公开(公告)号：US5173556A

公开(公告)日：1992-12-22

申请号：US696414

申请日：1991-05-06

申请人： Frank Mares ,  Bryce C. Oxenrider ,  David J. Long ,  John P. Sibilia

发明人： Frank Mares ,  Bryce C. Oxenrider ,  David J. Long ,  John P. Sibilia

IPC分类号： C08F8/12 ,  C08F214/18 ,  C08F218/04

CPC分类号： C08F214/186 ,  C08F218/04 ,  C08F8/12 ,  C08J5/18 ,  C08F2810/50

摘要： The present invention is directed to a copolymer of a fluoromonomer having the formula R.sub.1 R.sub.2 C.dbd.CR.sub.3 F wherein R.sub.1, R.sub.2 and R.sub.3 are selected from H and F, and R.sub.3 may be Cl when R.sub.1 and R.sub.2 are F; and a vinyl monomer having the formula H.sub.2 C.dbd.CHR.sub.x, wherein R.sub.x is a radical having the formula --O.sub.2 CR.sub.y, wherein R.sub.y is a radical selected from CH.sub.3 and C.sub.2 H.sub.5.The resulting copolymer comprises fluorinated units having the formula (R.sub.1 R.sub.2 C--CR.sub.3 F) wherein R.sub.1, R.sub.2 and R.sub.3 are selected from H and F, and R.sub.3 may be Cl when R.sub.1 and R.sub.2 are F, and corresponding amounts of vinyl units having the formula (H.sub.2 C--CHR.sub.x), wherein R.sub.x is selected from --CH.sub.3 and C.sub.2 H.sub.5. In an alternate and preferred embodiment the copolymer is hydrolyzed so that R.sub.x becomes --OH.

摘要翻译： 本发明涉及式R1R2C = CR3F的含氟单体的共聚物，其中R 1，R 2和R 3选自H和F，当R 1和R 2为F时，R 3可以为Cl; 和具有式H2C = CHRx的乙烯基单体，其中Rx是具有式-O2CRy的基团，其中Ry是选自CH3和C2H5的基团。 所得共聚物包括具有式（R 1 R 2 C-CR 3 F）的氟化单元，其中R 1，R 2和R 3选自H和F，当R 1和R 2为F时，R 3可为Cl，并且相应量的具有式 -CHRx），其中Rx选自-CH 3和C 2 H 5。 在替代和优选的实施方案中，共聚物被水解，使得Rx变成-OH。

公开(公告)号：US5151477A

公开(公告)日：1992-09-29

申请号：US796184

申请日：1991-11-22

申请人： Bryce C. Oxenrider ,  David J. Long ,  Frank Mares

发明人： Bryce C. Oxenrider ,  David J. Long ,  Frank Mares

IPC分类号： C08F2/00 ,  C08F8/12 ,  C08F214/18 ,  C08F218/04

CPC分类号： C08F214/186 ,  C08F218/04 ,  C08F8/12 ,  C08J5/18

摘要： A process of preparing a copolymer of vinyl monomer such as vinyl acetate, vinyl propionate and vinyl trifluoroacetate, and of fluorinated monomers such as tetrafluoroethylene and trifluoroethylene, said copolymer having an alternating or substantially alternating distribution of vinyl recurring monomeric units and fluorinated recurring monomeric units in the copolymer backbone which comprises copolymerizing said monomers in an aqueous reaction medium comprising water and a water miscible organic co-solvent in an amount less than the amount sufficient to form a distinct organic co-solvent phase.

摘要翻译： 一种制备乙酸乙烯酯，丙酸乙烯酯和三氟乙酸乙烯酯的乙烯基单体和氟代单体如四氟乙烯和三氟乙烯的共聚物的方法，所述共聚物具有乙烯基重复单体单元和氟化重复单体单元的交替或基本上交替的分布， 所述共聚物骨架包括使所述单体在包含水和水混溶性有机助溶剂的水性反应介质中的量低于足以形成不同有机共溶剂相的量。

公开(公告)号：US5137999A

公开(公告)日：1992-08-11

申请号：US695677

申请日：1991-05-06

申请人： Bryce C. Oxenrider ,  David J. Long ,  Frank Mares

发明人： Bryce C. Oxenrider ,  David J. Long ,  Frank Mares

IPC分类号： C08F2/00 ,  C08F8/12 ,  C08F214/18 ,  C08F218/04

CPC分类号： C08F214/186 ,  C08F218/04 ,  C08F8/12 ,  C08J5/18 ,  C08F2810/50

摘要： A process of preparing a copolymer of vinyl monomer selected from the group consisting of vinyl acetate, vinyl propionate and vinyl trifluoroacetate, and of fluorinated monomer selected from the group consisting of tetrafluoroethylene and trifluoroethylene, said copolymer having an alternating or substantially alternating distribution of vinyl recurring monomeric units and fluorinated recurring monomeric units in the copolymer backbone which comprises copolymerizing said monomers in an aqueous reaction medium comprising water and a water miscible organic co-solvent in an amount less than the amount sufficient to form a distinct organic co-solvent phase.

