公开(公告)号：US5582953A

公开(公告)日：1996-12-10

申请号：US450631

申请日：1995-05-25

申请人： Carlo Uyttendaele ,  Herman Uytterhoeven ,  Bartholomeus Horsten

发明人： Carlo Uyttendaele ,  Herman Uytterhoeven ,  Bartholomeus Horsten

IPC分类号： B41M5/32 ,  B41M5/323 ,  G03C1/498 ,  G03C8/110

CPC分类号： G03C1/4989 ,  G03C1/49872 ,  Y10S430/162 ,  Y10S430/166

摘要： A direct thermal recording process wherein a direct thermal recording material is heated dot-wise and said direct thermal recording material comprises on a substrate an imaging layer containing uniformly distributed in a film-forming polymeric binder (i) one or more substantially light-insensitive organic silver salts being no double salts, said silver salt(s) being in thermal working relationship with (ii) an organic reducing agent therefor, characterized in that said reducing agent is a benzene compound the benzene nucleus of which is substituted by no more than two hydroxy groups which are present in 3,4-position on said nucleus and have in the 1-position of said nucleus a substituent linked to said nucleus by means of a carbonyl group.

摘要翻译： 一种直接热敏记录方法，其中直接热敏记录材料是逐点加热的，并且所述直接热敏记录材料在基底上包含均匀分布在成膜聚合物粘合剂中的成像层（i）一种或多种基本上不透光的有机物 银盐不是双重盐，所述银盐与（ii）有机还原剂处于热作用关系中，其特征在于所述还原剂是苯化合物，其苯核被不超过两个 在所述核上存在于3,4位且在所述核的1位具有通过羰基与所述核连接的取代基的羟基。

公开(公告)号：US5527758A

公开(公告)日：1996-06-18

申请号：US449293

申请日：1995-05-24

申请人： Carlo Uyttendaele ,  Herman Uytterhoeven ,  Guy Jansen ,  Bartholomeus Horsten

发明人： Carlo Uyttendaele ,  Herman Uytterhoeven ,  Guy Jansen ,  Bartholomeus Horsten

IPC分类号： B41M5/26 ,  B41M5/28 ,  B41M5/32 ,  G03C1/498 ,  B41M5/035 ,  B41M5/38

CPC分类号： G03C1/4989 ,  G03C1/49827 ,  G03C1/49845

摘要： A direct thermal imaging process wherein a non-photosensitive direct thermal recording material is heated dot-wise, and said direct thermal recording material comprises an imaging layer containing uniformly distributed in a film-forming polymeric binder (i) one or more substantially light-insensitive organic silver salts, said silver salt(s) being uniformly in thermal working relationship with (ii) one or more organic reducing agents therefor, however neither including 3,5-dihydroxybenzoic acid as acidic reagent nor di-tert-butyl-p-cresol as a sole reducing agent, characterized in that said imaging layer contains at least one polycarboxylic acid and/or anhydride thereof in a molar percentage of at least 20 with respect to said silver salt(s).

摘要翻译： 一种直接热成像方法，其中非感光直接热敏记录材料被逐点加热，并且所述直接热敏记录材料包括均匀分布在成膜聚合物粘合剂中的成像层（i）一种或多种基本上不敏感的 有机银盐，所述银盐与（ii）一种或多种有机还原剂处于热作用的热处理关系中，但不包括作为酸性试剂的3,5-二羟基苯甲酸和二叔丁基对甲酚 作为唯一的还原剂，其特征在于所述成像层相对于所述银盐含有至少一种摩尔百分数至少为20的多元羧酸和/或其酸酐。

公开(公告)号：US06348308B1

公开(公告)日：2002-02-19

申请号：US09135448

申请日：1998-08-17

申请人： Johan Loccufier ,  David Terrell ,  Carlo Uyttendaele ,  Bartholomeus Horsten

发明人： Johan Loccufier ,  David Terrell ,  Carlo Uyttendaele ,  Bartholomeus Horsten

