公开(公告)号：US09346906B2

公开(公告)日：2016-05-24

申请号：US14160879

申请日：2014-01-22

申请人： Chuanbing Tang ,  Yali Qiao ,  Harry J. Ploehn ,  Sayful Islam

发明人： Chuanbing Tang ,  Yali Qiao ,  Harry J. Ploehn ,  Sayful Islam

IPC分类号： C08F28/06 ,  C08F220/30 ,  C08F220/38 ,  C08F220/60 ,  C08F220/36

CPC分类号： C08F220/38 ,  C08F220/30 ,  C08F220/60 ,  C08F293/005 ,  C08F2220/302 ,  C08F2220/365 ,  C08F2220/387 ,  C08F2220/606

摘要： A π-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer is generally provided, which can include a polymerizable group, a linker group, and a π-conjugated aromatic/heteroaromatic side chain. The π-conjugated aromatic/heteroaromatic side chain includes a first cyclopentadiene ring covalently attached to the linker group, a set of second cyclopentadiene rings covalently attached to the first cyclopentadiene ring, and a third cyclopentadiene ring positioned at a terminal end of the π-conjugated aromatic/heteroaromatic side chain such that the set of second cyclopentadiene rings is positioned between the first cyclopentadiene ring and the third cyclopentadiene ring. Methods are also provided for forming a polymer via polymerizing the π-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer, and for grafting a π-conjugated aromatic/heteroaromatic oligomer-containing polymer onto a surface of a nanomaterial.

摘要翻译： 通常提供含共轭芳族/杂芳族低聚物的乙烯基单体，其可以包括可聚合基团，连接基团和共轭芳族/杂芳族侧链。 共轭芳族/杂芳族侧链包括共价连接到连接基团上的第一环戊二烯环，共价连接到第一环戊二烯环上的一组第二环戊二烯环和位于第一环戊二烯末端的第三环戊二烯环; 共轭芳族/杂芳族侧链，使得该组第二环戊二烯环位于第一环戊二烯环和第三环戊二烯环之间。 还提供了通过聚合具有共轭芳香族/杂芳族低聚物的乙烯基单体形成聚合物的方法，以及用于将共轭芳族/杂芳族低聚物聚合物接枝到纳米材料的表面上。

公开(公告)号：US20140206821A1

公开(公告)日：2014-07-24

申请号：US14160879

申请日：2014-01-22

申请人： Chuanbing Tang ,  Yali Qiao ,  Harry J. Ploehn ,  MD. Sayful Islam

发明人： Chuanbing Tang ,  Yali Qiao ,  Harry J. Ploehn ,  MD. Sayful Islam

IPC分类号： C08F28/06

CPC分类号： C08F220/38 ,  C08F220/30 ,  C08F220/60 ,  C08F293/005 ,  C08F2220/302 ,  C08F2220/365 ,  C08F2220/387 ,  C08F2220/606

摘要： A π-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer is generally provided, which can include a polymerizable group, a linker group, and a π-conjugated aromatic/heteroaromatic side chain. The π-conjugated aromatic/heteroaromatic side chain includes a first cyclopentadiene ring covalently attached to the linder group, a set of second cyclopentadiene rings covalently attached to the first cyclopentadiene ring, and a third cyclopentadiene ring positioned at a terminal end of the π-conjugated aromatic/heteroaromatic side chain such that the set of second cyclopentadiene rings is positioned between the first cyclopentadiene ring and the third cyclopentadiene ring. Methods are also provided for forming a polymer via polymerizing the π-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer, and for grafting a π-conjugated aromatic/heteroaromatic oligomer-containing polymer onto a surface of a nanomaterial.

摘要翻译： 通常提供含共轭芳族/杂芳族低聚物的乙烯基单体，其可以包括可聚合基团，连接基团和共轭芳族/杂芳族侧链。 共轭芳族/杂芳族侧链包括共价连接到熔融基团上的第一环戊二烯环，共价连接到第一环戊二烯环上的一组第二环戊二烯环和位于第一环戊二烯末端的第三环戊二烯环; 共轭芳族/杂芳族侧链，使得该组第二环戊二烯环位于第一环戊二烯环和第三环戊二烯环之间。 还提供了通过聚合具有共轭芳香族/杂芳族低聚物的乙烯基单体形成聚合物的方法，以及用于将共轭芳族/杂芳族低聚物聚合物接枝到纳米材料的表面上。