摘要翻译： 一种制备乙烯基单体的共聚物的方法，所述乙烯基单体选自乙酸乙烯酯，丙酸乙烯酯和三氟乙酸乙烯酯，以及选自四氟乙烯和三氟乙烯的氟化单体，所述共聚物具有交替或基本交替的乙烯基重复分布 共聚物主链中的单体单元和氟化的重复单体单元，其包括在包含水和水混溶性有机助溶剂的水性反应介质中将所述单体共聚，其量小于足以形成不同有机共溶剂相的量。

公开(公告)号：US5135998A

公开(公告)日：1992-08-04

申请号：US726091

申请日：1991-07-05

申请人： Frank Mares ,  Bryce C. Oxenrider ,  David J. Long ,  John P. Sibilia

发明人： Frank Mares ,  Bryce C. Oxenrider ,  David J. Long ,  John P. Sibilia

IPC分类号： C08F2/00 ,  C08F8/12 ,  C08F214/18 ,  C08F218/04

CPC分类号： C08F214/186 ,  C08F218/04 ,  C08F8/12 ,  C08J5/18 ,  C08F2810/50

摘要： A process of preparing a copolymer of a vinyl monomer such as vinyl acetate, vinyl propionate and vinyl trifluoroacetate, and of fluorinated monomer such as tetrafluoroethylene and trifluoroethylene, said copolymer having an alternating or substantially alternating distributing of vinyl recurring monomeric units and fluorinated recurring monomeric units in the copolymers backbone which comprises copolymerizing said monomers in a reaction medium of a chlorocarbon, a fluorocarbon a chlorofluorocarbon or a mixture thereof.

摘要翻译： 制备乙烯基单体如乙酸乙烯酯，丙酸乙烯酯和三氟乙酸乙烯酯的共聚物和氟化单体如四氟乙烯和三氟乙烯的共聚物的方法，所述共聚物具有乙烯基重复单体单元和氟化重复单体单元的交替或基本上交替的分布 在共聚物主链中，其包括将所述单体在氯碳化合物，氟碳化合物，氯氟烃或其混合物的反应介质中共聚。

公开(公告)号：US5070162A

公开(公告)日：1991-12-03

申请号：US424441

申请日：1989-10-20

申请人： Bryce C. Oxenrider ,  David J. Long ,  Frank Mares

发明人： Bryce C. Oxenrider ,  David J. Long ,  Frank Mares

IPC分类号： C08F2/00 ,  C08F8/12 ,  C08F214/18 ,  C08F218/04

CPC分类号： C08F214/186 ,  C08F218/04 ,  C08F8/12 ,  C08F2810/50

摘要： A process of preparing a copolymer of vinyl monomer selected from the group consisting of vinyl acetate, vinyl propionate and vinyl trifluoroacetate, and of fluorinated monomer selected from the group consisting of tetrafluoroethylene and trifluoroethylene, said copolymer having an alternating or substantially alternating distribution of vinyl recurring monomeric units and fluorinated recurring monomeric units in the copolymer backbone which comprises copolymerizing said monomers in an aqueous reaction medium comprising water and a water miscible organic co-solvent in an amount less than the amount sufficient to form a distinct organic co-solvent phase.

摘要翻译： 一种制备乙烯基单体的共聚物的方法，所述乙烯基单体选自乙酸乙烯酯，丙酸乙烯酯和三氟乙酸乙烯酯，以及选自四氟乙烯和三氟乙烯的氟化单体，所述共聚物具有交替或基本交替的乙烯基重复分布 共聚物主链中的单体单元和氟化的重复单体单元，其包括在包含水和水混溶性有机助溶剂的水性反应介质中将所述单体共聚，其量小于足以形成不同有机共溶剂相的量。

