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公开(公告)号：US4321387A
公开(公告)日：1982-03-23
申请号：US132558
申请日：1980-03-21
IPC分类号： C07D207/08 , C07D401/04 , C07D207/12
CPC分类号： C07D207/08
摘要： A method is disclosed for preparing chiral nicotine and nicotine analogues of the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 are hydrogen or alkyl and R.sub.4 is alkyl. Also disclosed are novel intermediate compounds and a novel method for preparing 1-methylprolinol from prolinol, which compounds and method are useful for the preparation of these nicotinoids.
摘要翻译： 公开了一种制备下式的手性尼古丁和尼古丁类似物的方法：其中R1，R2和R3是氢或烷基，R4是烷基。 还公开了新型中间体化合物和用于从脯氨酸制备1-甲基丙酰醇的新方法，该化合物和方法可用于制备这些烟碱类。
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公开(公告)号：US4656164A
公开(公告)日：1987-04-07
申请号：US763571
申请日：1985-08-08
CPC分类号： C07F9/4081 , A01N57/20 , A01N57/22 , C07F9/4078
摘要： Compounds having the formula ##STR1## in which R.sub.1 is methyl or ethyl; R.sub.2 is C.sub.1 -C.sub.6 alkyl; R.sub.3 is hydrogen, halogen or methyl; and R.sub.4 is hydrogen, methyl or phenyl; or R.sub.3 and R.sub.4 taken together form a tetramethylene chain; provided that R.sub.3 and R.sub.4 are not both hydrogen, are insecticides and/or nematicides.
摘要翻译： 具有式“IMAGE”的化合物，其中R 1是甲基或乙基; R2是C1-C6烷基; R3是氢，卤素或甲基; 和R4是氢，甲基或苯基; 或R 3和R 4一起形成四亚甲基链; 只要R3和R4不都是氢，是杀虫剂和/或杀线虫剂。
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公开(公告)号：US4837209A
公开(公告)日：1989-06-06
申请号：US69996
申请日：1987-07-06
CPC分类号： C07F9/3276 , A01N57/20
摘要： Compounds and compositions containing them, for insecticidal control, particularly for use as soil and/or foliar insecticides, have the formula ##STR1## in which R.sub.1 is methyl or ethyl;R.sub.2 is C.sub.1 -C.sub.6 alkyl; andR.sub.3 is C.sub.3 -C.sub.6 cycloakyl.
摘要翻译： 含有它们的化合物和组合物，用于杀虫控制，特别是用作土壤和/或叶面杀虫剂，具有其中R1是甲基或乙基的式“IMAGE”; R2是C1-C6烷基; R3为C3-C6环烷基。
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公开(公告)号：US4737490A
公开(公告)日：1988-04-12
申请号：US933411
申请日：1986-11-21
CPC分类号： C07F9/4078 , A01N57/20
摘要： Compounds and compositions containing them, for insecticidal control, particularly for use as soil and/or foliar insecticides, have the formula ##STR1## in which R.sub.1 is methyl or ethyl;R.sub.2 is secondary butyl or tertiary butyl;R.sub.3 is hydrogen or methyl;R.sub.4 is hydrogen, methyl or fluoro; andR.sub.5 and R.sub.6 are either both hydrogen or both fluoro.
摘要翻译： 含有它们的化合物和组合物，用于杀虫控制，特别是用作土壤和/或叶面杀虫剂，具有其中R1是甲基或乙基的式“IMAGE”; R2是仲丁基或叔丁基; R3是氢或甲基; R4是氢，甲基或氟; R5和R6既可以是氢也可以是氟。
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5.发明授权S-Dithiocarbamoylmethyl trithiophosphonate insecticides, compositions and use 失效S-二硫代氨基甲酰甲基三硫代磷酸酯杀虫剂，组合物和用途
公开(公告)号：US4552870A
公开(公告)日：1985-11-12
申请号：US732338
申请日：1985-05-10
IPC分类号： A01N57/20 , C07F9/40 , C07F9/6533 , A01N57/24
CPC分类号： C07F9/6533 , A01N57/20 , C07F9/4075
摘要： Compounds and compositions containing them, for insecticidal control having the formula ##STR1## in which R.sub.1 is an alkyl group having from 1 to 3 carbon atoms, R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, and R.sub.3 and R.sub.4 are independently alkyl groups having from 1 to 6 carbon atoms, or R.sub.3 and R.sub.4 taken together form a ring having the formula ##STR2## in which m and n are each integers from 1 to 3 and X is oxygen or --CH.sub.2 --, together with insecticidal compositions containing such compounds, and methods for controlling insects.
摘要翻译： 含有它们的化合物和组合物，具有式（IMAGE）的杀虫剂对照，其中R 1是具有1至3个碳原子的烷基，R 2是具有1至6个碳原子的烷基，R 3和R 4独立地是烷基 具有1至6个碳原子的基团，或者R 3和R 4一起形成具有式“IMAGE”的环，其中m和n各自为1至3的整数，X为氧或-CH 2 - ，以及含有 这些化合物，以及防治昆虫的方法。
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公开(公告)号：US4686210A
公开(公告)日：1987-08-11
申请号：US725716
申请日：1985-04-22
CPC分类号： A01N57/20 , C07F9/4075
摘要： Compounds having the formula ##STR1## in which R.sub.1 is methyl or ethyl; R.sub.2 is C.sub.1 -C.sub.6 alkyl; R.sub.3 is hydrogen or methyl; and R.sub.4 is C.sub.1 -C.sub.4 alkyl; R.sub.3 and R.sub.5 taken together form a trimethylene chain, are insecticides.