IPC分类号： G03C1494

CPC分类号： G03C1/4989 ,  G03C1/49845 ,  Y10S430/165

摘要： A substantially light-insensitive monosheet recording material comprising a support and a thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the thermosensitive element further contains an unsaturated carbocyclic or heterocyclic stabilizer compound substituted with a —SA group where A is hydrogen, a counterion to compensate the negative charge of the thiolate group or a group forming a symmetrical or an asymmetrical disulfide and the recording material is capable of producing prints with a numerical gradation value defined as the quotient of the fraction (2.5-0.1)/(E2.5-E0.1) greater than 2.3 , where E2.5 is the energy in Joule applied in a dot area of 87 &mgr;m×87 &mgr;m of the imaging layer that produces an optical density value of 2.5, and E0.1 is the energy in Joule applied in a dot area of the imaging layer material that produces an optical density value of 0.1.

摘要翻译： 一种基本上不光敏的单片记录材料，其包括载体和含有基本上不光敏的有机银盐的热敏元件，与其热加工关系的有机还原剂和粘合剂，其中所述热敏元件还含有不饱和碳环或杂环 用-SA基团取代的稳定剂化合物，其中A是氢，补偿硫醇基的负电荷的抗衡离子或形成对称或不对称二硫化物的基团，并且记录材料能够产生具有定义为 分数（2.5-0.1）/（E2.5-E0.1）的商大于2.3，其中E2.5是在产生光学的成像层的87μmum87μm的点区域中施加的焦耳中的能量 密度值为2.5，E0.1为焦耳焦点的能量，该焦耳应用于产生光密度va的成像层材料的点区域 lue为0.1。

公开(公告)号：US06306573B1

公开(公告)日：2001-10-23

申请号：US09459933

申请日：1999-12-13

申请人： Bartholomeus Horsten ,  Johan Loccufier ,  Geert Defieuw ,  Luc Leenders

发明人： Bartholomeus Horsten ,  Johan Loccufier ,  Geert Defieuw ,  Luc Leenders

IPC分类号： G03C1498

CPC分类号： G03C1/4989 ,  G03C1/34 ,  G03C1/49854

摘要： A recording material comprising a support, a thermosensitive element and a protective layer therefor, the thermosensitive element comprising a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the thermosensitive element further comprises in reactive association with the substantially light-insensitive organic silver salt and the organic reducing agent a substituted, exclusive of groups having an exclusively electron withdrawing character, or unsubstituted compound with an unsaturated 5-membered heterocyclic ring annulated with an aromatic ring system, the ring consisting of nitrogen and carbon atoms with at least one of the nitrogen atoms having a hydrogen atom and none of the carbon atoms being directly linked to a sulfur atom or being part of a carbonyl-group; a production process therefor and a thermal image recording process utilizing the recording-material.

摘要翻译： 一种包含载体，热敏元件及其保护层的记录材料，所述热敏元件包括基本上不光敏的有机银盐，与其热加工关系的有机还原剂和粘合剂，其中所述热敏元件还包含 与基本上不光敏的有机银盐和有机还原剂的反应性缔合物被取代，不包括仅具有吸电子性质的基团，或未取代的化合物与具有芳族环系统的不饱和5元杂环，所述环包括 的氮和碳原子，其中至少一个氮原子具有氢原子，并且没有一个碳原子直接连接到硫原子或者是羰基的一部分; 其制造方法和使用记录材料的热图像记录处理。

公开(公告)号：US06244766B1

公开(公告)日：2001-06-12

申请号：US09452061

申请日：1999-11-30

申请人： Anthony Roy Dunn ,  Matthew Richard Palmer ,  Krystyna Maria Windle ,  Bartholomeus Horsten ,  David Tilemans ,  Guy Jansen

发明人： Anthony Roy Dunn ,  Matthew Richard Palmer ,  Krystyna Maria Windle ,  Bartholomeus Horsten ,  David Tilemans ,  Guy Jansen