公开(公告)号：US5032656A

公开(公告)日：1991-07-16

申请号：US616487

申请日：1990-11-21

申请人： Frank Mares ,  Bryce C. Oxenrider ,  David J. Long ,  John P. Sibilia

发明人： Frank Mares ,  Bryce C. Oxenrider ,  David J. Long ,  John P. Sibilia

IPC分类号： C08F2/00 ,  C08F8/12 ,  C08F214/18 ,  C08F218/04 ,  C08F14/18

CPC分类号： C08F214/186 ,  C08F218/04 ,  C08F8/12 ,  C08J5/18 ,  C08F2810/50

摘要： The present invention is directed to a copolymer of a fluoromonomer having the formula R.sub.1 R.sub.2 C=CR.sub.3 F wherein R.sub.1, R.sub.2 and R.sub.3 are selected from H and F, and R.sub.3 may be Cl when R.sub.1 and R.sub.2 are F; and a vinyl monomer having the formula H.sub.2 C=CHR.sub.x, wherein R.sub.x is a radical having the formula --O.sub.2 CR.sub.y, wherein R.sub.y is a radical selected from CH.sub.3 and C.sub.2 H.sub.5.The resulting copolymer comprises fluorinated units having the formula (R.sub.1 R.sub.2 C-CR.sub.3 F) wherein R.sub.1, R.sub.2 and R.sub.3 are selected from H and F, and R.sub.3 may be Cl when R.sub.1 and R.sub.2 are F, and corresponding amounts of vinyl units having the formula (H.sub.2 C-CHR.sub.x), wherein R.sub.x is selected from --CH.sub.3 and C.sub.2 H.sub.5. In an alternate and preferred embodiment the copolymer is hydrolyzed so that R.sub.x becomes --OH.

摘要翻译： 本发明涉及式R1R2C = CR3F的含氟单体的共聚物，其中R 1，R 2和R 3选自H和F，当R 1和R 2为F时，R 3可以为Cl; 和具有式H2C = CHRx的乙烯基单体，其中Rx是具有式-O2CRy的基团，其中Ry是选自CH3和C2H5的基团。 所得共聚物包括具有式（R 1 R 2 C-CR 3 F）的氟化单元，其中R 1，R 2和R 3选自H和F，当R 1和R 2为F时，R 3可为Cl，并且相应量的具有式 -CHRx），其中Rx选自-CH 3和C 2 H 5。 在替代和优选的实施方案中，共聚物被水解，使得Rx变成-OH。

公开(公告)号：US5453477A

公开(公告)日：1995-09-26

申请号：US207973

申请日：1994-03-07

申请人： Bryce C. Oxenrider ,  Frank Mares ,  Mo-Shu Yang

发明人： Bryce C. Oxenrider ,  Frank Mares ,  Mo-Shu Yang

IPC分类号： C08F14/24 ,  C08F4/40

CPC分类号： C08F14/24

摘要： Process for the production of PCTFE homopolymer and/or copolymer resins by the use of an aqueous suspension system incorporating a redox initiator system which comprises t-butyl hydroperoxide and sodium metabisulfite to initiate the polymerization or copolymerization process. The process parameters may be controlled to provide a PCTFE homopolymer or copolymer resin having a desired target range of molecular weights. The process provides stable PCTFE polymer suspensions which exhibit a low tendency to coagulate and further exhibit good wettability of the homopolymer and copolymer particles, notably in the absence of soaps.

摘要翻译： 通过使用包含叔丁基过氧化氢和偏亚硫酸氢钠的氧化还原引发剂体系的水性悬浮体系来制备PCTFE均聚物和/或共聚物树脂以引发聚合或共聚过程的方法。 可以控制工艺参数以提供具有期望的目标分子量范围的PCTFE均聚物或共聚物树脂。 该方法提供稳定的PCTFE聚合物悬浮液，其表现出低凝结倾向并且进一步显示均聚物和共聚物颗粒的良好润湿性，特别是在不存在皂的情况下。

公开(公告)号：US4195105A

公开(公告)日：1980-03-25

申请号：US861371

申请日：1977-12-16

申请人： Frank Mares ,  Bryce C. Oxenrider ,  Cyril Woolf, deceased

发明人： Frank Mares ,  Bryce C. Oxenrider ,  Cyril Woolf, deceased

IPC分类号： D06M13/408 ,  B05D3/02

CPC分类号： D06M13/408 ,  Y10T442/2172 ,  Y10T442/2893

摘要： Fluorinated poly-(C.sub.2 to C.sub.10) alkylene polyamides (especially alpha, omega-triazaalkanes) in which the endmost nitrogen atoms are acylated by fluorinated carboxylic acid groups and an interior nitrogen atom is acylated by a dibasic acid moiety of the group consisting of (C.sub.4 to C.sub.14) alkane dioic acid moieties and the thiocarbonic acid moieties --C(.dbd.O)S-- and --CS.sub.2 --; wherein per the invention, a radical is terminally attached to the acylating dibasic acid moiety, of the group --CH.sub.2 CH.sub.2 OH, --CH.sub.2 CH(CH.sub.3)OH, --CH.sub.2 CH(OH)CH.sub.2 X (X being halogen or --CN), or ##STR1## The compounds are amphipathic, behaving like surfactants when incorporated with nylon. They are prepared by broadly known methods of producing esters and thioesters of acids. The stain resistance of fibers incorporating these compounds can be improved as to durability and at least partially restored after abrasion of the fiber, by annealing.