公开(公告)号：US20100223979A1

公开(公告)日：2010-09-09

申请号：US12397520

申请日：2009-03-04

申请人： Harry J. Ploehn ,  John R. Monnier ,  Xiaoming Chen

发明人： Harry J. Ploehn ,  John R. Monnier ,  Xiaoming Chen

IPC分类号： G01N15/08 ,  H01J49/26

CPC分类号： G01N15/0826 ,  G01N2015/086

摘要： In accordance with one embodiment of the present disclosure, a system for determining the rate of gas permeation through a film is described. The system comprises a continuous flow permeation cell, a mass spectrometer, a test gas source, and a carrier gas source. The continuous flow permeation cell comprises a supply chamber in communication with the test gas source and a receiving chamber in communication with the carrier gas source and the mass spectrometer. The supply chamber is configured to be separated from the receiving chamber by a test film such that when a test gas stream is fed to the supply chamber from the test gas source and a carrier gas stream is fed to the receiving chamber from the carrier gas source. At least a portion of the test gas stream permeates from the supply chamber through the test film to the receiving chamber and mixes with the carrier gas stream and the mixture flows to the mass spectrometer. The mass spectrometer is utilized to determine the rate of permeation of the test gas stream through the film.

摘要翻译： 根据本公开的一个实施例，描述了一种用于确定通过膜的气体渗透速率的系统。 该系统包括连续流动渗透池，质谱仪，测试气体源和载气源。 连续流动渗透池包括与测试气体源连通的供应室和与载气源和质谱仪连通的接收室。 供给室被配置为通过测试膜与接收室分离，使得当将测试气体流从测试气体源供给到供应室时，并且载气流从载气源供给到接收室 。 至少一部分试验气流从供给室穿过测试膜渗透到接收室，并与载气流混合，混合物流入质谱仪。 使用质谱仪来确定测试气流通过膜的渗透速率。

公开(公告)号：US20100216924A1

公开(公告)日：2010-08-26

申请号：US12705761

申请日：2010-02-15

申请人： Arthur Peter Barber, III ,  Harry J. Ploehn ,  Hans-Conrad zur Loye

发明人： Arthur Peter Barber, III ,  Harry J. Ploehn ,  Hans-Conrad zur Loye

IPC分类号： C08K5/5317 ,  C07F9/28 ,  C07F9/02

CPC分类号： C08K5/5317 ,  C07F9/3834

摘要： Mixed metal phosphonates are generally provided. The mixed metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, or combinations thereof; B is Ti4+, Zr4+, Al3+, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The mixed metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the mixed metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.

摘要翻译： 通常提供混合金属膦酸盐。 混合金属膦酸盐通常可以具有：AB（RPO 3）3，其中A是Mg 2+，Ca 2+，Sr 2+，Ba 2+，Pb 2+，La 3+或其组合; B是Ti4 +，Zr4 +，Al3 +或它们的组合; R为有机基团（例如，芳基，烷基，烯基等）。 混合金属膦酸盐可以与聚合物材料组合以形成聚合物膜。 还提供了通过使金属氧化物和有机膦酸组合和反应制备混合金属膦酸盐的方法。

公开(公告)号：US08424367B2

公开(公告)日：2013-04-23

申请号：US12397520

申请日：2009-03-04

申请人： Harry J. Ploehn ,  John R. Monnier ,  Xiaoming Chen

发明人： Harry J. Ploehn ,  John R. Monnier ,  Xiaoming Chen

IPC分类号： G01N15/08

CPC分类号： G01N15/0826 ,  G01N2015/086

摘要： In accordance with one embodiment of the present disclosure, a system for determining the rate of gas permeation through a film is described. The system comprises a continuous flow permeation cell, a mass spectrometer, a test gas source, and a carrier gas source. The continuous flow permeation cell comprises a supply chamber in communication with the test gas source and a receiving chamber in communication with the carrier gas source and the mass spectrometer. The supply chamber is configured to be separated from the receiving chamber by a test film such that when a test gas stream is fed to the supply chamber from the test gas source and a carrier gas stream is fed to the receiving chamber from the carrier gas source. At least a portion of the test gas stream permeates from the supply chamber through the test film to the receiving chamber and mixes with the carrier gas stream and the mixture flows to the mass spectrometer. The mass spectrometer is utilized to determine the rate of permeation of the test gas stream through the film.