IPC分类号： B41J1126

CPC分类号： G03C1/4989 ,  B41J2/36 ,  B41J3/4075 ,  B41J15/04 ,  G03C2200/39

摘要： A label-printing process for obtaining a desired optical density and a desired color tone with a substantially light-insensitive elongated imaging material comprising: selecting an elongated imaging material, the selected elongated imaging material having a support and a thermosensitive element; supplying image data to a processing unit of a thermal printer including a printhead having energizable heating elements arranged in a column C; converting the image data which are not zero into at least one activation pulse per pixel to be printed; energizing the heating elements printing-line by printing-line adjacent to the selected substantially light-insensitive elongated imaging material thereby producing an image; transporting the imaging material past and adjacent to the printhead in a transport direction with a transport system; forming an image dot with a heat energy of 50 to 200 mJ/mm2 of heating element surface area; wherein the thermosensitive element contains a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith and a binder; and the thermosensitive element excludes a colorless or light colored dye precursor and also excludes an encapsulated organic silver salt in a heat-responsive microcapsule; and an apparatus therefor.

摘要翻译： 一种标签印刷方法，用于使用基本上不光泽的细长成像材料获得所需的光密度和期望的色调，包括：选择细长的成像材料，所选择的细长成像材料具有支撑体和热敏元件;将图像数据提供给 热敏打印机的处理单元，其包括具有布置在列C中的可激励加热元件的打印头;将不为零的图像数据转换为每个要打印的像素的至少一个激活脉冲;通过打印 - 与所选择的基本上不感光的细长成像材料相邻，从而产生图像;通过传送系统在成像材料的输送方向上运送成像材料并将其邻近打印头;形成图像点，其热能为50〜200mJ / mm2的加热元件表面积;其中热敏元件包含基本上不发光的元件 有机银盐，与其的热加工关系的还原剂和粘合剂; 并且热敏元件排除无色或浅色染料前体，并且不包括热响应微胶囊中的包封的有机银盐; 及其装置。

公开(公告)号：US6159667A

公开(公告)日：2000-12-12

申请号：US271652

申请日：1999-03-17

申请人： Sabine Emmers ,  Bartholomeus Horsten ,  Ingrid Geuens ,  Yvan Gilliams ,  Andre Bellens ,  Dirk Bollen ,  Ivan Hoogmartens

发明人： Sabine Emmers ,  Bartholomeus Horsten ,  Ingrid Geuens ,  Yvan Gilliams ,  Andre Bellens ,  Dirk Bollen ,  Ivan Hoogmartens

IPC分类号： C07C51/41 ,  G03C1/498

CPC分类号： G03C1/49809 ,  C07C51/412 ,  G03C1/498 ,  G03C1/4989 ,  G03C2001/0157 ,  G03C2001/7635 ,  G03C2200/43 ,  C07C53/126

摘要： A recording material comprising a support and a thermosensitive element containing silver behenate, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the silver behenate is not associated with mercury and/or lead ions and when the recording material is irradiated with a copper K.alpha..sub.1 X-ray source the ratio, normalized to a quantity of silver in the recording material of 1 g per m.sup.2 thereof, of the sum of the peak heights of the X-ray diffraction lines attributable to silver behenate at Bragg angles, 2.THETA., of 6.01.degree., 7.56.degree., 9.12.degree., 10.66.degree., 12.12.degree. and 13.62.degree. to the sum of the peak heights of the X-ray diffraction lines at Bragg angles, 2.THETA., of 25.60.degree., 35.16.degree. and 43.40.degree. of NIST standard 1976, rhombohedral Al.sub.2 O.sub.3, determined with the same X-ray diffractometer in the same state of adjustment, is greater than 0.85; production processes for particles of substantially light-insensitive organic silver salt comprising silver behenate with these X-ray characteristics in the presence and substantial absence of organic solvent.

