行,并且任选地在添加剂存在下进行,其中取代基和 指数具有以下含义:M是元素周期表第VIIIB族的金属; E1,E2彼此独立地为元素周期表第ⅤA族元素; Z是桥接结构单元; Ar代表彼此独立的芳环单元; L1,L2代表正式不带电的路易斯碱配体; X表示一价或二价阴离子; k表示1或2; l,m,n表示1或2,由此mxn = 1。