Hydrazodicarboxylates and use thereof as blowing agents
    1.
    发明授权
    Hydrazodicarboxylates and use thereof as blowing agents 失效
    二羧酸锌及其作为发泡剂的用途

    公开(公告)号:US3946064A

    公开(公告)日:1976-03-23

    申请号:US566478

    申请日:1975-04-09

    IPC分类号: C08J9/10 C07C69/96

    CPC分类号: C08J9/104

    摘要: Certain hydrazodicarboxylates, namely polymers or oligomers made by reacting hydrazine with polyfunctional haloformates, especially difunctional haloformates, cyclized forms of said oligomers and condensation products of hydrocarbyl carbazates with polyfunctional, especially difunctional, haloformates are useful as chemical blowing agents for expanding gas-expandable polymeric materials. These compounds are novel.

    摘要翻译: 某些肼基二羧酸盐,即通过肼与多官能卤代甲酸酯,特别是双官能卤代甲酸酯反应制得的聚合物或低聚物,所述低聚物的环化形式和烃基碳酸肼与多官能的,特别是双官能的卤代甲酸酯的缩合产物可用作膨胀气体可膨胀聚合材料的化学发泡剂 。 这些化合物是新的。

    Blowing agent composition
    2.
    发明授权
    Blowing agent composition 失效
    发泡剂组成

    公开(公告)号:US4692475A

    公开(公告)日:1987-09-08

    申请号:US940873

    申请日:1986-12-10

    IPC分类号: C08J9/10

    CPC分类号: C08J9/103 Y10S521/909

    摘要: A blowing agent composition, comprising: (i) azodicarbonamide; (ii) zinc oxide and/or zinc carbonate; and (iii) at least one member selected from the group consisting of zinc salts of C.sub.1 -C.sub.6 organic acids, and C.sub.1 -C.sub.6 organic carboxamides characterized by a high gas evolution rate. The blowing agent composition may be used in effective amounts in formulations containing a foamable polymer to yield an efficiently gas expanded polymeric composition upon exposure to heat. Suitable C.sub.1 -C.sub.6 organic acids for said zinc salts include straight-chain carboxylic acids, and useful organic carboxamides include formamide.

    摘要翻译: 一种发泡剂组合物,其包含:(i)偶氮二甲酰胺; (ii)氧化锌和/或碳酸锌; 和(iii)选自C1-C6有机酸锌盐和C1-C6有机甲酰胺中的至少一种,其特征在于高的气体逸出速率。 发泡剂组合物可以在含有可发泡聚合物的制剂中有效地使用,以在暴露于热量时产生有效气体发泡的聚合物组合物。 用于所述锌盐的合适的C 1 -C 6有机酸包括直链羧酸,有用的有机羧酰胺包括甲酰胺。

    Sulfonyl carbazates
    4.
    发明授权
    Sulfonyl carbazates 失效
    磺酰肼基甲酸酯

    公开(公告)号:US4209632A

    公开(公告)日:1980-06-24

    申请号:US866121

    申请日:1977-12-30

    申请人: Byron A. Hunter

    发明人: Byron A. Hunter

    IPC分类号: C08J9/10 C07C143/825

    CPC分类号: C08J9/105

    摘要: Sulfonyl carbazates containing at least one group of:--SO.sub.2 --NHNH--COO--wherein the oxygen and the sulfur atoms attach to various organic groups are useful as high temperature blowing agents for gas-expandable polymers. Additionally, novel polyfunctional and secondary-alkyl substituted sulfonyl carbazates have been discovered.

