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公开(公告)号:US11965089B2
公开(公告)日:2024-04-23
申请号:US16758839
申请日:2018-10-25
申请人: CHINA PETROLEUM & CHEMICAL CORPORATION , BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
发明人: Wenbo Song , Hao Yuan , Zhenjie Liu , Jinliang Qiao , Shijun Zhang , Hua Yin , Huijie Hu , Qing Shao , Jie Zhang , Xiaomeng Zhang , Dezhan Li , Fuyong Bi
IPC分类号: C08L67/02 , C08F212/08 , C08F212/36 , C08F222/06 , C08L35/06
CPC分类号: C08L67/02 , C08F212/08 , C08F212/36 , C08F222/06 , C08L35/06 , C08F2500/24 , C08F2810/20
摘要: A microspheric ionomer having a cross-linked structure, a preparation method therefor, applications thereof, and a preparation system thereof. The ionomer comprises structure units A represented by formula (1), structure units B represented by formula (2), and a cross-linking structure provided by a cross-linking agent, M being separately selected from H, a metal cation, and a straight chain, a saturated alkyl of branched or ring-shaped C1-C20, R being H or a methyl; and metal cations are introduced to part of structure units A in the ionomer. The ionomer shows an outstanding effect on nucleation of PET, serves as a nucleating agent for PET modification, so as to obtain a corresponding PET composition. A system and method for continuously preparing maleic acid ester ionomer microspheres and cross-linked maleic acid ionomer microspheres, so as to achieve continuous preparation, washing and separation of ionomer microspheres, effectively stabilizes the separation effect, and avoids frequent start and stop operations of a centrifuge.