公开(公告)号：US20140206821A1

公开(公告)日：2014-07-24

申请号：US14160879

申请日：2014-01-22

申请人： Chuanbing Tang ,  Yali Qiao ,  Harry J. Ploehn ,  MD. Sayful Islam

发明人： Chuanbing Tang ,  Yali Qiao ,  Harry J. Ploehn ,  MD. Sayful Islam

IPC分类号： C08F28/06

CPC分类号： C08F220/38 ,  C08F220/30 ,  C08F220/60 ,  C08F293/005 ,  C08F2220/302 ,  C08F2220/365 ,  C08F2220/387 ,  C08F2220/606

摘要： A π-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer is generally provided, which can include a polymerizable group, a linker group, and a π-conjugated aromatic/heteroaromatic side chain. The π-conjugated aromatic/heteroaromatic side chain includes a first cyclopentadiene ring covalently attached to the linder group, a set of second cyclopentadiene rings covalently attached to the first cyclopentadiene ring, and a third cyclopentadiene ring positioned at a terminal end of the π-conjugated aromatic/heteroaromatic side chain such that the set of second cyclopentadiene rings is positioned between the first cyclopentadiene ring and the third cyclopentadiene ring. Methods are also provided for forming a polymer via polymerizing the π-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer, and for grafting a π-conjugated aromatic/heteroaromatic oligomer-containing polymer onto a surface of a nanomaterial.

摘要翻译： 通常提供含共轭芳族/杂芳族低聚物的乙烯基单体，其可以包括可聚合基团，连接基团和共轭芳族/杂芳族侧链。 共轭芳族/杂芳族侧链包括共价连接到熔融基团上的第一环戊二烯环，共价连接到第一环戊二烯环上的一组第二环戊二烯环和位于第一环戊二烯末端的第三环戊二烯环; 共轭芳族/杂芳族侧链，使得该组第二环戊二烯环位于第一环戊二烯环和第三环戊二烯环之间。 还提供了通过聚合具有共轭芳香族/杂芳族低聚物的乙烯基单体形成聚合物的方法，以及用于将共轭芳族/杂芳族低聚物聚合物接枝到纳米材料的表面上。

公开(公告)号：US09346906B2

公开(公告)日：2016-05-24

申请号：US14160879

申请日：2014-01-22

申请人： Chuanbing Tang ,  Yali Qiao ,  Harry J. Ploehn ,  Sayful Islam

发明人： Chuanbing Tang ,  Yali Qiao ,  Harry J. Ploehn ,  Sayful Islam

IPC分类号： C08F28/06 ,  C08F220/30 ,  C08F220/38 ,  C08F220/60 ,  C08F220/36

CPC分类号： C08F220/38 ,  C08F220/30 ,  C08F220/60 ,  C08F293/005 ,  C08F2220/302 ,  C08F2220/365 ,  C08F2220/387 ,  C08F2220/606

摘要： A π-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer is generally provided, which can include a polymerizable group, a linker group, and a π-conjugated aromatic/heteroaromatic side chain. The π-conjugated aromatic/heteroaromatic side chain includes a first cyclopentadiene ring covalently attached to the linker group, a set of second cyclopentadiene rings covalently attached to the first cyclopentadiene ring, and a third cyclopentadiene ring positioned at a terminal end of the π-conjugated aromatic/heteroaromatic side chain such that the set of second cyclopentadiene rings is positioned between the first cyclopentadiene ring and the third cyclopentadiene ring. Methods are also provided for forming a polymer via polymerizing the π-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer, and for grafting a π-conjugated aromatic/heteroaromatic oligomer-containing polymer onto a surface of a nanomaterial.

摘要翻译： 通常提供含共轭芳族/杂芳族低聚物的乙烯基单体，其可以包括可聚合基团，连接基团和共轭芳族/杂芳族侧链。 共轭芳族/杂芳族侧链包括共价连接到连接基团上的第一环戊二烯环，共价连接到第一环戊二烯环上的一组第二环戊二烯环和位于第一环戊二烯末端的第三环戊二烯环; 共轭芳族/杂芳族侧链，使得该组第二环戊二烯环位于第一环戊二烯环和第三环戊二烯环之间。 还提供了通过聚合具有共轭芳香族/杂芳族低聚物的乙烯基单体形成聚合物的方法，以及用于将共轭芳族/杂芳族低聚物聚合物接枝到纳米材料的表面上。