摘要翻译： 一种记录材料，包括载体和含有山嵛酸银的热敏元件，与其热加工关系的有机还原剂和粘合剂，其中山嵛酸银与汞和/或铅离子不相关，并且当记录材料被照射时 铜Kα1 X射线源的比率，归一化为记录材料中的银量为1g / m2，为归因于布拉格角的山嵛酸银的X射线衍射线的峰高的总和 ，2 THETA，6.01°，7.56°，9.12°，10.66°，12.12°和13.62°，与布拉格角X射线衍射线峰值高度之和为25.60°，35.16°， NIST标准1976年的43.40°，菱形Al2O3用相同的X射线衍射仪在相同的调节状态下测定，大于0.85; 在存在并且基本上不存在有机溶剂的情况下，包含具有这些X射线特性的山嵛酸银的基本上不光敏的有机银盐颗粒的生产方法。

公开(公告)号：US6096486A

公开(公告)日：2000-08-01

申请号：US982318

申请日：1997-12-10

申请人： Sabine Emmers ,  Bartholomeus Horsten ,  Ingrid Geuens ,  Yvan Gilliams ,  Andre Bellens ,  Dirk Bollen ,  Ivan Hoogmartens

发明人： Sabine Emmers ,  Bartholomeus Horsten ,  Ingrid Geuens ,  Yvan Gilliams ,  Andre Bellens ,  Dirk Bollen ,  Ivan Hoogmartens

IPC分类号： C07C51/41 ,  G03C1/498

CPC分类号： G03C1/49809 ,  C07C51/412 ,  G03C1/498 ,  G03C1/4989

摘要： A recording material comprising a support and a thermosensitive element containing silver behenate, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the silver behenate is not associated with mercury and/or lead ions and when the recording material is irradiated with a copper K.alpha..sub.1 X-ray source the ratio, normalized to a quantity of silver in the recording material of 1 g per m.sup.2 thereof, of the sum of the peak heights of the X-ray diffraction lines attributable to silver behenate at Bragg angles, 2.THETA., of 6.01.degree., 7.56.degree., 9.12.degree., 10.66.degree., 12.12.degree. and 13.62.degree. to the sum of the peak heights of the X-ray diffraction lines at Bragg angles, 2.THETA., of 25.60.degree., 35.16.degree. and 43.40.degree. of NIST standard 1976, rhombohedral Al.sub.2 O.sub.3, determined with the same X-ray diffractometer in the same state of adjustment, is greater than 0.85; production processes for particles of substantially light-insensitive organic silver salt comprising silver behenate with these X-ray characteristics in the presence and substantial absence of organic solvent.

公开(公告)号：US6030764A

公开(公告)日：2000-02-29

申请号：US856097

申请日：1997-05-14

申请人： Bartholomeus Horsten ,  Johan Loccufier ,  Geert Defieuw ,  Luc Leenders

发明人： Bartholomeus Horsten ,  Johan Loccufier ,  Geert Defieuw ,  Luc Leenders

IPC分类号： G03C1/498

CPC分类号： G03C1/4989 ,  G03C1/49854

摘要： A recording material comprising a support, a thermosensitive element and a protective layer therefor, the thermosensitive element comprising a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the thermosensitive element further comprises in reactive association with the substantially light-insensitive organic silver salt and the organic reducing agent a substituted, exclusive of groups having an exclusively electron withdrawing character, or unsubstituted compound with an unsaturated 5-membered heterocyclic ring annulated with an aromatic ring system, the ring consisting of nitrogen and carbon atoms with at least one of the nitrogen atoms having a hydrogen atom and none of the carbon atoms being directly linked to a sulfur atom or being part of a carbonyl-group; a production process therefor and a thermal image recording process utilizing the recording material.