摘要翻译： 通过氟化羧酸基团和内部氮原子酰化最终氮原子的氟化聚（C 2〜C 10）亚烷基聚酰胺（特别是α，ω-三氮杂烷）由（C4〜 至C14）链烷二酸部分和硫代碳酸部分-C（= O）S-和-CS2-; 其中根据本发明，基团与基团-CH 2 CH 2 OH，-CH 2 CH（CH 3）OH，-CH 2 CH（OH）CH 2 X（X为卤素或-CN）的酰化二元酸部分末端连接，或者 化合物是两亲性的，当与尼龙结合时表现为表面活性剂。 它们通过广泛已知的生产酸和硫酸酯的方法制备。 结合这些化合物的纤维的耐污染性可以通过退火来改善耐久性并在纤维磨损后至少部分恢复。

公开(公告)号：US4219625A

公开(公告)日：1980-08-26

申请号：US861383

申请日：1977-12-16

申请人： Frank Mares ,  Bryce C. Oxenrider ,  Cyril Woolf

发明人： Frank Mares ,  Bryce C. Oxenrider ,  Cyril Woolf

IPC分类号： C08K5/103 ,  C07C69/80 ,  C07C69/82 ,  C08G63/76

CPC分类号： C08K5/103 ,  C08K5/10 ,  Y10T428/2969

摘要： As an additive imparting oil and water repellency, durable against laundering and abrasion, to PET fibers: a partially or fully acylated polyol, especially pentaerythritol, glycerol, hydroquinone or ethylene glycol, acylated with a phthalic or terephthalic monoester having a perfluorinated alkyl or alkoxyalkyl C.sub.2 to C.sub.20 radical, especially C.sub.5 to C.sub.10 n-alkyl or (CF.sub.2).sub.n OR.sub.f where R.sub.f is C.sub.1 to C.sub.6 perfluoroalkyl, especially perfluoroisopropyl and (CF.sub.2).sub.n is a straight chain C.sub.2 to C.sub.10 diradical.

摘要翻译： 作为赋予PET纤维耐油和防水性的涂料，对PET纤维：部分或完全酰化的多元醇，特别是季戊四醇，甘油，氢醌或乙二醇，用具有全氟化烷基或烷氧基烷基C2的邻苯二甲酸或对苯二甲酸单酯酰化 特别是C 5〜C 10的正烷基或（CF 2）nOR f，其中R f为C 1〜C 6全氟烷基，特别是全氟异丙基，（CF 2）n为直链C 2〜C 10的双基。

公开(公告)号：US4209610A

公开(公告)日：1980-06-24

申请号：US861372

申请日：1977-12-16

申请人： Frank Mares ,  Bryce C. Oxenrider ,  Cyril Woolf, deceased ,  by Helga Woolf, executrix

发明人： Frank Mares ,  Bryce C. Oxenrider ,  Cyril Woolf, deceased ,  by Helga Woolf, executrix

IPC分类号： C08G63/682 ,  D06M13/408 ,  C08G63/12 ,  C08G69/44 ,  C11C3/00

CPC分类号： D06M13/408 ,  C08G63/682 ,  C08K5/12

摘要： Polycarboxybenzenes esterified with certain partially fluorinated alcohols and with hydroxyl-containing organic radicals such as 2-hydroxyethyl, glyceryl and chlorohydryl or bromohydryl, leaving no free carboxy groups, when incorporated with PET or nylon fibers as by contact in a liquid medium, these compounds concentrate at the fiber surface especially if the fiber is annealed (heated without abrading above its T.sub.g). A relatively durable oil and water repellency is thus imparted to the fiber; which durability can be enhanced by contacting said compound in situ in the fiber with a polyepoxide or polyisocyanate.Alternatively, partially fluorinated N,N-disubstituted amides, esterified also with the same above-cited hydroxyl-containing organic radicals, can be used. The resulting fibers can be dyed, after or together with said treatment imparting repellency.

摘要翻译： 这些化合物浓缩时，与某些部分氟化的醇和含羟基的有机基团如2-羟基乙基，甘油基和氯代氢溴酸根或溴代氢溴酸酯酯化，不含游离羧基的聚羧基苯，当与液体介质接触时与PET或尼龙纤维结合时， 特别是如果纤维退火（加热而不研磨高于其Tg）。 因此赋予纤维相对耐久的防油和防水性; 通过使纤维中的原位与聚环氧化物或多异氰酸酯接触，可以提高耐久性。 或者，可以使用部分氟化的N，N-二取代的酰胺，也可以用相同的上述含羟基的有机基团酯化。 所得到的纤维可以在所述处理赋予斥力之后或之后染色。