    摘要翻译: 含有至少一个基团的磺酰基肼基甲酸酯:-SO 2 -NHNH-COO-,其中氧和硫原子连接到各种有机基团上,可用作气体可膨胀聚合物的高温发泡剂。 另外,已经发现新的多官能和仲烷基取代的磺酰基肼基甲酸酯。

    Blowing agent composition containing zinc formate and metal salt
activator
    6.
    发明授权
    Blowing agent composition containing zinc formate and metal salt activator 失效
    含有甲酸锌和金属盐活化剂的发泡剂组合物

    公开(公告)号:US4462927A

    公开(公告)日:1984-07-31

    申请号:US559115

    申请日:1983-12-07

    申请人: Byron A. Hunter

    发明人: Byron A. Hunter

    IPC分类号: C08J9/08 C09K3/00

    CPC分类号: C08J9/08

    摘要: A blowing agent composition is provided comprising:(a) zinc formate, and(b) a compound having the formula M.sub.m X, wherein M is sodium or potassium; X is chlorine, bromine, iodine, CO.sub.3, HCO.sub.3, SO.sub.4, SO.sub.3, S.sub.2 O.sub.3, NO.sub.2, SCN, OCN, BO.sub.2, HBO.sub.3, HPO.sub.4, PO.sub.4 or H.sub.2 PO.sub.4, and m is an integer representing the valence of X; or a compound having the formula M.sub.n.sup.1 R.sub.p, wherein M.sup.1 is alkali metal, calcium, lead or zinc, R is organic mono- or polybasic acid having 1-18 carbon atoms and from 0 to 2 nitrogen atoms, or a benzenesulfonyl or toluenesulfonyl radical; and n and p are integers representing the valences of R and M.sup.1, respectively or whole fractions thereof.

    摘要翻译: 提供了一种发泡剂组合物,其包含:(a)甲酸锌,和(b)具有式MmX的化合物,其中M是钠或钾; X是氯,溴,碘,CO 3,HCO 3,SO 4,SO 3,S 2 O 3,NO 2,SCN,OCN,BO 2,HBO 3,HPO 4,PO 4或H 2 PO 4,m是表示X的化合价的整数; 或具有式Mn1Rp的化合物,其中M1是碱金属,钙,铅或锌,R是具有1-18个碳原子和0-2个氮原子的有机单酸或多元酸,或苯磺酰基或甲苯磺酰基; n和p分别代表R和M1的化合价或其全部馏分的整数。

    3,3-Carbonylbis(carbazates) as blowing agents
    7.
    发明授权
    3,3-Carbonylbis(carbazates) as blowing agents 失效
    作为发泡剂的3,3-CARBONYLBIS(CARBAZATES)

    公开(公告)号:US4169954A

    公开(公告)日:1979-10-02

    申请号:US908023

    申请日:1978-05-22

    IPC分类号: C08J9/10

    CPC分类号: C08J9/104

    摘要: Novel blowing agents are disclosed comprising 3,3'-carbonylbis(organo carbazates). The organo group may be alkyl, cycloalkyl, aryl or aralkyl moieties. In the preferred embodiment the organo group is an alkyl group selected from the group consisting of methyl, isopropyl, secondary butyl or tertiary butyl. The blowing agents find utility in the preparation of expanded organoplastic materials such as rubbers, thermosetting resins and thermoplastic resins.

    Cementitious structures of improved durability
    9.
    发明授权
    Cementitious structures of improved durability 失效
    改善耐久性的水泥结构

    公开(公告)号:US3955994A

    公开(公告)日:1976-05-11

    申请号:US533394

    申请日:1974-12-16

    摘要: Cementitious structures characterized by improved durability and weather resistance are obtained by: Incorporating alkyl and alkenyl succinic acids, their anhydrides, acid esters, acid amides, halogenated compounds and salts, into cementitious mixtures prior to setting; applying said succinic compounds onto concrete subsequent to setting; or by a combination of the forgoing steps; said alkyl and alkenyl substituents containing from 8 to 40 carbon atoms.

    摘要翻译: 特征在于耐久性和耐候性提高的水泥结构通过以下步骤获得:在凝固之前将烷基和链烯基琥珀酸,其酸酐,酸酯,酰胺,卤代化合物和盐掺入水泥混合物中; 在凝固后将所述琥珀酸化合物施用到混凝土上; 或通过前述步骤的组合; 所述烷基和链烯基取代基含有8至40个碳原子。