摘要翻译： 一种包含载体，热敏元件及其保护层的记录材料，所述热敏元件包括基本上不光敏的有机银盐，与其热加工关系的有机还原剂和粘合剂，其中所述热敏元件还包含 与基本上不光敏的有机银盐和有机还原剂的反应性缔合物被取代，不包括仅具有吸电子性质的基团，或未取代的化合物与具有芳族环系统的不饱和5元杂环，所述环包括 的氮和碳原子，其中至少一个氮原子具有氢原子，并且没有一个碳原子直接连接到硫原子或者是羰基的一部分; 其制造方法和使用记录材料的热图像记录处理。

公开(公告)号：US5652195A

公开(公告)日：1997-07-29

申请号：US501827

申请日：1995-07-13

申请人： Bartholomeus Horsten ,  Guy Jansen ,  Ronald Schuerwegen

发明人： Bartholomeus Horsten ,  Guy Jansen ,  Ronald Schuerwegen

IPC分类号： B41M5/28 ,  B41M5/30 ,  B41M5/32 ,  B41M5/323 ,  B41M5/337 ,  B41M5/42 ,  B41M5/44 ,  B41M5/46 ,  G03C1/498 ,  B41M5/40

CPC分类号： B41M5/44 ,  B41M5/32 ,  G03C1/4989

摘要： A heat-sensitive recording material suited for use in direct thermal imaging, wherein said recording material comprises in the order given:(i) a transparent polymeric support,(ii) a heat-sensitive imaging layer, and(iii) a protective layer characterized in that said protective layer is an opaque layer containing uniformly distributed in an organic hydrophilic polymeric binder at least one opacifying pigment in the form of particulate material some of which protrudes from the surface of said binder and has anti-stick properties with regard to a thermal print head, and wherein the opacity of layer (iii) corresponds with an absorption and/or scattering of at least 80% of the light of the visible wavelength range (400 to 700 nm), wherein said opaque layer has been coated from an aqueous dispersion of said opacifying pigment particles or precursors thereof.

摘要翻译： 适用于直接热成像的热敏记录材料，其中所述记录材料按照以下顺序包括：（i）透明聚合物载体，（ii）热敏成像层，和（iii）表征的保护层 因为所述保护层是均匀分布在有机亲水聚合物粘合剂中的不透明层，至少一种以颗粒材料形式的不透明颜料，其中一些不透明颜料从所述粘合剂的表面突出并且具有关于热 打印头，并且其中层（iii）的不透明度对应于可见波长范围（400至700nm）的光的至少80％的吸收和/或散射，其中所述不透明层已经由水性 所述不透明颜料颗粒或其前体的分散体。

公开(公告)号：US06579671B2

公开(公告)日：2003-06-17

申请号：US09854749

申请日：2001-05-14

申请人： Sabine Emmers ,  Bartholomeus Horsten ,  Ingrid Geuens ,  Yvan Gilliams ,  Dirk Bollen ,  Ivan Hoogmartens ,  Andre Bellens

发明人： Sabine Emmers ,  Bartholomeus Horsten ,  Ingrid Geuens ,  Yvan Gilliams ,  Dirk Bollen ,  Ivan Hoogmartens ,  Andre Bellens

IPC分类号： G03C100

CPC分类号： G03C1/00 ,  G03C1/49809 ,  G03C1/4989 ,  G03C2200/43

摘要： A recording material comprising a support and a thermosensitive element containing one or more of silver behenate, silver palmitate, and silver stearate, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the silver behenate, palmitate, or stearate is not associated with mercury and/or lead ions, production processes for particles of substantially light-insensitive organic silver salt primarily comprising silver behenate, silver palmitate, or stearate, with described X-ray characteristics in the substantial absence of organic solvent.

摘要翻译： 一种记录材料，其包含载体和含有山嵛酸银，棕榈酸棕榈酯和硬脂酸银中的一种或多种的热敏元件，与其热加工关系的有机还原剂和粘合剂，其中山嵛酸银，棕榈酸酯或硬脂酸酯不是 与汞和/或铅离子相关的生物过程，主要包含山嵛酸银，棕榈酸棕榈酸酯或硬脂酸酯的基本上不受光敏的有机银盐的颗粒的生产方法，其基本上不存在有机溶剂时具有所述的X射线特性。