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公开(公告)号：US4521260A
公开(公告)日：1985-06-04
申请号：US665335
申请日：1984-10-26
IPC分类号： C06B45/10 , C08F290/04
CPC分类号： C06B45/10 , C08F290/048
摘要： An energetic composition useful in transferring detonation through thin cnels in a logic pattern comprises a binder comprising vinyl-terminated polybutadiene-acrylonitrile copolymer crosslinked with a monofunctional unsaturated ester monomer in an amount from about 50 to about 90 percent of the binder weight and a plasticizer selected from the group consisting of dioctyl phthalate, maleate and adipate, isodecyl pelargonate, dibutyl phthalate and maleate in an amount from about 10 to 50 percent of the binder weight, and pentaerythritol tetranitrate in amount from about 76 to 84 percent of the total composition weight. The composition is cured with ionizing radiation in a dose from about 0.6.times.10.sup.6 to 1.2 to 10.sup.6 rads.
摘要翻译： 用于以逻辑图案转移爆炸通过薄通道的能量组合物包括粘合剂，其包含以约50至约90％的粘合剂重量的量与单官能不饱和酯单体交联的乙烯基封端的聚丁二烯 - 丙烯腈共聚物和选择的增塑剂 来自邻苯二甲酸二辛酯，马来酸酯和己二酸酯，壬酸异癸酯，邻苯二甲酸二丁酯和马来酸酯的量为粘合剂重量的约10至50％，季戊四醇四硝酸酯的量为总组合物重量的约76至84％。 组合物以约0.6×106至1.2至106弧度的剂量用电离辐射固化。
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公开(公告)号：US3981756A
公开(公告)日：1976-09-21
申请号：US611772
申请日：1975-09-09
申请人： Carl Gotzmer, Jr.
发明人： Carl Gotzmer, Jr.
CPC分类号： C06B45/10 , C06B21/0025 , Y10S149/119
摘要： High density solid propellants are prepared by a process which comprises mixing the solid propellant components comprising a perfluorinated polymer, such as high molecular weight polytetrafluorethylene, and an inorganic oxidizer salt, such as NF.sub.4 BF.sub.4, with a dispersion containing a dissolved low molecular weight perfluorinated polymer, a suspended low molecular weight pefluorinated polymer and a suitable solvent, removing the solvent from the mixture, and drying the solids.
摘要翻译： 通过以下方法制备高密度固体推进剂，该方法包括将包含全氟化聚合物如高分子量聚四氟乙烯的固体推进剂组分与无机氧化剂盐如NF4BF4与含有溶解的低分子量全氟化聚合物的分散体混合， 悬浮的低分子量聚氟化聚合物和合适的溶剂，从混合物中除去溶剂，并干燥固体。
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公开(公告)号：US06668727B1
公开(公告)日：2003-12-30
申请号：US10463936
申请日：2003-06-18
申请人： Steven S. Kim , Christopher G. Melkonian , Michael P. Dunnigan , Carl Gotzmer, Jr. , Joe Mayersak
发明人： Steven S. Kim , Christopher G. Melkonian , Michael P. Dunnigan , Carl Gotzmer, Jr. , Joe Mayersak
IPC分类号： F42B1210
摘要： An explosively driven impactor grenade includes a grenade body having a substantially spherical shape and a hollow central portion, the grenade body including a plurality of recesses formed on an external surface thereof with each recess including an opening into the hollow central portion of the grenade body, the grenade body including an opening on the exterior surface that connects with the hollow central portion; a fuze disposed in the hollow central portion of the grenade body; a fuze cap for closing the opening on the exterior surface that connects with the hollow central portion; and a plurality of explosively driven impactors respectively disposed in the plurality of recesses formed on the external surface of the grenade body, the explosively driven impactors being connected to the fuze through the recess openings into the hollow central portion of the grenade body.
