公开(公告)号：US20200325262A1

公开(公告)日：2020-10-15

申请号：US16759153

申请日：2018-10-24

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Rong GAO ,  Zifang GUO ,  Junling ZHOU ,  Dongbing LIU ,  Jie FU ,  Jingjing LAI ,  Tingjie HUANG ,  Shiyuan XU ,  Xinyang LI

IPC分类号： C08F220/04 ,  C08J9/16 ,  C08F210/02

摘要： The present invention provides a copolymer of an olefin and an unsaturated carboxylic acid or an unsaturated carboxylic acid derivative, said copolymer being a spherical and/or spherical-like polymer. The copolymer provided by the invention exhibits a good morphology and has good prospects in industrial use.

公开(公告)号：US20220396646A1

公开(公告)日：2022-12-15

申请号：US17755542

申请日：2020-10-30

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Rong GAO ,  Jingjing LAI ,  Zifang GUO ,  Qingqiang GOU ,  Junling ZHOU ,  Wenbo SONG ,  Xinyang LI ,  Xiaofan ZHANG ,  Jie LIN ,  Dongbing LIU ,  Junhui ZHANG ,  Hongtao WANG ,  Shijun ZHANG ,  Yuanning GU ,  Jingyan AN ,  Hui ZHAO ,  Tingjie HUANG ,  Dong MA ,  Ruen WANG ,  Shiyuan XU ,  Jie FU

IPC分类号： C08F4/70 ,  C08F220/64

摘要： A method for preparing an olefin-olefinic alcohol copolymer and an olefin-olefinic alcohol copolymer prepared by the method are provided. The catalyst used in the method for preparing the olefin-olefinic alcohol copolymer has a diimine metal complex as shown in Formula I.

公开(公告)号：US20230257499A1

公开(公告)日：2023-08-17

申请号：US18304743

申请日：2023-04-21

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Rong GAO ,  Zifang GUO ,  Junling ZHOU ,  Dongbing LIU ,  Jie FU ,  Jingjing LAI ,  Tingjie HUANG ,  Shiyuan XU ,  Xinyang LI

IPC分类号： C08F220/04 ,  C08F210/02 ,  C08J9/16

CPC分类号： C08F220/04 ,  C08F210/02 ,  C08J9/16 ,  C08J2205/04 ,  C08J2323/08 ,  C08J2333/02

摘要： A preparation method for a copolymer includes the step(s) of contacting an olefin and an unsaturated carboxylic acid shown in Formula II or a derivative of the unsaturated carboxylic acid shown in Formula II with a catalyst and optionally a chain transfer agent for reaction in the presence of an alkane solvent to obtain the copolymer. The copolymer is a spherical and/or spherical-like copolymer.

公开(公告)号：US20230192915A1

公开(公告)日：2023-06-22

申请号：US17997143

申请日：2021-04-26

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Nannan CUI ,  Zifang GUO ,  Qingqiang GOU ,  Bingyi LI ,  Ruen WANG ,  Yan LI ,  Jie FU ,  Lixin YAN ,  Jingyan AN ,  Peng KOU ,  Shiyuan XU ,  Tongxuan ZHANG

IPC分类号： C08F10/02 ,  C08F4/642 ,  C08F4/02 ,  C08F4/649

CPC分类号： C08F10/02 ,  C08F4/02 ,  C08F4/6425 ,  C08F4/6498

摘要： The present disclosure relates to olefin polymerization catalysts, and discloses a catalyst component for olefin polymerization or copolymerization and a preparation method therefor, and a catalyst and an application thereof. The catalyst component for olefin polymerization or copolymerization in the present disclosure comprises titanium element, magnesium element, an electron donor, an organic silicon polymer, and an inorganic oxide support, wherein the molecular composition of the organic silicon polymer is [RxSiO(4-x)/2]m, wherein R is selected from alkyl, aryl, vinyl or oxygen, x is 0 or more and 2 or less, and the value of m makes the number-average molecular weight of the organic silicon polymer be 1×103-1×106 g/mol. The catalyst has the characteristics of high activity, good hydrogen-regulating copolymerization performance, high bulk density of resulting polymer powder, and a low content of fine powder in the polymer powder when applied to olefin polymerization, particularly to ethylene and α-olefin polymerization.

公开(公告)号：US20210380730A1

公开(公告)日：2021-12-09

申请号：US17288071

申请日：2019-10-25

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Yu KANG ,  Xinping LYU ,  Dongbing LIU ,  Zifang GUO ,  Hongmei LIU ,  Shiyuan XU

IPC分类号： C08F4/642 ,  C08F110/02

摘要： The invention relates to the technical field of heterogeneous catalytic olefin polymerization, and discloses a polyolefin catalyst, its preparation and its us. A method for preparing the polyolefin catalyst comprises: (i) providing a thermally activated mesoporous material, with the thermal activation treatment being performed at a temperature of 300 to 900° C. for a period of time of 3 to 48 hours; (ii) under an inert atmosphere, (iia) conducting impregnation treatment of the thermally activated mesoporous material with a solution containing a magnesium component and then with a solution containing a titanium component, (iib) conducting impregnation treatment of the thermally activated mesoporous material with a solution containing a titanium component and then with a solution containing a magnesium component, or (iic) conducting co-impregnation treatment of the thermally activated mesoporous material with a solution containing both a titanium component and a magnesium component, to obtain a slurry to be sprayed; and (iii) spray drying the slurry to be sprayed from step (ii), to obtain a solid polyolefin catalyst component. When used in olefin polymerization, the polyolefin catalysts prepared by using the method provided by the invention have high catalytic activities, and polyolefin products having a narrow molecular weight distribution and an excellent melt index can be obtained.

公开(公告)号：US20200325315A1

公开(公告)日：2020-10-15

申请号：US16759193

申请日：2018-10-24

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Rong GAO ,  Zifang GUO ,  Junling ZHOU ,  Dongbing LIU ,  Jie FU ,  Jingjing LAI ,  Tingjie HUANG ,  Shiyuan XU ,  Xinyang LI

IPC分类号： C08L23/08 ,  C08F210/02 ,  C08F216/06 ,  C08F2/38 ,  C08F2/06 ,  C08F4/70 ,  C08F4/14

摘要： The invention provides an olefin-olefinic alcohol copolymer and a preparation method thereof, said copolymer comprising a spherical and/or spherical-like polymer. The copolymer provided by the invention exhibits a good morphology and has good prospects in industrial use.