CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYETHYLENE VIA REFINERY FCC FEED PRETREATER AND FCC UNITS

    公开(公告)号:US20210301210A1

    公开(公告)日:2021-09-30

    申请号:US17131928

    申请日:2020-12-23

    Abstract: Provided in one embodiment is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil and optionally pyrolysis wax comprising a naphtha/diesel fraction and heavy fraction, and char. The pyrolysis oil and wax is passed to a refinery FCC feed pretreater unit. A heavy fraction is recovered and sent to a refinery FCC unit, from which a C3 olefin/paraffin mixture fraction is recovered, which is passed to a steam cracker for ethylene production. In another embodiment, a propane fraction (C3) is recovered from a propane/propylene splitter and passed to the steam cracker.

    CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYETHYLENE VIA REFINERY FCC OR FCC/ALKYLATION UNITS

    公开(公告)号:US20210301209A1

    公开(公告)日:2021-09-30

    申请号:US17131910

    申请日:2020-12-23

    Abstract: Provided in one embodiment is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil and optionally wax comprising a naphtha/diesel and heavy fraction, and char. The pyrolysis oil is passed to a refinery FCC unit from which a liquid petroleum gas C3 olefin/paraffin mixture fraction is recovered, as well as a C4 olefin/paraffin mixture fraction. The liquid petroleum gas C3 olefin/paraffin mixture fraction is passed to a steam cracker for ethylene production. The C4 olefin/paraffin mixture fraction is passed to a refinery alkylation unit, from which a n-butane and naphtha feed for a stream cracker to produce ethylene is recovered.

    Circular economy for plastic waste to polyethylene via refinery FCC feed pretreater and FCC units

    公开(公告)号:US11566182B2

    公开(公告)日:2023-01-31

    申请号:US17131928

    申请日:2020-12-23

    Abstract: Provided in one embodiment is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil and optionally pyrolysis wax comprising a naphtha/diesel fraction and heavy fraction, and char. The pyrolysis oil and wax is passed to a refinery FCC feed pretreater unit. A heavy fraction is recovered and sent to a refinery FCC unit, from which a C3 olefin/paraffin mixture fraction is recovered, which is passed to a steam cracker for ethylene production. In another embodiment, a propane fraction (C3) is recovered from a propane/propylene splitter and passed to the steam cracker.

    Circular economy for plastic waste to polyethylene via refinery FCC or FCC/alkylation units

    公开(公告)号:US11306253B2

    公开(公告)日:2022-04-19

    申请号:US17131910

    申请日:2020-12-23

    Abstract: Provided in one embodiment is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil and optionally wax comprising a naphtha/diesel and heavy fraction, and char. The pyrolysis oil is passed to a refinery FCC unit from which a liquid petroleum gas C3 olefin/paraffin mixture fraction is recovered, as well as a C4 olefin/paraffin mixture fraction. The liquid petroleum gas C3 olefin/paraffin mixture fraction is passed to a steam cracker for ethylene production. The C4 olefin/paraffin mixture fraction is passed to a refinery alkylation unit, from which a n-butane and naphtha feed for a stream cracker to produce ethylene is recovered.

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