摘要翻译： 根据本公开的一个实施例，描述了一种用于确定通过膜的气体渗透速率的系统。 该系统包括连续流动渗透池，质谱仪，测试气体源和载气源。 连续流动渗透池包括与测试气体源连通的供应室和与载气源和质谱仪连通的接收室。 供给室被配置为通过测试膜与接收室分离，使得当将测试气体流从测试气体源供给到供应室时，并且载气流从载气源供给到接收室 。 至少一部分试验气流从供给室穿过测试膜渗透到接收室，并与载气流混合，混合物流入质谱仪。 使用质谱仪来确定测试气流通过膜的渗透速率。

公开(公告)号：US08247586B2

公开(公告)日：2012-08-21

申请号：US13329731

申请日：2011-12-19

申请人： Arthur Peter Barber, III ,  Harry J. Ploehn ,  Hans-Conrad zur Loye

发明人： Arthur Peter Barber, III ,  Harry J. Ploehn ,  Hans-Conrad zur Loye

IPC分类号： C07F9/02

CPC分类号： C08K5/5317 ,  C07F9/3834

摘要： Multi-metal phosphonates are generally provided. The multi-metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, or combinations thereof; B is Ti4+, Zr4+, Al3−, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The multi-metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the multi-metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.

摘要翻译： 通常提供多金属膦酸盐。 多金属膦酸盐通常可以具有：AB（RPO 3）3，其中A是Mg 2+，Ca 2+，Sr 2+，Ba 2+，Pb 2+，La 3+或其组合; B是Ti4 +，Zr4 +，Al3-或它们的组合; R为有机基团（例如，芳基，烷基，烯基等）。 多金属膦酸盐可以与聚合物材料组合以形成聚合物膜。 还提供了通过使金属氧化物和有机膦酸组合和反应制备多金属膦酸盐的方法。

公开(公告)号：US20120095142A1

公开(公告)日：2012-04-19

申请号：US13329731

申请日：2011-12-19

申请人： Arthur Peter Barber, III ,  Harry J. Ploehn ,  Hans-Conrad zur Loye

发明人： Arthur Peter Barber, III ,  Harry J. Ploehn ,  Hans-Conrad zur Loye

IPC分类号： C08K5/5317 ,  C08L25/06 ,  C07F19/00

CPC分类号： C08K5/5317 ,  C07F9/3834

摘要： Mixed metal phosphonates are generally provided. The mixed metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, or combinations thereof; B is Ti4+, Zr4+, Al3−, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The mixed metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the mixed metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.

摘要翻译： 通常提供混合金属膦酸盐。 混合金属膦酸盐通常可以具有：AB（RPO 3）3，其中A是Mg 2+，Ca 2+，Sr 2+，Ba 2+，Pb 2+，La 3+或其组合; B是Ti4 +，Zr4 +，Al3-或它们的组合; R为有机基团（例如，芳基，烷基，烯基等）。 混合金属膦酸盐可以与聚合物材料组合以形成聚合物膜。 还提供了通过使金属氧化物和有机膦酸组合和反应制备混合金属膦酸盐的方法。

公开(公告)号：US08080600B2

公开(公告)日：2011-12-20

申请号：US12705761

申请日：2010-02-15

申请人： Arthur Peter Barber, III ,  Harry J. Ploehn ,  Hans-Conrad zur Loye

发明人： Arthur Peter Barber, III ,  Harry J. Ploehn ,  Hans-Conrad zur Loye

IPC分类号： C08K5/5333

CPC分类号： C08K5/5317 ,  C07F9/3834

摘要： Mixed metal phosphonates are generally provided. The mixed metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, Co2+, Mn2+, Fe2+, or combinations thereof; B is Ti4+, Zr4+, Al3+, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The mixed metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the mixed metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.

摘要翻译： 通常提供混合金属膦酸盐。 混合金属膦酸盐通常可以具有：AB（RPO 3）3，其中A是Mg 2+，Ca 2+，Sr 2+，Ba 2+，Pb 2+，La 3+，Co 2+，Mn 2+，Fe 2+，或其组合; B是Ti4 +，Zr4 +，Al3 +或它们的组合; R为有机基团（例如，芳基，烷基，烯基等）。 混合金属膦酸盐可以与聚合物材料组合以形成聚合物膜。 还提供了通过使金属氧化物和有机膦酸组合和反应制备混合金属膦酸盐的方法。