摘要翻译： 爆炸驱动的冲击手榴弹包括具有大致球形的手榴弹体和中空的中心部分，手榴弹体包括形成在其外表面上的多个凹部，每个凹部包括穿过手榴弹体的中空中心部分的开口， 所述手榴弹体包括在所述外表面上与所述中空中心部分连接的开口; 布置在手榴弹身体中空部分的引信; 用于封闭与中空中心部分连接的外表面上的开口的引信盖; 以及分别设置在形成在手榴弹体的外表面上的多个凹部中的多个爆炸驱动的冲击器，爆炸驱动的冲击器通过凹部开口连接到引信到手榴弹体的中空中心部分。
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公开(公告)号：US4978482A
公开(公告)日：1990-12-18
申请号：US665906
申请日：1984-10-29
IPC分类号： C06B21/00
CPC分类号： C06B21/005
摘要： A method of melt casting plastic bonded explosives by:A. forming a uniform binder mixture of the following ingredients(1) from 10 to 30 weight percent of a triblock polymer of the formula A-B-A wherein A represents a polystyrene block and B represents an elastomeric midblock which is selected from the group consisting of polybutadiene, polyisoprene, and polyethylenebutylene; and(2) from 70 to 90 weight percent of a low viscosity oil selected from the group consisting of naphthenic, paraffinic, and olefinic oils by mixing the ingredients under low-shear conditions at a temperature of from 80.degree. C. to 110.degree. C.;B. mixing an energetic filler into the binder mixture under low shear conditions and at a temperature of from 80.degree. C. to 110.degree. C., provided that the viscosity of the mixture does not exceed 20 kilopoise;C. pouring the energetic filler-binder mixture formed in step B into a mold; andD. cooling energetic filler-binder mixture to form a solid explosive composite.Rubber phase associating and polystyrene phase associating hot melt resins may also be used in the binder mixture to improve the physical properties of the final plastic bonded explosive composite.
摘要翻译： 一种通过以下方法熔融浇铸塑料粘结炸药的方法：A.形成以下成分（1）的均匀粘合剂混合物，10至30重量％的式ABA的三嵌段聚合物，其中A表示聚苯乙烯嵌段，B表示弹性体中间嵌段 其选自聚丁二烯，聚异戊二烯和聚乙烯丁烯; 和（2）70至90重量％的选自环烷烃，链烷烃和烯烃油的低粘度油，通过在低剪切条件下在80℃至110℃的温度下混合成分 。 B.在低剪切条件下和在80℃至110℃的温度下将能量填料混合到粘合剂混合物中，条件是混合物的粘度不超过20千泊; C.将步骤B中形成的高能填料 - 粘合剂混合物倒入模具中; 和D.冷却能量填料 - 粘合剂混合物以形成固体爆炸复合材料。 橡胶相缔合和聚苯乙烯相缔合的热熔树脂也可用于粘合剂混合物中以改善最终的塑料粘结的爆炸复合材料的物理性能。
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公开(公告)号：US4219490A
公开(公告)日：1980-08-26
申请号：US39059
申请日：1979-05-14
申请人： Carl Gotzmer, Jr.
发明人： Carl Gotzmer, Jr.
CPC分类号： C07F17/02 , C06B23/007
摘要： Ferrocenyl thiols of the formula ##STR1## wherein n is an integer of from 2 to 4 are prepared by reacting a compoundf the formula ##STR2## with thioacetic acid, ##STR3## at elevated temperatures in the presence of a free radical initiator to produce a thiol ester of the formula ##STR4## and then hydrolyzing the thiol ester to produce the thiol. The thiols are useful as non-migrating burning rate modifiers for unsaturated rubber-based propellants.
摘要翻译： 其中n是2至4的整数的二茂铁硫醇通过在升高的温度下在自由基引发剂的存在下使式“IMAGE”的化合物与硫代乙酸反应来制备，以产生 一种式“IMAGE”的硫羟酸酯，然后水解硫醇酯以产生硫醇。 硫醇可用作不饱和橡胶基推进剂的非迁移燃烧速率改性剂。
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公开(公告)号：US4168362A
公开(公告)日：1979-09-18
申请号：US863299
申请日：1977-12-14
CPC分类号： C06B23/006 , C06B45/10 , C08C19/26 , C08G63/681
摘要： A ferrocenyl thiol compound is reacted with an unsaturated prepolymer to form a polymeric material suitable for use as a binder in composite propellant.
摘要翻译： 二茂铁基硫醇化合物与不饱和预聚物反应形成适合用作复合推进剂中的粘合剂的聚合材料。
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