摘要:
Certain hydrazodicarboxylates, namely polymers or oligomers made by reacting hydrazine with polyfunctional haloformates, especially difunctional haloformates, cyclized forms of said oligomers and condensation products of hydrocarbyl carbazates with polyfunctional, especially difunctional, haloformates are useful as chemical blowing agents for expanding gas-expandable polymeric materials. These compounds are novel.
摘要:
A blowing agent composition, comprising: (i) azodicarbonamide; (ii) zinc oxide and/or zinc carbonate; and (iii) at least one member selected from the group consisting of zinc salts of C.sub.1 -C.sub.6 organic acids, and C.sub.1 -C.sub.6 organic carboxamides characterized by a high gas evolution rate. The blowing agent composition may be used in effective amounts in formulations containing a foamable polymer to yield an efficiently gas expanded polymeric composition upon exposure to heat. Suitable C.sub.1 -C.sub.6 organic acids for said zinc salts include straight-chain carboxylic acids, and useful organic carboxamides include formamide.
摘要:
The present invention relates to an improved nitro urea compound specifically the zinc salt of nitro urea useful as a blowing agent composition, its preparation and its use.
摘要:
Sulfonyl carbazates containing at least one group of:--SO.sub.2 --NHNH--COO--wherein the oxygen and the sulfur atoms attach to various organic groups are useful as high temperature blowing agents for gas-expandable polymers. Additionally, novel polyfunctional and secondary-alkyl substituted sulfonyl carbazates have been discovered.
摘要:
Hydrocarbylsulfonyl carbohydrazides of the following structural formulae are disclosed for use as blowing agents: ##STR1## The compounds wherein the R groups are alkyl are novel, as are the polymeric products.
摘要:
A blowing agent composition is provided comprising:(a) zinc formate, and(b) a compound having the formula M.sub.m X, wherein M is sodium or potassium; X is chlorine, bromine, iodine, CO.sub.3, HCO.sub.3, SO.sub.4, SO.sub.3, S.sub.2 O.sub.3, NO.sub.2, SCN, OCN, BO.sub.2, HBO.sub.3, HPO.sub.4, PO.sub.4 or H.sub.2 PO.sub.4, and m is an integer representing the valence of X; or a compound having the formula M.sub.n.sup.1 R.sub.p, wherein M.sup.1 is alkali metal, calcium, lead or zinc, R is organic mono- or polybasic acid having 1-18 carbon atoms and from 0 to 2 nitrogen atoms, or a benzenesulfonyl or toluenesulfonyl radical; and n and p are integers representing the valences of R and M.sup.1, respectively or whole fractions thereof.
摘要翻译:提供了一种发泡剂组合物,其包含:(a)甲酸锌,和(b)具有式MmX的化合物,其中M是钠或钾; X是氯,溴,碘,CO 3,HCO 3,SO 4,SO 3,S 2 O 3,NO 2,SCN,OCN,BO 2,HBO 3,HPO 4,PO 4或H 2 PO 4,m是表示X的化合价的整数; 或具有式Mn1Rp的化合物,其中M1是碱金属,钙,铅或锌,R是具有1-18个碳原子和0-2个氮原子的有机单酸或多元酸,或苯磺酰基或甲苯磺酰基; n和p分别代表R和M1的化合价或其全部馏分的整数。
摘要:
Novel blowing agents are disclosed comprising 3,3'-carbonylbis(organo carbazates). The organo group may be alkyl, cycloalkyl, aryl or aralkyl moieties. In the preferred embodiment the organo group is an alkyl group selected from the group consisting of methyl, isopropyl, secondary butyl or tertiary butyl. The blowing agents find utility in the preparation of expanded organoplastic materials such as rubbers, thermosetting resins and thermoplastic resins.
摘要:
A process for preparing hydrazodicarbonamide directly from a ketazine and urea in water without any acid catalyst according to the following reaction is disclosed. ##EQU1## wherein the R groups may be the same or different.
摘要翻译:公开了根据以下反应直接从酮连氮和尿素在水中制备肼基二酰胺的方法,没有任何酸催化剂。 R ANGLE C = N-N = C ANGLE + 2 H2N-CO-NH2 + 2H2O RR→H2N-CO-NHNH-CO-NH2 + R-CO-R + 2NH3其中R基团可以相同或不同。
摘要:
Cementitious structures characterized by improved durability and weather resistance are obtained by: Incorporating alkyl and alkenyl succinic acids, their anhydrides, acid esters, acid amides, halogenated compounds and salts, into cementitious mixtures prior to setting; applying said succinic compounds onto concrete subsequent to setting; or by a combination of the forgoing steps; said alkyl and alkenyl substituents containing from 8 to 40 carbon atoms.
摘要:
The present invention relates to an improved nitro urea compound specifically the zinc salt of nitro urea useful as a blowing agent composition, its preparation and its use.