摘要翻译： 具有式“IMAGE”的化合物，其中R 1是甲基或乙基; R2是C1-C6烷基; R3是氢或甲基; R4为C1-C4烷基; R3和R5一起形成三亚甲基链，是杀虫剂。
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7.发明授权S-dithiocarbamoylmethyl trithiophosphonate insecticides, compositions and use 失效S-二硫代氨基甲酰甲基三硫代磷酸酯杀虫剂，组合物和用途
公开(公告)号：US4588714A
公开(公告)日：1986-05-13
申请号：US567489
申请日：1984-01-03
IPC分类号： A01N57/20 , C07F9/38 , C07F9/40 , C07F9/6533
CPC分类号： C07F9/6533 , A01N57/20 , C07F9/4075
摘要： Compounds and compositions containing them, for insecticidal control having the formula ##STR1## in which R.sub.1 is an alkyl group having from 1 to 3 carbon atoms, R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, and R.sub.3 and R.sub.4 are independently alkyl groups having from 1 to 6 carbon atoms, or R.sub.3 and R.sub.4 taken together form a ring having the formula ##STR2## in which m and n are each integers from 1 to 3 and X is oxygen or --CH.sub.2 --, together with insecticidal compositions containing such compounds, and methods for controlling insects.
摘要翻译： 含有它们的化合物和组合物，具有式（IMAGE）的杀虫剂对照，其中R 1是具有1至3个碳原子的烷基，R 2是具有1至6个碳原子的烷基，R 3和R 4独立地是烷基 具有1至6个碳原子的基团，或者R 3和R 4一起形成具有式“IMAGE”的环，其中m和n各自为1至3的整数，X为氧或-CH 2 - ，以及含有 这些化合物，以及防治昆虫的方法。
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公开(公告)号：US4544651A
公开(公告)日：1985-10-01
申请号：US600660
申请日：1984-04-16
CPC分类号： A01N57/20 , C07F9/4078
摘要： Compounds for insecticidal control, having the formula ##STR1## in which R.sub.1 is methyl or ethyl; R.sub.2 is a straight or branched chain alkyl group having from 3 to 5 carbon atoms; R.sub.3 is hydrogen, methyl or carbomethoxy; and R.sub.4 is an alkyl group having from 1 to 4 carbon atoms, together with insecticidal compositions containing such compounds, and methods for controlling insects.
摘要翻译： 具有杀虫控制的化合物，其具有式（I），其中R 1是甲基或乙基; R2是具有3至5个碳原子的直链或支链烷基; R3是氢，甲基或甲酯基; R4为具有1至4个碳原子的烷基，以及含有这些化合物的杀虫组合物，以及用于防治昆虫的方法。
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公开(公告)号：US5215998A
公开(公告)日：1993-06-01
申请号：US629536
申请日：1990-12-18
IPC分类号： A01N57/16 , A01N57/24 , C07F9/58 , C07F9/60 , C07F9/6509 , C07F9/6512
CPC分类号： C07F9/65122 , A01N57/16 , A01N57/24 , C07F9/582 , C07F9/60 , C07F9/650917
摘要： Compounds and compositions containing alkylphosphonothioates, for insecticidal control, particularly for use as soil and/or foliar insecticides, having the formula. ##STR1## in which R is C.sub.1 -C.sub.3 alkyl;R.sub.1 is C.sub.4 -C.sub.6 branched alkyl;R.sub.2 is hydrogen, methyl, ethyl, cyano or C.sub.2 -C.sub.4 alkynyl; ##STR2## R.sub.4 is halo, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 thioalkyl or mono-or di-C.sub.1 -C.sub.2 alkylamino;n is 1-3; andX is O or S.
摘要翻译： 含有烷基硫代磷酸酯的化合物和组合物，用于杀虫控制，特别是用作土壤和/或叶面杀虫剂，具有下式。 其中R为C1-C3烷基; R1是C4-C6支链烷基; R2是氢，甲基，乙基，氰基或C2-C4炔基; R4是卤素，C1-C2卤代烷基，C1-C4烷氧基，C1-C4硫代烷基或单或二C1-C2烷基氨基; n为1-3; X是O或S.
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公开(公告)号：US4683225A
公开(公告)日：1987-07-28
申请号：US792087
申请日：1985-10-28
CPC分类号： A01N57/22 , C07F9/4087
摘要： Compounds having the formula ##STR1## in which R.sub.1 is methyl or ethyl; R.sub.2 is C.sub.1 -C.sub.6 alkyl; R.sub.3 is halogen, C.sub.1 -C.sub.4 alkyl, trifluoromethyl, thio-(C.sub.1 -C.sub.4 alkyl) or phenoxy, and n is 0, 1 or 2; provided that if R.sub.2 is methyl, then R.sub.1 is methyl, are insecticides.
摘要翻译： 具有式“IMAGE”的化合物，其中R 1是甲基或乙基; R2是C1-C6烷基; R3是卤素，C1-C4烷基，三氟甲基，硫代 - （C1-C4烷基）或苯氧基，n是0,1或2; 条件是如果R2是甲基，则R1是甲基，是杀虫剂。
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