摘要:
Cellulosic materials such as cotton fabrics or garments are made crease resistant by exposing them to formaldehyde vapor at an elevated temperature after pre-impregnation of fabric with a formaldehyde-free aqueous solution of a latent catalyst, preferably zinc chloride.
摘要:
The dimensional stability, wrinkle resistance, smooth drying characteristics and total shape retentivity of cellulosic material such as cotton fabrics are improved by impregnating the fabric with an aqueous solution of a monomeric compound which has at least one active hydrogen and reacts with formaldehyde, e.g., urea, exposing the impregnated fabric to an atmosphere containing formaldehyde vapors in the absence of a catalyst until a creaseproofing amount of an at least partially polymerized, substantially water-insoluble condensate (such as an amideformaldehyde condensate) is affixed to the fabric without, however, effecting any substantial amount of cross-linking with the cellulosic fiber. The thus-exposed fabric is thereafter postheated in an inert gaseous atmosphere also in the absence of a catalyst to further polymerize and cross-link the fabric.
摘要:
The dimensional stability, crease retention, wrinkle resistance and smooth drying characteristics of a cellulose fiber-containing material such as a cotton fabric are improved by impregnating the material with an aqueous formaldehyde phase and curing the formaldehyde-containing material at high temperature in the presence of catalyst-forming sulfur dioxide while governing the amount of water in the system to provide a self-limiting reaction system, water being the limiting factor in the reaction by which an acid curing catalyst is formed from formaldehyde, sulfur dioxide and water. The aqueous formaldehyde phase may be applied to the material as such, or it may be formed in the material by exposing the latter in a humidified state to formaldehyde vapor. Sulfur dioxide may be introduced into the system either in the course of the aqueous impregnation step or in the curing step.
摘要:
The dimensional stability, wrinkle resistance, smooth drying characteristics and total shape retentivity of cellulosic materials such as cotton fabrics are improved by treatment with acetic acid or formic acid vapors after impregnation of the materials with an aqueous solution of a water-soluble creaseproofing agent containing reactive N-methylol groups such as trimethylolmelamine or DHDMEU, whereby the cellulosic fibers become crosslinked.
摘要:
MATERIALS SUCH AS CELLULOSIC TEXTILE MATERIALS ARE MADE FLAME-RETARDANT BY TREATING THEM WITH COMPOUNDS CONTAINING METHYLOL GROUPS, NITROGEN AND PHOSPHORUS. TYPICAL SUCH COMPOUNDS HAVE AT LEAST ONE RADICAL OF THE FORMULA:
>N-CH2-P(=O)(-O-R5)2
WHEREIN R5 IS LOWER ALKYL. TYPICAL SUCH COMPOUNDS ALSO HAVE > NH GROUPS AND/OR AMINOMETHYLOL GROUPS OF THE FORMULA > NCH2OH.