Process for producing natural cis-3-hexenol from unsaturated fatty acids
    3.
    发明授权
    Process for producing natural cis-3-hexenol from unsaturated fatty acids 失效
    从不饱和脂肪酸生产天然顺-3-己烯醇的方法

    公开(公告)号:US5620879A

    公开(公告)日:1997-04-15

    申请号:US497146

    申请日:1995-06-30

    CPC分类号: C07C33/025 C12P7/04

    摘要: The present invention relates to a process for producing cis-3-hexen-1-ol from an unsaturated fatty acid, in which said synthesis is carried out from the latter by the combined action of a natural system of enzyme(s) allowing the oxidation of said fatty acid to cis-3-hexenal and of a yeast allowing the reduction of cis-3-hexenal to cis-3-hexenol in a culture medium. According to a first characteristic of the present invention, the enzymatic system consists of a plant mass obtained by grinding leaves harvested whole without predilacerating them. According to a second characteristic of the present invention, the enzymatic system is introduced in the form of a ground cellular product obtained by grinding followed by cell disintegration. Finally, advantageously, a reagent chosen from a ferrous cation, acetylsalicylic acid, chlorophyll B and the enzyme catalase, makes it possible to increase the yields of cis-3-hexenol.

    摘要翻译: 本发明涉及从不饱和脂肪酸生产顺式-3-己烯-1-醇的方法,其中所述合成通过允许氧化的酶的天然体系的组合从后者进行 的所述脂肪酸转化为顺式-3-己烯醛,以及允许在培养基中将顺式-3-己烯醛还原成顺式-3-己烯醇的酵母。 根据本发明的第一特征,酶系统由通过研磨叶片的叶片而获得的植物团块组成,而不会使它们前体化。 根据本发明的第二特征,酶系统以通过研磨获得的研磨细胞产物的形式引入,随后进行细胞分解。 最后,有利地,选自亚铁阳离子,乙酰水杨酸,叶绿素B和酶过氧化氢酶的试剂使得有可能提高顺式-3-己烯醇的产率。